Unexpected Solute Occupancy and Anisotropic Polarizability in Lewis Basic Solutions

2019 ◽  
Vol 123 (40) ◽  
pp. 8512-8518 ◽  
Author(s):  
Siyan Gao ◽  
Yongli Huang ◽  
Xi Zhang ◽  
Chang Q. Sun
Keyword(s):  
Anisotropic Polarizability ◽  
Basic Solutions

Concept and principles of building an integrated system of management of activities of regional gas supply system entities Kaliningrad region

2019 ◽  
pp. 64-72
Author(s):  
G.G. Arunyants
Keyword(s):  
Control System ◽  
Natural Gas ◽  
Supply System ◽  
Integrated System ◽  
Software Complex ◽  
Geographically Distributed ◽  
Basic Solutions ◽  
Kaliningrad Region ◽  
And Control ◽  
Gas Supply

The results of analysis of problems of regulation of gas supply complex of Kaliningrad region and main ways to increase its efficiency, as well as basic solutions for creation of a software complex Т-GAZ-2 automated calculation of natural gas tariffs for ACS of gas supply system subjects, geographically distributed and information connected to the regional automated information and control system (RAIS).

Basic Solutions to Carbon/Carbon Oxidation: Science and Technology

1998 ◽  
Author(s):  
Ian R. Harrison ◽  
T-C. Chung ◽  
Carlo Pantano ◽  
Ljubisa Radovic ◽  
Peter Thrower
Keyword(s):  
Science And Technology ◽  
Carbon Oxidation ◽  
Basic Solutions

Viscosity of Diluted Aqueous K2CO3/KHCO3 Solutions

1992 ◽  
Vol 57 (9) ◽  
pp. 1879-1887 ◽  
Author(s):  
Zdeněk Palatý
Keyword(s):  
Dynamic Viscosity ◽  
Correlation Equation ◽  
Viscosity Data ◽  
Electrolyte Mixtures ◽  
Interaction Coefficients ◽  
Basic Solutions ◽  
Good Agreement

The applicability of the equation derived for calculating the dynamic viscosity of ternary non-electrolyte mixtures, to the correlation of viscosity data of the H2O- K2CO3/KHCO3 system is verified in this work. It was found out that the values of dynamic viscosity obtained experimentally are in good agreement with the viscosity values calculated from this equation. The equation constants - interaction coefficients - were determined from the measurements of dynamic viscosity on mixing the basic solutions of K2CO3 and KHCO3 of known concentration. The correlation equation makes it possible to calculate viscosity of the K2CO3/KHCO3 solutions in the K2CO3 and KHCO3 concentration range from 0 to about 2.0 kmol m-3.

Acidity Functions for Strongly Basic Solutions

1966 ◽  
Vol 66 (2) ◽  
pp. 119-131 ◽  
Author(s):  
Keith Bowden
Keyword(s):  
Basic Solutions ◽  
Acidity Functions

Desorption of methionine from KU-5 sulforcation-exchange resign with basic solutions

1975 ◽  
Vol 9 (10) ◽  
pp. 662-663
Author(s):  
M. A. Gavrikova ◽  
G. V. Samsonov ◽  
V. Ya. Vorob'eva ◽  
G. B. Zvegintseva
Keyword(s):  
Basic Solutions

In x Ga 1−x N performance as a band-gap-tunable photo-electrode in acidic and basic solutions

2014 ◽  
Vol 130 ◽  
pp. 36-41 ◽  
Author(s):  
Jurga Juodkazytė ◽  
Benjaminas Šebeka ◽  
Irena Savickaja ◽  
Arūnas Kadys ◽  
Edgaras Jelmakas ◽  
...  
Keyword(s):  
Band Gap ◽  
Basic Solutions ◽  
Photo Electrode

scholarly journals Synthesis and Guest-Binding Properties of pH/Reduction Dual-Responsive Cyclophane Dimer

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3097
Author(s):  
Osamu Hayashida ◽  
Yudai Tanaka ◽  
Takaaki Miyazaki
Keyword(s):  
Electrostatic Interaction ◽  
Disulfide Bonds ◽  
Water Soluble ◽  
Guest Molecules ◽  
Binding Behavior ◽  
Dual Responsive ◽  
Guest Binding ◽  
Basic Solutions ◽  
Ph Conditions ◽  
Almost All

