Structures of Bimetallic Copper–Ruthenium Nanoparticles: Incoherent Interface and Surface Active Sites for Catalytic Nitric Oxide Dissociation

2017 ◽  
Vol 121 (1) ◽  
pp. 300-307 ◽  
Author(s):  
Ryoichi Fukuda ◽  
Nozomi Takagi ◽  
Shigeyoshi Sakaki ◽  
Masahiro Ehara
Keyword(s):  
Nitric Oxide ◽  
Active Sites ◽  
Ruthenium Nanoparticles ◽  
Incoherent Interface ◽  
Surface Active

scholarly journals Heterogeneous Photocatalysis and Prospects of TiO2-Based Photocatalytic DeNOxing the Atmospheric Environment

Catalysts ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 553 ◽  
Author(s):  
Nick Serpone
Keyword(s):  
Nitric Oxide ◽  
Metal Oxide ◽  
Nitrogen Dioxide ◽  
Active Sites ◽  
Heterogeneous Photocatalysis ◽  
Atmospheric Environment ◽  
Laboratory Setting ◽  
Noise Barriers ◽  
Surface Active ◽  
The Many

This article reviews the efforts of the last two decades to deNOxify the atmospheric environment with TiO2-based photocatalytic materials supported on various cementitious-like substrates. Prior to undertaking this important aspect of applied photocatalysis with metal-oxide emiconductor photocatalysts, however, it is pertinent to describe and understand the fundamentals of Heterogeneous Photocatalysis. The many attempts done in a laboratory setting to degrade (deNOxify) the major components that make up the NOx, namely nitric oxide (NO) and nitrogen dioxide (NO2), but most importantly the efforts expended in deNOxifying the real environment upon depositing titania-based coatings on various model and authentic infrastructures, such as urban roads, highway noise barriers, tunnels, and building external walls among others, are examined. Both laboratory and outdoor experimentations have been performed toward NOx being oxidized to form nitrates (NO3−) that remain adsorbed on the TiO2-based photocatalytic surfaces (except in tunnels—indoor walls) but get subsequently dislodged by rain or by periodic washings of the infrastructures. However, no serious considerations have been given to the possible conversion of NOx via photocatalytic reduction back to N2 and O2 gases that would restore the atmospheric environment, as the adsorbed nitrates block the surface-active sites of the photocatalyst and when washed-off ultimately cause unduly damages to the environment.

Role of the Structure and Electronic Properties of Fe2O3-MoO3 Catalyst on the Dehydration of Isopropyl Alcohol

1993 ◽  
Vol 58 (7) ◽  
pp. 1591-1599 ◽  
Author(s):  
Abd El-Aziz A. Said
Keyword(s):  
Active Sites ◽  
Isopropyl Alcohol ◽  
Oxide Catalyst ◽  
Flow System ◽  
Charge Carriers ◽  
X Ray Diffraction ◽  
X Ray ◽  
Catalyst Composition ◽  
Surface Active

Molybdenum oxide catalyst doped or mixed with (1 - 50) mole % Fe3+ ions were prepared. The structure of the original samples and the samples calcined at 400 °C were characterized using DTA, X-ray diffraction and IR spectra. Measurements of the electrical conductivity of calcined samples with and without isopropyl alcohol revealed that the conductance increases on increasing the content of Fe3+ ions up to 50 mole %. The activation energies of charge carriers were determined in presence and absence of the alcohol. The catalytic dehydration of isopropyl alcohol was carried out at 250 °C using a flow system. The results obtained showed that the doped or mixed catalysts are active and selective towards propene formation. However, the catalyst containing 40 mole % Fe3+ ions exhibited the highest activity and selectivity. Correlations were attempted to the catalyst composition with their electronic and catalytic properties. Probable mechanism for the dehydration process is proposed in terms of surface active sites.

