Calculations of Hydrogen Associative Desorption on Mono- and Bimetallic Catalysts

2021 ◽  
Author(s):  
Huiling Zheng ◽  
Hao Li ◽  
Weiyu Song ◽  
Zhen Zhao ◽  
Graeme Henkelman
Keyword(s):  
Bimetallic Catalysts

Structure and composition of metal particles in Pt-Sn/Al2O3 bimetallic catalysts

1990 ◽  
Vol 48 (4) ◽  
pp. 278-279
Author(s):  
A. Sachdev ◽  
J. Schwank
Keyword(s):  
Bimetallic Catalysts ◽  
Bimetallic Catalyst ◽  
Size Structure ◽  
High Surface ◽  
High Surface Area ◽  
Metal Particles ◽  
Alloy Formation ◽  
Particle Size Range ◽  
Oxide Supports ◽  
Petroleum Fractions

Platinum - tin bimetallic catalysts have been primarily utilized in the chemical industry in the catalytic reforming of petroleum fractions. In this process the naphtha feedstock is converted to hydrocarbons with higher octane numbers and high anti-knock qualities. Most of these catalysts contain small metal particles or crystallites supported on high surface area insulating oxide supports. The determination of the structure and composition of these particles is crucial to the understanding of the catalytic behavior. In a bimetallic catalyst it is important to know how the two metals are distributed within the particle size range and in what way the addition of a second metal affects the size, structure and composition of the metal particles. An added complication in the Pt-Sn system is the possibility of alloy formation between the two elements for all atomic ratios.

Nb2C MXene assisted CoNi bimetallic catalysts for hydrogenolysis of aromatic ethers

2021 ◽  
Author(s):  
Sen-Wang Wang ◽  
Zhen-Hong He ◽  
Jian-Gang Chen ◽  
Kuan Wang ◽  
Zhong-Yu Wang ◽  
...  
Keyword(s):  
Bimetallic Catalysts ◽  
Precious Metal ◽  
Renewable Biomass ◽  
Biomass Resources

Hydrogenolysis of biomass-derived lignin sources is highly important for the conversion of renewable biomass resources to biofuels. However, lots of developed catalysts suffer from the drawbacks of expensive precious metal...

scholarly journals High-throughput computational-experimental screening protocol for the discovery of bimetallic catalysts

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Byung Chul Yeo ◽  
Hyunji Nam ◽  
Hyobin Nam ◽  
Min-Cheol Kim ◽  
Hong Woo Lee ◽  
...  
Keyword(s):  
High Throughput ◽  
Bimetallic Catalysts ◽  
High Throughput Screening ◽  
Direct Synthesis ◽  
Catalytic Performance ◽  
Platinum Group Metals ◽  
Pt Catalyst ◽  
Electronic Density ◽  
Bimetallic Alloy ◽  
Screening Protocol

AbstractTo accelerate the discovery of materials through computations and experiments, a well-established protocol closely bridging these methods is required. We introduce a high-throughput screening protocol for the discovery of bimetallic catalysts that replace palladium (Pd), where the similarities in the electronic density of states patterns were employed as a screening descriptor. Using first-principles calculations, we screened 4350 bimetallic alloy structures and proposed eight candidates expected to have catalytic performance comparable to that of Pd. Our experiments demonstrate that four bimetallic catalysts indeed exhibit catalytic properties comparable to those of Pd. Moreover, we discover a bimetallic (Ni-Pt) catalyst that has not yet been reported for H2O2 direct synthesis. In particular, Ni61Pt39 outperforms the prototypical Pd catalyst for the chemical reaction and exhibits a 9.5-fold enhancement in cost-normalized productivity. This protocol provides an opportunity for the catalyst discovery for the replacement or reduction in the use of the platinum-group metals.

Methane Activation on Bimetallic Catalysts: Properties and Functions of Surface Ni−Ag Alloy

ChemCatChem ◽  
2019 ◽  
Vol 11 (15) ◽  
pp. 3401-3412 ◽  
Author(s):  
Anh Hoang Dam ◽  
Hongmin Wang ◽  
Roya Dehghan‐Niri ◽  
Xiaofeng Yu ◽  
John C. Walmsley ◽  
...  
Keyword(s):  
Bimetallic Catalysts ◽  
Methane Activation

scholarly journals Combined Macroscopic, Nanoscopic, and Atomic-Scale Characterization of Gold-Ruthenium Bimetallic Catalysts for Octanol Oxidation

2016 ◽  
Vol 33 (7) ◽  
pp. 419-437 ◽  
Author(s):  
Lidia E. Chinchilla ◽  
Carol Olmos ◽  
Mert Kurttepeli ◽  
Sara Bals ◽  
Gustaaf Van Tendeloo ◽  
...  
Keyword(s):  
Bimetallic Catalysts ◽  
Atomic Scale ◽  
Scale Characterization
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