scholarly journals Predicting Methane Storage in Open-Metal-Site Metal–Organic Frameworks

2015 ◽  
Vol 119 (24) ◽  
pp. 13451-13458 ◽  
Author(s):  
Hyun Seung Koh ◽  
Malay Kumar Rana ◽  
Antek G. Wong-Foy ◽  
Donald J. Siegel
Keyword(s):  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Metal Site ◽  
Metal Organic

scholarly journals Unravelling thermal stress due to thermal expansion mismatch in metal–organic frameworks for methane storage

2021 ◽  
Author(s):  
Jelle Wieme ◽  
Veronique Van Speybroeck
Keyword(s):  
Thermal Expansion ◽  
Thermal Stress ◽  
Pressure Coefficient ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Thermal Expansion Mismatch ◽  
Thermal Pressure ◽  
Temperature Changes ◽  
Metal Organic ◽  
The Impact

Thermal stress is present in metal–organic frameworks undergoing temperature changes during adsorption and desorption. We computed the thermal pressure coefficient as a proxy for this phenomenon and discuss the impact of thermal expansion mismatch.

Methane storage in flexible metal–organic frameworks with intrinsic thermal management

Nature ◽  
2015 ◽  
Vol 527 (7578) ◽  
pp. 357-361 ◽  
Author(s):  
Jarad A. Mason ◽  
Julia Oktawiec ◽  
Mercedes K. Taylor ◽  
Matthew R. Hudson ◽  
Julien Rodriguez ◽  
...  
Keyword(s):  
Thermal Management ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Metal Organic ◽  
Flexible Metal

High Methane Storage Working Capacity in Metal–Organic Frameworks with Acrylate Links

2016 ◽  
Vol 138 (32) ◽  
pp. 10244-10251 ◽  
Author(s):  
Juncong Jiang ◽  
Hiroyasu Furukawa ◽  
Yue-Biao Zhang ◽  
Omar M. Yaghi
Keyword(s):  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic

scholarly journals Tailoring the pore geometry and chemistry in microporous metal–organic frameworks for high methane storage working capacity

2019 ◽  
Vol 55 (76) ◽  
pp. 11402-11405 ◽  
Author(s):  
Kai Shao ◽  
Jiyan Pei ◽  
Jia-Xin Wang ◽  
Yu Yang ◽  
Yuanjing Cui ◽  
...  
Keyword(s):  
Pore Size ◽  
Metal Organic Frameworks ◽  
Pore Geometry ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic

We realized that engineering the pore size/geometry and chemistry in a series of MOFs can optimize the volumetric methane storage working capacity.

Ultrafast assembly of swordlike Cu3(1,3,5-benzenetricarboxylate)n metal–organic framework crystals with exposed active metal sites

2020 ◽  
Vol 5 (7) ◽  
pp. 1050-1057 ◽  
Author(s):  
Heba Ahmed ◽  
Xinci Yang ◽  
Yemima Ehrnst ◽  
Ninweh N. Jeorje ◽  
Susan Marqus ◽  
...  
Keyword(s):  
Aspect Ratio ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Large Aspect Ratio ◽  
Metal Site ◽  
Site Density ◽  
Active Metal ◽  
Metal Organic ◽  
Enhanced Conductivity ◽  
Organic Framework

A new acoustomicrofluidic method for synthesizing copper-based metal–organic frameworks is shown to yield novel large aspect ratio elongated crystal morphologies with high active metal site density on their surfaces, leading to enhanced conductivity.

Engineering of Pore Geometry for Ultrahigh Capacity Methane Storage in Mesoporous Metal–Organic Frameworks

2017 ◽  
Vol 139 (38) ◽  
pp. 13300-13303 ◽  
Author(s):  
Cong-Cong Liang ◽  
Zhao-Lin Shi ◽  
Chun-Ting He ◽  
Jing Tan ◽  
Hu-Die Zhou ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Pore Geometry ◽  
Methane Storage ◽  
Metal Organic ◽  
Mesoporous Metal
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