The Electronic Structure and Photoinduced Electron Transfer Rate of CdSe Quantum Dots on Single Crystal Rutile TiO2: Dependence on the Crystal Orientation of the Substrate

2016 ◽  
Vol 120 (4) ◽  
pp. 2047-2057 ◽  
Author(s):  
Taro Toyoda ◽  
Witoon Yindeesuk ◽  
Keita Kamiyama ◽  
Kenji Katayama ◽  
Hisayoshi Kobayashi ◽  
...  
Author(s):  
MOHAMED E. EL-KHOULY ◽  
MAMORU FUJITSUKA ◽  
OSAMU ITO

Photoinduced electron-transfer processes between C 60 or C 70 and zinc octaethylporphyrin ( ZnOEP ) have been studied in polar solvents with the nanosecond laser flash photolysis method, observing the transient absorption spectra in the visible and near-IR regions. By the predominant excitation of ZnOEP with 532 nm laser light the transient absorption bands of 3 ZnOEP * decayed, accompanied by the appearance of the transient absorption bands of [Formula: see text] and [Formula: see text]. By the predominant excitation of C 60 and C 70 with 610 nm laser light the decays of [Formula: see text] and [Formula: see text] were observed, accompanied by the appearance of [Formula: see text] and [Formula: see text]. The electron transfer rate constants (k et ) and the quantum yields (Φ et ) of [Formula: see text] and [Formula: see text] formation via 3 ZnOEP * and [Formula: see text] or [Formula: see text] have been evaluated. These values increase with the solvent polarity; in polar benzonitrile these values are higher than for other porphyrins such as zinc tetraphenylporphyrin. The back electron transfer rate constants were evaluated from the decays of [Formula: see text] and [Formula: see text], which also show a solvent polarity dependence.


2018 ◽  
Vol 122 (28) ◽  
pp. 15819-15825 ◽  
Author(s):  
Ayan Bhattacharyya ◽  
Soumalya Mukherjee ◽  
Anju Chadha ◽  
Edamana Prasad

2007 ◽  
Vol 111 (20) ◽  
pp. 5694-5699 ◽  
Author(s):  
Fumio Tanaka ◽  
Haik Chosrowjan ◽  
Seiji Taniguchi ◽  
Noboru Mataga ◽  
Kyosuke Sato ◽  
...  

2007 ◽  
Vol 111 (26) ◽  
pp. 9008-9011 ◽  
Author(s):  
Hiromasa Nishikiori ◽  
Wei Qian ◽  
Mostafa A. El-Sayed ◽  
Nobuaki Tanaka ◽  
Tsuneo Fujii

Nanoscale ◽  
2014 ◽  
Vol 6 (12) ◽  
pp. 7004-7011 ◽  
Author(s):  
H. Zhao ◽  
Z. Fan ◽  
H. Liang ◽  
G. S. Selopal ◽  
B. A. Gonfa ◽  
...  

We investigate the photoelectron transfer rate from PbS@CdS core@shell QDs to wide bandgap mesoporous films using photoluminescence lifetime spectroscopy, which is strongly size, shell thickness and oxide dependent.


2016 ◽  
Vol 120 (30) ◽  
pp. 16367-16376 ◽  
Author(s):  
Taro Toyoda ◽  
Witoon Yindeesuk ◽  
Keita Kamiyama ◽  
Shuzi Hayase ◽  
Qing Shen

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