Performance Evolution of Alkylation Graphene Oxide Reinforcing High-Density Polyethylene

2017 ◽  
Vol 121 (39) ◽  
pp. 21685-21694 ◽  
Author(s):  
Wensheng Gao ◽  
Yue Lu ◽  
Yuanzhi Chao ◽  
Yu Ma ◽  
Bochao Zhu ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
High Density Polyethylene ◽  
High Density

High-density polyethylene/graphene oxide nanocomposites prepared via in situ polymerization: Morphology, thermal, and electrical properties

2018 ◽  
Vol 16 ◽  
pp. 232-241 ◽  
Author(s):  
Antonio Cruz-Aguilar ◽  
Dámaso Navarro-Rodríguez ◽  
Odilia Pérez-Camacho ◽  
Salvador Fernández-Tavizón ◽  
Carlos Alberto Gallardo-Vega ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Electrical Properties ◽  
High Density Polyethylene ◽  
In Situ Polymerization ◽  
High Density ◽  
Thermal And Electrical Properties

Fabrication of fullerene-decorated graphene oxide and its influence on flame retardancy of high density polyethylene

2016 ◽  
Vol 129 ◽  
pp. 123-129 ◽  
Author(s):  
Zhenghong Guo ◽  
Runfeng Ye ◽  
Liping Zhao ◽  
Shiya Ran ◽  
Zhengping Fang ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Flame Retardancy ◽  
High Density Polyethylene ◽  
High Density

scholarly journals Microbeam two-dimensional small-angle X-ray scattering investigating the effects of reduced graphene oxide on local microstructures of high-density polyethylene/reduced graphene oxide nanocomposite bars

2019 ◽  
Vol 6 (2) ◽  
pp. 181866 ◽  
Author(s):  
Guibin Yao ◽  
Tianchen Duan ◽  
Enyi Chi ◽  
Pengran Guo ◽  
Yiguo Li ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Small Angle ◽  
High Density Polyethylene ◽  
High Density ◽  
Two Dimensional ◽  
X Ray ◽  
X Ray Scattering ◽  
Reduced Graphene

It has been reported that the introduction of reduced graphene oxide (RGO) can enhance the crystallization and orientation of high-density polyethylene (HDPE) matrix and thus improve the mechanical properties of HDPE/RGO nanocomposites. In this study, the local microstructures and orientations in different regions of HDPE/RGO bars with varied RGO contents were further explored by two-dimensional small-angle X-ray scattering using a microbeam technique. It is unveiled that the orientation orderings of each position is intensified with increasing RGO amount, and of particular interest is the observation of the slight change of the ordering degrees in diverse zones of HDPE/RGO nanocomposite bars, indicating that RGO imposes a uniform enhancing effect upon HDPE matrix within different areas and consequently induces an effective increase of the mechanical properties of HDPE/RGO nanocomposites.

scholarly journals The influence of epitaxial crystallization on the mechanical properties of a high density polyethylene/reduced graphene oxide nanocomposite injection bar

RSC Advances ◽  
2017 ◽  
Vol 7 (35) ◽  
pp. 21918-21925 ◽  
Author(s):  
Guibin Yao ◽  
Tianchen Duan ◽  
Minfang An ◽  
Haojun Xu ◽  
Feng Tian ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Graphene Oxide ◽  
Injection Molding ◽  
Reduced Graphene Oxide ◽  
High Density Polyethylene ◽  
High Density ◽  
Epitaxial Crystallization ◽  
Reduced Graphene

High density polyethylene (HDPE)/reduced graphene oxide (RGO) nanocomposite bars were prepared by injection molding and the effects of RGO on the HDPE matrix were investigated.

scholarly journals Graphene oxide modification for enhancing high-density polyethylene properties: a comparison between solvent reaction and melt mixing

2018 ◽  
Vol 39 (1) ◽  
pp. 85-93
Author(s):  
Antimo Graziano ◽  
Shaffiq Jaffer ◽  
Mohini Sain
Keyword(s):  
Graphene Oxide ◽  
High Density Polyethylene ◽  
High Performance ◽  
Stress Transfer ◽  
Cost Effective ◽  
Industrial Applications ◽  
High Density ◽  
Strong Interactions ◽  
Melt Mixing ◽  
Functionalized Graphene Oxide

Abstract Graphene oxide (GO) was chemically modified in xylene with dodecyl amine and hydrazine monohydrate to obtain reduced functionalized graphene oxide (RFGO). Composites of high-density polyethylene (HDPE) and GO were made via solvent reaction, whereas both melt mixing and solvent reaction were used for HDPE-RFGO composites for comparison purposes. Elemental and thermal analysis showed the success of GO modification in grafting amine functionalities onto its structure and restoring most of the original graphene C=C bonds. A significant increase in mechanical properties, thermal stability, and crystallization behavior was observed for HDPE-RFGO (solvent) compared with HDPE and HDPE-GO, proving that homogeneous dispersion of RFGO in the polymer matrix and strong interactions between them resulted in facilitated stress transfer, delayed thermal degradation, and more efficient nucleating effect in inducing the crystal growth of HDPE. A comparison of HDPE-RFGO properties enhancement between the melt mixing method and the solvent reaction method showed that, apart from mechanical behavior, the RFGO contribution was the same, suggesting that the optimization of the ecofriendlier approach (melt) could eventually lead to its total use for the mass production of high-performance, cost-effective, and more environmentally friendly graphene-based thermoplastic polyolefin nanocomposites suitable for highly demanding industrial applications.

Sign in / Sign up

Export Citation Format

Share Document