Methanol Decomposition on Co(0001): Influence of the Cobalt Oxidation State on Reactivity

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Qing Guo ◽  
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Wenshao Yang ◽  
Dongxu Dai ◽  
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Kazunori Takada ◽  
Hiroya Sakurai ◽  
Eiji Takayama-Muromachi ◽  
Fujio Izumi ◽  
Ruben A. Dilanian ◽  
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2005 ◽  
Vol 72 (13) ◽  
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P. Barnes ◽  
M. Avdeev ◽  
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H. Claus ◽  
...  

2020 ◽  
Vol 124 (30) ◽  
pp. 16508-16514
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James L. White ◽  
Forrest S. Gittleson ◽  
Mark Homer ◽  
Farid El Gabaly

2010 ◽  
Vol 269 (2) ◽  
pp. 309-317 ◽  
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S. Zafeiratos ◽  
T. Dintzer ◽  
D. Teschner ◽  
R. Blume ◽  
M. Hävecker ◽  
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2003 ◽  
Vol 104 ◽  
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Philippe Renaud

<div><div><div><div><p>A very concise total synthesis of (+)-brefeldin C starting from 2-furanylcyclopentene is described. This approach is based on an unprecedented enantioselective radical hydroalkynylation process to introduce the two cyclopentane stereocenters in a single step. The use of a furan substituent allows to achieve a high trans diastereoselectivity during the radical process and it contains the four carbon atoms C1–C4 of the natural product in an oxidation state closely related to the one of the target molecule. The eight-step synthesis require six product purifications and it provides (+)-brefeldin C in 18% overall yield.</p></div></div></div></div>


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