Cathodic Corrosion Activated Fe-based Nanoglass as Highly-Active and -Stable Oxygen Evolution Catalyst for Water Splitting

2021 ◽  
Author(s):  
Kaiyao Wu ◽  
Fei Chu ◽  
Yuying Meng ◽  
Kaveh Edalati ◽  
Qingsheng Gao ◽  
...  
Keyword(s):  
Water Splitting ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Amorphous Alloys ◽  
Precious Metal ◽  
Active Sites ◽  
Metal Free ◽  
Highly Active ◽  
Stable Oxygen ◽  
Surface Active

Transition metal-based amorphous alloys have attracted increasing attention as precious-metal-free electrocatalysts for oxygen evolution reaction (OER) of water splitting due to their high macro-conductivity and abundant surface active sites. However,...

scholarly journals LPS-Induced Formation of Immunoproteasomes: TNF-α and Nitric Oxide Production are Regulated by Altered Composition of Proteasome-Active Sites

2011 ◽  
Vol 60 (1-2) ◽  
pp. 77-88 ◽  
Author(s):  
Julia Reis ◽  
Xiu Qin Guan ◽  
Alexei F. Kisselev ◽  
Christopher J. Papasian ◽  
Asaf A. Qureshi ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Active Sites ◽  
Nitric Oxide Production ◽  
Oxide Production ◽  
Tnf Α

scholarly journals Prepare a catalyst consist of rare earth minerals to denitrate via NH3-SCR

2020 ◽  
Vol 9 (1) ◽  
pp. 191-202
Author(s):  
Jian Wang ◽  
Chao Zhu ◽  
Baowei Li ◽  
Zhijun Gong ◽  
Zhaolei Meng ◽  
...  
Keyword(s):  
Rare Earth ◽  
Active Sites ◽  
Nh3 Scr ◽  
Composite Oxides ◽  
Rare Earth Minerals ◽  
Denitrification Activity ◽  
Denitrification Reactor ◽  
Surface Active ◽  
Rare Earth Tailings ◽  
Treatment Step

AbstractTo research the roles of rare earth minerals in denitrification via the NH3-SCR, a mixture was made by certain ratio of rare earth concentrates and rare earth tailings, then treated by microwave roasting, and acids and bases to form a denitrification catalyst. The mineral phase structure and surface morphology of the catalyst were characterized by XRD, BET, SEM and EDS. The surface properties of the catalyst were tested by TPD and XPS methods, and the denitrification activity of the catalyst was evaluated in a denitrification reactor. The results showed that the denitrification efficiency increased up to 82% with complete processing. XRD, BET, SEM, and EDS spectrum analysis stated that the treated minerals contained cerium oxides and Fe−Ce composite oxides. The surface of the modified minerals became rough and porous, the surface area increased, and the surface-active sites were exposed. The results of NH3-TPD and NO-TPD showed that the catalyst surface could gradually adsorb more NH3 and NO after each step. XPS analysis indicated that there were more Ce3+, Fe2+, and lattice oxygen in rare earth minerals catalyst after each treatment step.

Enhanced photocatalytic H2 evolution over micro-SiC by coupling with CdS under visible light irradiation

2014 ◽  
Vol 2 (18) ◽  
pp. 6296-6300 ◽  
Author(s):  
Yuan Peng ◽  
Zhongnan Guo ◽  
Jingjing Yang ◽  
Da Wang ◽  
Wenxia Yuan
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Active Sites ◽  
Fine Tuning ◽  
Surface Activation ◽  
H2 Evolution ◽  
Effective Surface ◽  
Suitable Amount ◽  
Surface Active ◽  
Photocatalytic H2 Evolution

Fine-tuning surface activation of the micro-SiC catalyst via hybridizing a suitable amount of CdS to obtain effective surface active sites.

3D self-assembled VS4 microspheres with high pseudocapacitance as highly efficient anodes for Na-ion batteries

Nanoscale ◽  
2018 ◽  
Vol 10 (46) ◽  
pp. 21671-21680 ◽  
Author(s):  
Wenbin Li ◽  
Jianfeng Huang ◽  
Liangliang Feng ◽  
Liyun Cao ◽  
Shuwei He
Keyword(s):  
Active Sites ◽  
High Capacity ◽  
Rate Capability ◽  
High Rate ◽  
High Rate Capability ◽  
Highly Efficient ◽  
Pseudocapacitive Behavior ◽  
Surface Active ◽  
Self Assembled ◽  
Cycling Life

The decreasing crystallinity of VS4 microspheres greatly increases the surface active sites, and then promotes the pseudocapacitive behavior, and finally leads to the high capacity, long cycling life and high rate capability.

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