Stereoselective Oxidative Rearrangement of Disubstituted Unactivated Alkenes Using Hypervalent Iodine(III) Reagent

2020 ◽  
Vol 85 (15) ◽  
pp. 10175-10181
Author(s):  
Chandra Bhan Pandey ◽  
Tazeen Azaz ◽  
Ram Subhawan Verma ◽  
Monika Mishra ◽  
Jawahar L. Jat ◽  
...  
Keyword(s):  
Hypervalent Iodine ◽  
Oxidative Rearrangement

scholarly journals Oxidative rearrangement of alkenes using in situ generated hypervalent iodine(III)

2013 ◽  
Vol 54 (43) ◽  
pp. 5818-5820 ◽  
Author(s):  
Anees Ahmad ◽  
Paulo Scarassati ◽  
Nazli Jalalian ◽  
Berit Olofsson ◽  
Luiz F. Silva
Keyword(s):  
Hypervalent Iodine ◽  
Oxidative Rearrangement

ChemInform Abstract: Oxidative Rearrangement of Alkenes Using in situ Generated Hypervalent Iodine(III).

ChemInform ◽  
2014 ◽  
Vol 45 (7) ◽  
pp. no-no
Author(s):  
Anees Ahmad ◽  
Paulo Scarassati ◽  
Nazli Jalalian ◽  
Berit Olofsson ◽  
Luiz F. Jr. Silva
Keyword(s):  
Hypervalent Iodine ◽  
Oxidative Rearrangement

Oxidative rearrangement strategy for synthesis of 2,4,5-trisubstituted oxazoles utilizing hypervalent iodine reagent

Tetrahedron ◽  
2016 ◽  
Vol 72 (38) ◽  
pp. 5749-5753 ◽  
Author(s):  
Qing Liu ◽  
Xiaohui Zhang ◽  
Yang He ◽  
Muhammad Ijaz Hussain ◽  
Wen Hu ◽  
...  
Keyword(s):  
Hypervalent Iodine ◽  
Oxidative Rearrangement

Hypervalent iodine-mediated synthesis of benzoxazoles and benzimidazoles via an oxidative rearrangement

Tetrahedron ◽  
2015 ◽  
Vol 71 (4) ◽  
pp. 700-708 ◽  
Author(s):  
Xiaohui Zhang ◽  
Ruofeng Huang ◽  
Jérôme Marrot ◽  
Vincent Coeffard ◽  
Yan Xiong
Keyword(s):  
Hypervalent Iodine ◽  
Oxidative Rearrangement

Synthesis of 3-acylindoles by oxidative rearrangement of 2-aminochalcones using a hypervalent iodine reagent and cyclization sequence

2017 ◽  
Vol 15 (32) ◽  
pp. 6702-6705 ◽  
Author(s):  
Akira Nakamura ◽  
Satoshi Tanaka ◽  
Akira Imamiya ◽  
Reo Takane ◽  
Chiaki Ohta ◽  
...  
Keyword(s):  
Hypervalent Iodine ◽  
One Pot ◽  
Oxidative Rearrangement

An efficient one-pot 3-acylindole synthesis by oxidative rearrangement of 2-aminochalcones and sequential cyclization has been developed.

Hypervalent Iodine Reagents in the Synthesis of Flavonoids and Related Compounds

2020 ◽  
Vol 24 (18) ◽  
pp. 2031-2047
Author(s):  
Rajesh Kumar ◽  
Nitya Sharma ◽  
Om Prakash
Keyword(s):  
Carbonyl Compounds ◽  
Hypervalent Iodine ◽  
Unsaturated Ketones ◽  
Oxidative Rearrangement ◽  
Iodine Compounds ◽  
Oxidative Transformations ◽  
Oxidation Of Phenols ◽  
Related Compounds

Hypervalent iodine compounds have proved to be very useful reagents to bring about various oxidative transformations including (i) α-functionalization of carbonyl compounds, (ii) oxidation of phenols, and (iii) oxidative rearrangement of ketones and α,β- unsaturated ketones. These reactions find interesting applications in the development of newer and convenient approaches for the synthesis of flavonoids. This review focuses on the use of most common three hypervalent compounds, namely iodobenzene diacetate, [hydroxy(tosyloxy)iodo]benzene, and [bis-trifluoroacetoxy(iodo)]benzene in the synthesis of cis/trans-3-hydroxyflavanones, 3-hydroxyflavones (flavonols), flavones, isoflavones and related compounds.

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