Infrared Photodissociation Spectroscopy of Heteronuclear Arsenic–Iron Carbonyl Cluster Anions

2020 ◽  
Vol 124 (6) ◽  
pp. 1158-1166
Author(s):  
Luyan Meng ◽  
Siying Liu ◽  
Qifeng Qin ◽  
Bin Zeng ◽  
Chaoxian Chi
Keyword(s):  
Iron Carbonyl ◽  
Carbonyl Cluster ◽  
Cluster Anions

Photoelectron spectroscopy of iron carbonyl cluster anions (Fen(CO)−m, n = 1−4)

1994 ◽  
Vol 221 (5-6) ◽  
pp. 436-440 ◽  
Author(s):  
Atsushi Nakajima ◽  
Tetsuya Taguwa ◽  
Koji Kaya
Keyword(s):  
Photoelectron Spectroscopy ◽  
Iron Carbonyl ◽  
Carbonyl Cluster ◽  
Cluster Anions

Infrared Photodissociation Spectroscopy of Heteronuclear Group 15 Metal–Iron Carbonyl Cluster Anions AmFe(CO)n− (A = Sb, Bi; m, n = 2, 3)

2021 ◽  
Author(s):  
Luyan Meng ◽  
Siying Liu ◽  
Qifeng Qin ◽  
Bin Zeng ◽  
Zhen Luo ◽  
...  
Keyword(s):  
Gas Phase ◽  
Iron Carbonyl ◽  
Carbonyl Cluster ◽  
Cluster Anions ◽  
Cluster Complexes ◽  
Group 15

Heteronuclear Group 15 metal–iron carbonyl cluster complexes of AmFe(CO)n− (A = Sb, Bi; m, n = 2–3) were generated in the gas phase and studied by infrared photodissociation spectroscopy in...

Infrared photodissociation spectra of mass selected homoleptic dinuclear iron carbonyl cluster anions in the gas phase

2012 ◽  
Vol 3 (5) ◽  
pp. 1698 ◽  
Author(s):  
Chaoxian Chi ◽  
Jieming Cui ◽  
Zhen Hua Li ◽  
Xiaopeng Xing ◽  
Guanjun Wang ◽  
...  
Keyword(s):  
Gas Phase ◽  
Iron Carbonyl ◽  
Carbonyl Cluster ◽  
Cluster Anions ◽  
Dinuclear Iron

Ruthenium and Iron Carbonyl Clusters Catalyzed Reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl)benzamide

2011 ◽  
Vol 396-398 ◽  
pp. 2485-2488
Author(s):  
Bao Hua Zhu ◽  
Guo Hua Xu ◽  
Zhi Wei Xia
Keyword(s):  
Ir Spectroscopy ◽  
Elemental Analysis ◽  
Iron Carbonyl ◽  
Carbonyl Cluster ◽  
Carbonyl Clusters ◽  
Excellent Yield ◽  
Ruthenium Carbonyl ◽  
Vis Spectroscopy

One new Ruthenium and one known Iron bimetallic carbonyl clusters containing triphos (1,1,1-tris(diphenylphosphinomethyl)ethane) ligand have been prepared as catalyst to study the reduction of amide to amine. All clusters were characterized by elemental analysis, 1HNMR, 31PNMR and IR spectroscopy. The reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl) benzamide catalyzed by Ru and Fe carbonyl clusters were investigated at 100 ~ 110 °C for 24 ~ 28h, polymethylhydrogensiloxane (PMHS) as reduction agent. The products were analysized using GC-MS, IR and UV-vis spectroscopy and an excellent yield (97%) of N,N-diethyl- (3-methyl)benzamine was obtained when using 3 mol% of bimetallic ruthenium carbonyl cluster as catalyst. The data of IR and UV-vis show that the frameworks of clusters are not changed remarkably during the reaction.

Infrared Photodissociation Spectroscopy of Mass-Selected Heteronuclear Iron–Copper Carbonyl Cluster Anions in the Gas Phase

2015 ◽  
Vol 119 (18) ◽  
pp. 4142-4150 ◽  
Author(s):  
Ning Zhang ◽  
Mingbiao Luo ◽  
Chaoxian Chi ◽  
Guanjun Wang ◽  
Jieming Cui ◽  
...  
Keyword(s):  
Gas Phase ◽  
Carbonyl Cluster ◽  
Cluster Anions ◽  
Iron Copper

A systematic synthetic route to ruthenium carbonyl cluster anions

1983 ◽  
Vol 2 (9) ◽  
pp. 1187-1193 ◽  
Author(s):  
Alak A. Bhattacharyya ◽  
Colleen C. Nagel ◽  
Sheldon G. Shore
Keyword(s):  
Carbonyl Cluster ◽  
Cluster Anions ◽  
Synthetic Route ◽  
Ruthenium Carbonyl
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