Fast Voltage Decay in Perovskite Solar Cells Caused by Depolarization of Perovskite Layer

2018 ◽  
Vol 122 (9) ◽  
pp. 4822-4827 ◽  
Author(s):  
Qiong Wang
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Perovskite Layer ◽  
Voltage Decay

scholarly journals A general approach to high-efficiency perovskite solar cells by any antisolvent

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Alexander D. Taylor ◽  
Qing Sun ◽  
Katelyn P. Goetz ◽  
Qingzhi An ◽  
Tim Schramm ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Precursor Solution ◽  
Microstructural Characterization ◽  
Application Rate ◽  
Perovskite Layer ◽  
Highly Efficient ◽  
Application Procedure ◽  
Wide Range

AbstractDeposition of perovskite films by antisolvent engineering is a highly common method employed in perovskite photovoltaics research. Herein, we report on a general method that allows for the fabrication of highly efficient perovskite solar cells by any antisolvent via manipulation of the antisolvent application rate. Through detailed structural, compositional, and microstructural characterization of perovskite layers fabricated by 14 different antisolvents, we identify two key factors that influence the quality of the perovskite layer: the solubility of the organic precursors in the antisolvent and its miscibility with the host solvent(s) of the perovskite precursor solution, which combine to produce rate-dependent behavior during the antisolvent application step. Leveraging this, we produce devices with power conversion efficiencies (PCEs) that exceed 21% using a wide range of antisolvents. Moreover, we demonstrate that employing the optimal antisolvent application procedure allows for highly efficient solar cells to be fabricated from a broad range of precursor stoichiometries.

scholarly journals Effect of SnO2 Colloidal Dispersion Solution Concentration on the Quality of Perovskite Layer of Solar Cells

Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 591
Author(s):  
Keke Song ◽  
Xiaoping Zou ◽  
Huiyin Zhang ◽  
Chunqian Zhang ◽  
Jin Cheng ◽  
...  
Keyword(s):  
Solar Cells ◽  
Low Temperature ◽  
High Efficiency ◽  
Surface Condition ◽  
Perovskite Solar Cells ◽  
Colloidal Dispersion ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Perovskite Layer ◽  
Dispersion Solution

The electron transport layer (ETL) is critical to carrier extraction for perovskite solar cells (PSCs). Moreover, the morphology and surface condition of the ETL could influence the topography of the perovskite layer. ZnO, TiO2, and SnO2 were widely investigated as ETL materials. However, TiO2 requires a sintering process under high temperature and ZnO has the trouble of chemical instability. SnO2 possesses the advantages of low-temperature fabrication and high conductivity, which is critical to the performance of PSCs prepared under low temperature. Here, we optimized the morphology and property of SnO2 by modulating the concentration of a SnO2 colloidal dispersion solution. When adjusting the concentration of SnO2 colloidal dispersion solution to 5 wt.% (in water), SnO2 film indicated better performance and the perovskite film has a large grain size and smooth surface. Based on high efficiency (16.82%), the device keeps a low hysteresis index (0.23).

scholarly journals Chemical anti-corrosion strategy for stable inverted perovskite solar cells

2020 ◽  
Vol 6 (51) ◽  
pp. eabd1580
Author(s):  
Xiaodong Li ◽  
Sheng Fu ◽  
Wenxiao Zhang ◽  
Shanzhe Ke ◽  
Weijie Song ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Electrochemical Corrosion ◽  
Metal Electrodes ◽  
Maximum Power Point ◽  
Perovskite Layer ◽  
Point Tracking ◽  
Power Point Tracking ◽  
Organic Corrosion Inhibitor ◽  
Power Point

One big challenge for long-lived inverted perovskite solar cells (PSCs) is that commonly used metal electrodes react with perovskite layer, inducing electrode corrosion and device degradation. Motivated by the idea of metal anticorrosion, here, we propose a chemical anticorrosion strategy to fabricate stable inverted PSCs through introducing a typical organic corrosion inhibitor of benzotriazole (BTA) before Cu electrode deposition. BTA molecules chemically coordinate to the Cu electrode and form an insoluble and polymeric film of [BTA-Cu], suppressing the electrochemical corrosion and reaction between perovskite and the Cu electrode. PSCs with BTA/Cu show excellent air stability, retaining 92.8 ± 1.9% of initial efficiency after aging for 2500 hours. In addition, >90% of initial efficiency is retained after 85°C aging for over 1000 hours. PSCs with BTA/Cu also exhibit good operational stability, and 88.6 ± 2.6% of initial efficiency is retained after continuous maximum power point tracking for 1000 hours.

