Importance of Long-Term Storage for Fluorine-Substituted Aromatic Self-Assembled Monolayers by the Example of 4-Fluorobenzene-1-Thiolate Films on Au(111)

2019 ◽  
Vol 123 (7) ◽  
pp. 4308-4318 ◽  
Author(s):  
Waleed Azzam ◽  
Eric Sauter ◽  
Awad A. Alrashdi ◽  
Najd Al-Refaie ◽  
Michael Rohwerder ◽  
...  
Keyword(s):  
Self Assembled Monolayers ◽  
Long Term Storage ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Term Storage

scholarly journals Variations in the structure and reactivity of thioester functionalized self-assembled monolayers and their use for controlled surface modification

2012 ◽  
Vol 3 ◽  
pp. 213-220 ◽  
Author(s):  
Inbal Aped ◽  
Yacov Mazuz ◽  
Chaim N Sukenik
Keyword(s):  
Surface Modification ◽  
Structural Diversity ◽  
Self Assembled Monolayers ◽  
Wetting Properties ◽  
Long Term Storage ◽  
Assembled Monolayers ◽  
Important Approach ◽  
Self Assembled ◽  
Term Storage

Thioester-functionalized, siloxane-anchored, self-assembled monolayers provide a powerful tool for controlling the chemical and physical properties of surfaces. The thioester moiety is relatively stable to long-term storage and its structure can be systematically varied so as to provide a well-defined range of reactivity and wetting properties. The oxidation of thioesters with different-chain-length acyl groups allows for very hydrophobic surfaces to be transformed into very hydrophilic, sulfonic acid-bearing, surfaces. Systematic variation in the length of the polymethylene chain has also allowed us to examine how imbedding reaction sites at various depths in a densely packed monolayer changes their reactivity. π-Systems (benzene and thiophene) conjugated to the thioester carbonyl enable the facile creation of photoreactive surfaces that are able to use light of different wavelengths. These elements of structural diversity combine with the utility of the hydrophilic, strongly negatively charged sulfonate-bearing surface to constitute an important approach to systematic surface modification.

Long-Term Stability of Self-Assembled Monolayers in Biological Media

Langmuir ◽  
2003 ◽  
Vol 19 (26) ◽  
pp. 10909-10915 ◽  
Author(s):  
Nolan T. Flynn ◽  
Thanh Nga T. Tran ◽  
Michael J. Cima ◽  
Robert Langer
Keyword(s):  
Self Assembled Monolayers ◽  
Biological Media ◽  
Term Stability ◽  
Long Term Stability ◽  
Assembled Monolayers ◽  
Self Assembled

scholarly journals Increased Stability of Glycol-Terminated Self-Assembled Monolayers for Long-Term Patterned Cell Culture

Langmuir ◽  
2012 ◽  
Vol 28 (9) ◽  
pp. 4318-4324 ◽  
Author(s):  
Matthew K. Strulson ◽  
Dawn M. Johnson ◽  
Joshua A. Maurer
Keyword(s):  
Cell Culture ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Using Mixed Self-Assembled Monolayers Presenting RGD and (EG)3OH Groups To Characterize Long-Term Attachment of Bovine Capillary Endothelial Cells to Surfaces

1998 ◽  
Vol 120 (26) ◽  
pp. 6548-6555 ◽  
Author(s):  
Carmichael Roberts ◽  
Christopher S. Chen ◽  
Milan Mrksich ◽  
Valerie Martichonok ◽  
Donald E. Ingber ◽  
...  
Keyword(s):  
Endothelial Cells ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Capillary Endothelial Cells ◽  
Self Assembled

Long-term stability of self-assembled monolayers on 316L stainless steel

2010 ◽  
Vol 5 (2) ◽  
pp. 025008 ◽  
Author(s):  
C R Kaufmann ◽  
G Mani ◽  
D Marton ◽  
D M Johnson ◽  
C M Agrawal
Keyword(s):  
Stainless Steel ◽  
316L Stainless Steel ◽  
Self Assembled Monolayers ◽  
Term Stability ◽  
Long Term Stability ◽  
Assembled Monolayers ◽  
Self Assembled

Electrochemical behavior of self-assembled monolayers based on functionalized oligothiophenes

1998 ◽  
Vol 95 (6) ◽  
pp. 1339-1342 ◽  
Author(s):  
R. Michalitsch ◽  
A. El Kassmi ◽  
P. Lang ◽  
A. Yassar ◽  
F. Garnier
Keyword(s):  
Electrochemical Behavior ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Imaging of patterned self-assembled monolayers by scanning photoelectron microscopy

2003 ◽  
Vol 104 ◽  
pp. 459-462 ◽  
Author(s):  
R. Klauser ◽  
M. Zharnikov ◽  
I.-H. Hong ◽  
S.-C. Wang ◽  
A. Gölzhäuser ◽  
...  
Keyword(s):  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Scanning Photoelectron Microscopy ◽  
Self Assembled
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