A systematic synthetic route to ruthenium carbonyl cluster anions

1983 ◽  
Vol 2 (9) ◽  
pp. 1187-1193 ◽  
Author(s):  
Alak A. Bhattacharyya ◽  
Colleen C. Nagel ◽  
Sheldon G. Shore
Keyword(s):  
Carbonyl Cluster ◽  
Cluster Anions ◽  
Synthetic Route ◽  
Ruthenium Carbonyl

scholarly journals Gas-phase reactivity of ruthenium carbonyl cluster anions

2009 ◽  
Vol 20 (4) ◽  
pp. 658-666 ◽  
Author(s):  
Matthew A. Henderson ◽  
Samantha Kwok ◽  
J. Scott McIndoe
Keyword(s):  
Gas Phase ◽  
Carbonyl Cluster ◽  
Cluster Anions ◽  
Ruthenium Carbonyl

Reversible π-coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

2004 ◽  
Vol 7 (3) ◽  
pp. 443-446 ◽  
Author(s):  
Anders Thapper ◽  
Emma Sparr ◽  
Brian F.G. Johnson ◽  
Jack Lewis ◽  
Paul R. Raithby ◽  
...  
Keyword(s):  
Carbonyl Cluster ◽  
Ruthenium Carbonyl

Ruthenium and Iron Carbonyl Clusters Catalyzed Reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl)benzamide

2011 ◽  
Vol 396-398 ◽  
pp. 2485-2488
Author(s):  
Bao Hua Zhu ◽  
Guo Hua Xu ◽  
Zhi Wei Xia
Keyword(s):  
Ir Spectroscopy ◽  
Elemental Analysis ◽  
Iron Carbonyl ◽  
Carbonyl Cluster ◽  
Carbonyl Clusters ◽  
Excellent Yield ◽  
Ruthenium Carbonyl ◽  
Vis Spectroscopy

One new Ruthenium and one known Iron bimetallic carbonyl clusters containing triphos (1,1,1-tris(diphenylphosphinomethyl)ethane) ligand have been prepared as catalyst to study the reduction of amide to amine. All clusters were characterized by elemental analysis, 1HNMR, 31PNMR and IR spectroscopy. The reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl) benzamide catalyzed by Ru and Fe carbonyl clusters were investigated at 100 ~ 110 °C for 24 ~ 28h, polymethylhydrogensiloxane (PMHS) as reduction agent. The products were analysized using GC-MS, IR and UV-vis spectroscopy and an excellent yield (97%) of N,N-diethyl- (3-methyl)benzamine was obtained when using 3 mol% of bimetallic ruthenium carbonyl cluster as catalyst. The data of IR and UV-vis show that the frameworks of clusters are not changed remarkably during the reaction.

Infrared Photodissociation Spectroscopy of Mass-Selected Heteronuclear Iron–Copper Carbonyl Cluster Anions in the Gas Phase

2015 ◽  
Vol 119 (18) ◽  
pp. 4142-4150 ◽  
Author(s):  
Ning Zhang ◽  
Mingbiao Luo ◽  
Chaoxian Chi ◽  
Guanjun Wang ◽  
Jieming Cui ◽  
...  
Keyword(s):  
Gas Phase ◽  
Carbonyl Cluster ◽  
Cluster Anions ◽  
Iron Copper

Platinum-ruthenium Carbonyl Cluster Complexes

2007 ◽  
pp. 280-284 ◽  
Author(s):  
R. D. Adams ◽  
T. S. Barnard ◽  
J. E. Cortopassi ◽  
W. Wu ◽  
Z. Li ◽  
...  
Keyword(s):  
Carbonyl Cluster ◽  
Cluster Complexes ◽  
Ruthenium Carbonyl
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