A Strategy to Simplify the Preparation Process of Perovskite Solar Cells by Co-deposition of a Hole-Conductor and a Perovskite Layer

2016 ◽  
Vol 28 (43) ◽  
pp. 9648-9654 ◽  
Author(s):  
Senyun Ye ◽  
Haixia Rao ◽  
Weibo Yan ◽  
Yunlong Li ◽  
Weihai Sun ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Preparation Process ◽  
Perovskite Layer

scholarly journals CuI/Spiro-OMeTAD Double-Layer Hole Transport Layer to Improve Photovoltaic Performance of Perovskite Solar Cells

Coatings ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 978
Author(s):  
Chaoqun Lu ◽  
Weijia Zhang ◽  
Zhaoyi Jiang ◽  
Yulong Zhang ◽  
Cong Ni
Keyword(s):  
Solar Cells ◽  
Double Layer ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Perovskite Layer

The hole transport layer (HTL) is one of the main factors affecting the efficiency and stability of perovskite solar cells (PSCs). However, obtaining HTLs with the desired properties through current preparation techniques remains a challenge. In the present study, we propose a new method which can be used to achieve a double-layer HTL, by inserting a CuI layer between the perovskite layer and Spiro-OMeTAD layer via a solution spin coating process. The CuI layer deposited on the surface of the perovskite film directly covers the rough perovskite surface, covering the surface defects of the perovskite, while a layer of CuI film avoids the defects caused by Spiro-OMetad pinholes. The double-layer HTLs improve roughness and reduce charge recombination of the Spiro-OMeTAD layer, thereby resulting in superior hole extraction capabilities and faster hole mobility. The CuI/Spiro-OMeTAD double-layer HTLs-based devices were prepared in N2 gloveboxes and obtained an optimized PCE (photoelectric conversion efficiency) of 17.44%. Furthermore, their stability was improved due to the barrier effect of the inorganic CuI layer on the entry of air and moisture into the perovskite layer. The results demonstrate that another deposited CuI film is a promising method for realizing high-performance and air-stable PSCs.

Modeling of Abnormal Hysteresis in CsPbBr3 based Perovskite Solar Cells

2021 ◽  
Vol 34 (1) ◽  
pp. 01-08
Author(s):  
B GopalKrishna ◽  
Sanjay Tiwari
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Simulation Study ◽  
Open Circuit Voltage ◽  
Layer Structure ◽  
Short Circuit ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Open Circuit ◽  
Perovskite Layer

Perovskite solar cells are emerging photovoltaic devices with PCE of above 25%. Perovskite are suitable light absorber materials in solar cells with excellent properties like appropriate band gap energy, long carrier lifetime and diffusion length, and high extinction coefficient. Simulation study is an important technique to understand working mechanisms of perovskites solar cells. The study would help develop efficient, stable PSCs experimentally. In this study, modeling of perovskite solar cell was carried out through Setfos software. The optimization of different parameters of layer structure of solar cell would help to achieve maximum light absorption in the perovskite layer of solar cell. Simulation study is based drift-diffusion model to study the different parameters of perovskite solar cell. Hysteresis is one of the factors in the perovskite solar cell which may influence the device performance. The measurement of abnormal hysteresis can be done by current-voltage curve during backward scan during simulation study. In backward scan, the measurement starts from biasing voltage higher than open circuit voltage and sweep to voltage below zero. The numerical simulation used to study the various parameters like open circuit voltage, short circuit current, fill factor, power conversion efficiency and hysteresis. The simulation results would help to understand the photophysics of solar cell physics which would help to fabricate highly efficient and stable perovskite solar cells experimentally.

scholarly journals Effect of UV-Light Treatment on Efficiency of Perovskite Solar Cells (PSCs)

Energies ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1069 ◽  
Author(s):  
Sangmo Kim ◽  
Hoang Van Quy ◽  
Hyung Wook Choi ◽  
Chung Wung Bark
Keyword(s):  
Solar Cells ◽  
Conversion Efficiency ◽  
Uv Light ◽  
Perovskite Solar Cells ◽  
Ultra Violet ◽  
Light Treatment ◽  
Light Sources ◽  
Perovskite Layer ◽  
Solar Conversion ◽  
Solar Conversion Efficiency

We employed ultra-violet (UV) light treatment on the TiO2 layer prior to coating the perovskite layer to improve the solar conversion efficiency of perovskite solar cells (PSCs). A laboratory-made UV treatment system was equipped with various UV light sources (8 W power; maximum wavelengths of 254, 302, and 365 nm). The UV light treatment improved the power conversion efficiency (PCE) while coating the uniformity layer and removing impurities from the surface of cells. After the PSCs were exposed to UV light, their PCE developed approximately 10% efficiency; PBI2 decreased without changing the structure.

Efficient and Stable Perovskite Solar Cells Prepared in Ambient Air Based on Surface-Modified Perovskite Layer

2017 ◽  
Vol 121 (12) ◽  
pp. 6546-6553 ◽  
Author(s):  
Chang Liu ◽  
Wenhui Ding ◽  
Xianyong Zhou ◽  
Jishu Gao ◽  
Chun Cheng ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Ambient Air ◽  
Perovskite Layer ◽  
Surface Modified
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