Cooperative Assembly of Metal Nitrate and Citric Acid with Block Copolymers: Role of Carbonate Conversion Temperature on the Mesostructure of Ordered Porous Oxides

2015 ◽  
Vol 119 (22) ◽  
pp. 12138-12148 ◽  
Author(s):  
Michael C. Burroughs ◽  
Sarang M. Bhaway ◽  
Pattarasai Tangvijitsakul ◽  
Kevin A. Cavicchi ◽  
Mark D. Soucek ◽  
...  
Keyword(s):  
Citric Acid ◽  
Block Copolymers ◽  
Metal Nitrate ◽  
Porous Oxides ◽  
Cooperative Assembly ◽  
Ordered Porous ◽  
Conversion Temperature

scholarly journals Role of CA-EDTA on the Synthesizing Process of Cerate-Zirconate Ceramics Electrolyte

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Nur Athirah Abdullah ◽  
Sharizal Hasan ◽  
Nafisah Osman
Keyword(s):  
Thermal Decomposition ◽  
Citric Acid ◽  
Chelating Agents ◽  
Sol Gel ◽  
Decomposition Temperature ◽  
Metal Nitrate ◽  
Molar Ratio ◽  
Calcination Temperatures ◽  
Decomposition Behaviour

The role of a combination between citric acid (CA) and ethylenediaminetetra acetic acid (EDTA) as chelating agents in preparation of BaCe0.54Zr0.36Y0.1O2.95powder by a modified sol-gel method is reported. The precursor solutions were prepared from metal nitrate salts (M+), chelating agents (C), and ethylene glycol (EG) at molar ratio of M+ : C : EG = 3 : 2 : 3. Chemical and phase transformation of samples during thermal decomposition were analyzed by thermogravimetric analysis (TGA) and Fourier transform infrared (FTIR) spectroscopy. TGA results show that the sample prepared by a combination of CA-EDTA exhibited the lowest thermal decomposition temperature,Ttdsince there was no significant weight loss after 750°C. After calcined at 1100°C, the carbonates residue remained in the samples as proven by FTIR results. It was found that the used combination of CA-EDTA acts as a better combustion reagent to increase the reaction rate and influence the thermal decomposition behaviour compared to a single citric acid and EDTA, respectively. Apparently, calcination temperatures above 1100°C are needed to produce a pure perovskitic BaCe0.54Zr0.36Y0.1O2.95.

scholarly journals Phytoextraction of Lead Using a Hedge Plant [Alternanthera bettzickiana (Regel) G. Nicholson]: Physiological and Biochemical Alterations through Bioresource Management

2021 ◽  
Vol 13 (9) ◽  
pp. 5074
Author(s):  
Urooj Kanwal ◽  
Muhammad Ibrahim ◽  
Farhat Abbas ◽  
Muhammad Yamin ◽  
Fariha Jabeen ◽  
...  
Keyword(s):  
Citric Acid ◽  
Growth Parameters ◽  
Cost Effective ◽  
Dry Weight ◽  
Citric Acid Concentration ◽  
Biochemical Alterations ◽  
Biomass Plant ◽  
Environmentally Friendly Approach ◽  
Pb Concentration

Phytoremediation is a cost-effective and environmentally friendly approach that can be used for the remediation of metals in polluted soil. This study used a hedge plant–calico (Alternanthera bettzickiana (Regel) G. Nicholson) to determine the role of citric acid in lead (Pb) phytoremediation by exposing it to different concentrations of Pb (0, 200, 500, and 1000 mg kg−1) as well as in a combination with citric acid concentration (0, 250, 500 µM). The analysis of variance was applied on results for significant effects of the independent variables on the dependent variables using SPSS (ver10). According to the results, maximum Pb concentration was measured in the upper parts of the plant. An increase in dry weight biomass, plant growth parameters, and photosynthetic contents was observed with the increase of Pb application (200 mg kg−1) in soil while a reduced growth was experienced at higher Pb concentration (1000 mg kg−1). The antioxidant enzymatic activities like superoxide dismutase (SOD) and peroxidase (POD) were enhanced under lower Pb concentration (200, 500 mg kg−1), whereas the reduction occurred at greater metal concentration Pb (1000 mg kg−1). There was a usual reduction in electrolyte leakage (EL) at lower Pb concentration (200, 500 mg kg−1), whereas EL increased at maximum Pb concentration (1000 mg kg−1). We concluded that this hedge plant, A. Bettzickiana, has the greater ability to remediate polluted soils aided with citric acid application.