A water-soluble cyclophane dimer having two disulfide groups as a reduction-responsive cleavable bond as well as several acidic and basic functional groups as a pH-responsive ionizable group 1 was successfully synthesized. It was found that 1 showed pH-dependent guest-binding behavior. That is, 1 strongly bound an anionic guest, 6-p-toluidinonaphthalene-2-sulfonate (TNS) with binding constant (K/M−1) for 1:1 host-guest complexes of 9.6 × 104 M−1 at pH 3.8, which was larger than those at pH 7.4 and 10.7 (6.0 × 104 and 2.4 × 104 M−1, respectively), indicating a favorable electrostatic interaction between anionic guest and net cationic 1. What is more, release of the entrapped guest molecules by 1 was easily controlled by pH stimulus. Large favorable enthalpies (ΔH) for formation of host-guest complexes were obtained under the pH conditions employed, suggesting that electrostatic interaction between anionic TNS and 1 was the most important driving force for host-guest complexation. Such contributions of ΔH for formation of host-guest complexes decreased along with increased pH values from acidic to basic solutions. Upon addition of dithiothreitol (DTT) as a reducing reagent to an aqueous PBS buffer (pH 7.4) containing 1 and TNS, the fluorescence intensity originating from the bound guest molecules decreased gradually. A treatment of 1 with DTT gave 2, having less guest-binding affinity by the cleavage of disulfide bonds of 1. Consequently, almost all entrapped guest molecules by 1 were released from the host. Moreover, such reduction-responsive cleavage of 1 and release of bound guest molecules was performed more rapidly in aqueous buffer at pH 10.7.

Electrodeposited Thin Conformal TiO2 Coating Enabling Stable Operation of BiVO4 Photoanodes in Basic Media

2018 ◽  
Vol MA2018-01 (31) ◽  
pp. 1917-1917
Author(s):  
Dongho Lee ◽  
Kyoung-Shin Choi
Keyword(s):  
Oxygen Evolution ◽  
Water Oxidation ◽  
Synthesis Method ◽  
Protective Layer ◽  
Photoelectrochemical Cell ◽  
Semiconductor Surface ◽  
Stable Operation ◽  
Solar Water Splitting ◽  
Wide Range ◽  
Basic Solutions

Producing hydrogen via solar water splitting using a photoelectrochemical cell (PEC) persists as one of the most exciting research topics in the field of solar fuels. The construction of efficient PECs requires the integration of multiple components including a photoanode, a photocathode, an oxygen evolution catalyst, and a hydrogen evolution catalyst. Therefore, the compatibility and stability of all of these elements in a given operating condition are crucial. When the stability of a semiconductor electrode used as the photoanode or photocathode is limited in an acidic or basic condition which is optimum for the operation of the other components, a thin protective layer has been deposited on the semiconductor surface to prevent its chemical dissolution. Surface coating of a thin and conformal TiO2 layer has been proven to be successful for protecting photoelectrodes since TiO2 is chemically and electrochemically stable in a wide range of pH conditions under both anodic and cathodic conditions. In order to prevent the semiconductor surface from coming into direct contact with the corrosive electrolyte, complete coverage of the photoelectrode with TiO2 is required. At the same time, the TiO2 layer should be thin enough not to interfere with the charge transport properties of the photoelectrode. As a result, atomic layer deposition (ALD) has been the only successful tool used to date to produce an effective protective layer. However, the slow processing time and economic viability of ALD methods motivated us to develop an inexpensive and facile solution-based synthesis method for the deposition of high quality TiO2 coating layers. In this presentation, we report a new electrochemical method to deposit a thin and conformal TiO2 layer on nanoporous BiVO4 that has an intricate, high surface area morphology. BiVO4 is a promising n-type photoanode material with a relatively low bandgap (2.4~2.5 eV). However, its usage has been limited to neutral and mildly basic conditions (pH 5~9) because it is chemically unstable in strongly acidic and basic conditions. Our method allows for the deposition of a 5~6 nm thick TiO2 layer on BiVO4 within 1 min and the resulting BiVO4/TiO2 electrodes exhibit chemical stability in basic solutions (pH 12~13). Sulfite oxidation measurements of BiVO4 and BiVO4/TiO2 electrodes show that the thin TiO2 protective layer does not significantly reduce the hole transfer to the electrolyte. Finally, we demonstrate the photoelectrochemical stability of the BiVO4/TiO2 electrode for photoelectrochemical water oxidation in basic solutions by coupling the BiVO4/TiO2 electrode with appropriate oxygen evolution catalysts.

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