Enantioselective Synthesis of a 1,2-Disubstituted Mitosene by a Copper-Catalyzed Intramolecular Carbon-Hydrogen Insertion Reaction of a Diazo Ester

1995 ◽  
Vol 60 (8) ◽  
pp. 2326-2327 ◽  
Author(s):  
Hee-Jong Lim ◽  
Gary A. Sulikowski
Keyword(s):  
Enantioselective Synthesis ◽  
Insertion Reaction ◽  
Hydrogen Insertion

scholarly journals Enantioselective synthesis of α-alkenyl α-amino acids via N–H insertion reactions

2016 ◽  
Vol 7 (2) ◽  
pp. 1104-1108 ◽  
Author(s):  
Jun-Xia Guo ◽  
Ting Zhou ◽  
Bin Xu ◽  
Shou-Fei Zhu ◽  
Qi-Lin Zhou
Keyword(s):  
Amino Acids ◽  
Amino Acid ◽  
Enantioselective Synthesis ◽  
Insertion Reaction ◽  
Amino Acid Derivatives ◽  
Insertion Reactions ◽  
Phosphoric Acids

A new highly enantioselective route to α-alkenyl α-amino acid derivatives using a N–H insertion reaction of vinyldiazoacetates and tert-butyl carbamate cooperatively catalyzed by achiral dirhodium(ii) carboxylates and chiral spiro phosphoric acids was developed.

Rh(II)-catalyzed enantioselective synthesis of acuminatin through a C–H insertion reaction of a non-stabilized carbenoid

Tetrahedron ◽  
2013 ◽  
Vol 69 (26) ◽  
pp. 5511-5516 ◽  
Author(s):  
Cristóbal López-Sánchez ◽  
Míriam Álvarez-Corral ◽  
Leticia Jiménez-González ◽  
Manuel Muñoz-Dorado ◽  
Ignacio Rodríguez-García
Keyword(s):  
Enantioselective Synthesis ◽  
Insertion Reaction

scholarly journals Dirhodium(II)-Catalyzed Intramolecular Carbon-Hydrogen Insertion Reaction of .ALPHA.-Diazoketones: Synthesis of 7-Silyloxyoctahydrobenzo(b)furan-2-ones.

1997 ◽  
Vol 45 (4) ◽  
pp. 651-658 ◽  
Author(s):  
Takayuki YAKURA ◽  
Daisaku YOSHIDA ◽  
Akiharu UEKI ◽  
Keiko NAKAO ◽  
Masazumi IKEDA
Keyword(s):  
Insertion Reaction ◽  
Hydrogen Insertion
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