Dual Role of Citric Acid as a Binding Inhibitor of Anionic Surfactant with Bivalent Cations and Co-Surfactant on Bio-Surfactant EOR

2018 ◽  
Author(s):  
Nao Miyazaki ◽  
Yuichi Sugai ◽  
Kyuro Sasaki ◽  
Yoshifumi Okamoto ◽  
Chencan Ouyang
Keyword(s):  
Citric Acid ◽  
Anionic Surfactant ◽  
Dual Role ◽  
Bivalent Cations

Insights about urinary hippuric and citric acid as biomarkers of fruit and vegetable intake in patients with kidney stones: The role of age and sex

Nutrition ◽  
2019 ◽  
Vol 59 ◽  
pp. 83-89 ◽  
Author(s):  
Angela Guerra ◽  
Andrea Ticinesi ◽  
Franca Allegri ◽  
Antonio Nouvenne ◽  
Beatrice Prati ◽  
...  
Keyword(s):  
Citric Acid ◽  
Kidney Stones ◽  
Vegetable Intake ◽  
Fruit And Vegetable Intake ◽  
Fruit And Vegetable ◽  
Age And Sex

Formation of hybrid colloids by suspension polycondensation in the presence of hydrophilic block copolymers

2002 ◽  
Vol 726 ◽  
Author(s):  
Corine Gerardin ◽  
Valérie Buissette ◽  
François Gaudemet ◽  
Olivier Anthony ◽  
Nicolas Sanson ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Colloidal Suspensions ◽  
Surface Charges ◽  
Inorganic Particles ◽  
Hydrous Oxides ◽  
Stabilization Phase ◽  
Metal Ratio ◽  
Forced Hydrolysis ◽  
Hydrolysis Of

AbstractDouble hydrophilic block copolymers were used to control the growth of inorganic particles and directly prepare hybrid colloidal suspensions. Colloids of metal hydrous oxides were obtained by forced hydrolysis of metal ions in presence of the copolymers. The block copolymers contain a metal-complexing polyelectrolyte block and a stabilizing neutral block. The role of the first block is to ensure a controlled growth of the inorganic phase, while simultaneously, the second block ensures the colloidal stabilization. Phase diagrams presenting the conditions under which precipitation is inhibited are established. The nanoparticles are then characterized in terms of sizes, morphologies and surface charges. The main parameters controlling the size were identified: the copolymer-to-metal ratio and the metal prehydrolysis ratio. The synthesis steps were characterized. First, a key step of induced micellization of the hydrophilic copolymers leads to hybrid core-shell assemblies. The second step consists in mineralization of the micellar core. The suspension polycondensation leads to hairy particles whose morphologies depend on the nature of the metal and on synthesis parameters.

scholarly journals Role of dissimilar interfaces in thin films of cylinder-forming block copolymers

2004 ◽  
Vol 120 (2) ◽  
pp. 1127-1137 ◽  
Author(s):  
K. S. Lyakhova ◽  
G. J. A. Sevink ◽  
A. V. Zvelindovsky ◽  
A. Horvat ◽  
R. Magerle
Keyword(s):  
Thin Films ◽  
Block Copolymers

scholarly journals Study on printing wastewater treatment by decomposition reaction H2O2 catalyzed of complex between ion Ni2+ and citric acid

2020 ◽  
Vol 9 (4) ◽  
pp. 106-110
Author(s):  
Tue Nguyen Ngoc ◽  
Nghia Nguyen Trong ◽  
Thuong Nghiem Thi ◽  
Quang Tran Thuong ◽  
Trung Nguyen Duc
Keyword(s):  
Wastewater Treatment ◽  
Citric Acid ◽  
Industrial Wastewater ◽  
Room Temperature ◽  
Organic Pollutant ◽  
Decomposition Reaction ◽  
Efficient Treatment ◽  
Catalytic Role ◽  
Printing Processes

In this article, the results of the research on organic pollutant treatment in the wastewater of printing processes on fabric by H2O2 under the catalytic role of the complex between ion Ni2+ and Citric acid (H4L) were presented. The condition of pH, H4L/Ni2+, H2O2, Ni2+ concentration has been explored to get the optimal conditions for improving COD efficient treatment. The results provide the solutions of the homogeneous complex  catalysts in the industrial wastewater treatment at room temperature and atmosphere. 

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