Charge Transport in MAPbI3 Pellets across the Tetragonal-to-Cubic Phase Transition: The Role of Grain Boundaries from Structural, Electrical, and Optical Characterizations

2020 ◽  
Vol 124 (20) ◽  
pp. 10793-10803 ◽  
Author(s):  
G. Sombrio ◽  
Z. Zhang ◽  
A. Bonadio ◽  
L. S. de Oliveira ◽  
T. B. de Queiroz ◽  
...  
Keyword(s):  
Phase Transition ◽  
Charge Transport ◽  
Grain Boundaries ◽  
Cubic Phase

scholarly journals The Role of Chloride Incorporation in Lead-Free 2D Perovskite (BA)2 SnI4 : Morphology, Photoluminescence, Phase Transition, and Charge Transport

2019 ◽  
Vol 6 (5) ◽  
pp. 1802019 ◽  
Author(s):  
Jun Wang ◽  
Hongzhi Shen ◽  
Wancai Li ◽  
Shuai Wang ◽  
Junze Li ◽  
...  
Keyword(s):  
Phase Transition ◽  
Charge Transport ◽  
Lead Free

scholarly journals Assessing the role of plasma-engineered acceptor-like intra- and inter-grain boundaries of heterogeneous WS2–WO3 nanosheets for photocurrent characteristics

2020 ◽  
Vol 2 (6) ◽  
pp. 2276-2283
Author(s):  
Gopika Gopakumar ◽  
Shantikumar V. Nair ◽  
Mariyappan Shanmugam
Keyword(s):  
Charge Transport ◽  
Plasma Treatment ◽  
Grain Boundaries ◽  
Transport Kinetics

Acceptor-like intra-/inter-grain boundaries in heterogeneous WS2–WO3 impede its charge transport kinetics, and can be engineered via plasma treatment.

Elucidation of block boundaries as the dissolution channels in hydrated cement

1978 ◽  
Vol 36 (1) ◽  
pp. 484-485
Author(s):  
N.V. Belov ◽  
U.I. Papiashwili ◽  
B.E. Yudovich
Keyword(s):  
Liquid Phase ◽  
Grain Boundaries ◽  
Benzoyl Peroxide ◽  
Phase Contrast ◽  
Active Role ◽  
Point Of View ◽  
Hardened Cement ◽  
Hydrated Cement ◽  
Hardened Cement Paste

It has been almost universally adopted that dissolution of solids proceeds with development of uniform, continuous frontiers of reaction.However this point of view is doubtful / 1 /. E.g. we have proved the active role of the block (grain) boundaries in the main phases of cement, these boundaries being the areas of hydrate phases' nucleation / 2 /. It has brought to the supposition that the dissolution frontier of cement particles in water is discrete. It seems also probable that the dissolution proceeds through the channels, which serve both for the liquid phase movement and for the drainage of the incongruant solution products. These channels can be appeared along the block boundaries.In order to demonsrate it, we have offered the method of phase-contrast impregnation of the hardened cement paste with the solution of methyl metacrylahe and benzoyl peroxide. The viscosity of this solution is equal to that of water.

Carbide precipitation and chromium depletion on coherent twin boundaries in deformed 304 stainless steels

1992 ◽  
Vol 50 (2) ◽  
pp. 1216-1217
Author(s):  
A.H. Advani ◽  
L.E. Murr ◽  
D.J. Matlock ◽  
W.W. Fisher ◽  
P.M. Tarin ◽  
...  
Keyword(s):  
Grain Boundaries ◽  
Stainless Steels ◽  
Interfacial Free Energy ◽  
Carbide Precipitation ◽  
Twin Boundaries ◽  
Invariant Structure ◽  
Heat Treated ◽  
Constant Structure ◽  
Cr Depletion

Coherent annealing-twin boundaries are constant structure and energy interfaces with an average interfacial free energy of ∼19mJ/m2 versus ∼210 and ∼835mJ/m2 for incoherent twins and “regular” grain boundaries respectively in 304 stainless steels (SS). Due to their low energy, coherent twins form carbides about a factor of 100 slower than grain boundaries, and limited work has also shown differences in Cr-depletion (sensitization) between twin versus grain boundaries. Plastic deformation, may, however, alter the kinetics and thermodynamics of twin-sensitization which is not well understood. The objective of this work was to understand the mechanisms of carbide precipitation and Cr-depletion on coherent twin boundaries in deformed SS. The research is directed toward using this invariant structure and energy interface to understand and model the role of interfacial characteristics on deformation-induced sensitization in SS. Carbides and Cr-depletion were examined on a 20%-strain, 0.051%C-304SS, heat treated to 625°C-4.5h, as described elsewhere.

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