A Synergistic Effect in a Composite Cathode Consisting of Spinel and Layered Structures To Increase the Electrochemical Performance for Li-Ion Batteries

2016 ◽  
Vol 120 (45) ◽  
pp. 25647-25656 ◽  
Author(s):  
Zu-Wei Yin ◽  
Zhen-Guo Wu ◽  
Ya-Ping Deng ◽  
Tao Zhang ◽  
Hang Su ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Electrochemical Performance ◽  
Composite Cathode ◽  
Layered Structures ◽  
Li Ion Batteries ◽  
Li Ion

Electrochemical performance of in situ LiFePO4 modified by N-doped graphene for Li-ion batteries

2021 ◽  
Author(s):  
Gui-Yang Luo ◽  
Yi-Jing Gu ◽  
Yuan Liu ◽  
Zi-Liang Chen ◽  
Yong-lin Huo ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Li Ion Batteries ◽  
Doped Graphene ◽  
Li Ion

Probing the Effect of High Energy Ball Milling on the Structure and Properties of LiNi1/3Mn1/3Co1/3O2 Cathodes for Li-Ion Batteries

2016 ◽  
Vol 13 (3) ◽  
Author(s):  
Malcolm Stein ◽  
Chien-Fan Chen ◽  
Matthew Mullings ◽  
David Jaime ◽  
Audrey Zaleski ◽  
...  
Keyword(s):  
Particle Size ◽  
Electrochemical Performance ◽  
Crystallite Size ◽  
Ball Milling ◽  
Lithium Ion ◽  
High Energy ◽  
Li Ion Batteries ◽  
Structure And Properties ◽  
Transfer Resistance ◽  
Li Ion

Particle size plays an important role in the electrochemical performance of cathodes for lithium-ion (Li-ion) batteries. High energy planetary ball milling of LiNi1/3Mn1/3Co1/3O2 (NMC) cathode materials was investigated as a route to reduce the particle size and improve the electrochemical performance. The effect of ball milling times, milling speeds, and composition on the structure and properties of NMC cathodes was determined. X-ray diffraction analysis showed that ball milling decreased primary particle (crystallite) size by up to 29%, and the crystallite size was correlated with the milling time and milling speed. Using relatively mild milling conditions that provided an intermediate crystallite size, cathodes with higher capacities, improved rate capabilities, and improved capacity retention were obtained within 14 μm-thick electrode configurations. High milling speeds and long milling times not only resulted in smaller crystallite sizes but also lowered electrochemical performance. Beyond reduction in crystallite size, ball milling was found to increase the interfacial charge transfer resistance, lower the electrical conductivity, and produce aggregates that influenced performance. Computations support that electrolyte diffusivity within the cathode and film thickness play a significant role in the electrode performance. This study shows that cathodes with improved performance are obtained through use of mild ball milling conditions and appropriately designed electrodes that optimize the multiple transport phenomena involved in electrochemical charge storage materials.

Enhanced electrochemical properties of a natural graphite anode using a promising crosslinked ionomer binder in Li-ion batteries

2017 ◽  
Vol 41 (20) ◽  
pp. 11759-11765 ◽  
Author(s):  
Shu Huang ◽  
Jianguo Ren ◽  
Rong Liu ◽  
Min Yue ◽  
Youyuan Huang ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Electrochemical Performance ◽  
Electrochemical Properties ◽  
Graphite Anode ◽  
Li Ion Batteries ◽  
Natural Graphite ◽  
Graphite Anodes ◽  
Li Ion ◽  
Enhanced Electrochemical Performance ◽  
Natural Graphite Anode

A crosslinked ionomer binder was prepared and used in graphite anodes for Li-ion batteries. These binder-based anodes exhibit enhanced electrochemical performance due to the formation of hydrogen bonds and the release of conductive Li+.

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