Photocatalytic Activity Suppression of CdS Nanoparticle-Decorated Cu2O Octahedra and Rhombic Dodecahedra

2018 ◽  
Vol 122 (24) ◽  
pp. 12944-12950 ◽  
Author(s):  
Jing-Yi Huang ◽  
Pei-Lun Hsieh ◽  
Gollapally Naresh ◽  
Hsin-Yi Tsai ◽  
Michael H. Huang
2015 ◽  
Vol 44 (25) ◽  
pp. 11321-11330 ◽  
Author(s):  
Yanhui Ao ◽  
Liya Xu ◽  
Peifang Wang ◽  
Chao Wang ◽  
Jun Hou ◽  
...  

In this work, a series of novel flower-like Bi2O2CO3/CdS heterojunctions were prepared by a simple and feasible two-step process. The results showed that the as-prepared Bi2O2CO3/CdS heterojunctions exhibited much higher activity than pure Bi2O2CO3.


2019 ◽  
Vol 123 (4) ◽  
pp. 2314-2320 ◽  
Author(s):  
Gollapally Naresh ◽  
An-Ting Lee ◽  
Vandana Meena ◽  
M. Satyanarayana ◽  
Michael H. Huang

2021 ◽  
Author(s):  
Yanqing Cong ◽  
Xiang Chen ◽  
Wanxing Wang ◽  
Shi-Wen Lv

Photocatalytic technique is an attractive strategy to activate persulfate for generating free radicals in the wastewater purification process. Herein, the CdS nanoparticle with unique optical property was employed to decorate...


2018 ◽  
Vol 18 (3) ◽  
pp. 81-91 ◽  
Author(s):  
C. Lalhriatpuia

Nanopillars-TiO2 thin films was obtained on a borosilicate glass substrate with (S1) and without (S2) polyethylene glycol as template. The photocatalytic behaviour of S1 and S2 thin films was assessed inthe degradation of methylene blue (MB) dye from aqueous solution under batch reactor operations. The thin films were characterized by the SEM, XRD, FTIR and AFM analytical methods. BET specific surface area and pore sizes were also obtained. The XRD data confirmed that the TiO2 particles are in its anatase mineral phase. The SEM and AFM images indicated the catalyst is composed with nanosized pillars of TiO2, evenly distributed on the surface of the substrate. The BET specific surface area and pore sizes of S1 and S2 catalyst were found to be 5.217 and 1.420 m2/g and 7.77 and 4.16 nm respectively. The photocatalytic degradation of MB was well studied at wide range of physico-chemical parameters. The effect of solution pH (pH 4.0 to 10.0) and MB initial concentration (1.0 to 10.0 mg/L) was extensively studied and the effect of several interfering ions, i.e., cadmium nitrate, copper sulfate, zinc chloride, sodium chloride, sodium nitrate, sodium nitrite, glycine, oxalic acid and EDTA in the photocatalytic degradation of MB was demonstrated. The maximum percent removal of MB was observed at pH 8.0 beyond which it started decreasing and a low initial concentration of the pollutant highly favoured the photocatalytic degradation using thin films and the presence of several interfering ions diminished the photocatalytic activity of thin films to some extent. The overall photocatalytic activity was in the order: S2 > S1 > UV. The photocatalytic degradation of MB was followed the pseudo-first-order rate kinetics. The mineralization of MB was studied with total organic carbon measurement using the TOC (total organic carbon) analysis.


MRS Advances ◽  
2020 ◽  
Vol 5 (61) ◽  
pp. 3141-3152
Author(s):  
Alma C. Chávez-Mejía ◽  
Génesis Villegas-Suárez ◽  
Paloma I. Zaragoza-Sánchez ◽  
Rafael Magaña-López ◽  
Julio C. Morales-Mejía ◽  
...  

AbstractSeveral photocatalysts, based on titanium dioxide, were synthesized by spark anodization techniques and anodic spark oxidation. Photocatalytic activity was determined by methylene blue oxidation and the catalytic activities of the catalysts were evaluated after 70 hours of reaction. Scanning Electron Microscopy and X Ray Diffraction analysis were used to characterize the catalysts. The photocatalyst prepared with a solution of sulfuric acid and 100 V presented the best performance in terms of oxidation of the dye (62%). The electric potential during the synthesis (10 V, low potential; 100 V, high potential) affected the surface characteristics: under low potential, catalyst presented smooth and homogeneous surfaces with spots (high TiO2 concentration) of amorphous solids; under low potential, catalyst presented porous surfaces with crystalline solids homogeneously distributed.


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