Modeling σ-Bond Activations by Nickel(0) Beyond Common Approximations: How Accurately Can We Describe Closed-Shell Oxidative Addition Reactions Mediated by Low-Valent Late 3d Transition Metal?

2017 ◽  
Vol 13 (10) ◽  
pp. 4841-4853 ◽  
Author(s):  
Lianrui Hu ◽  
Kejuan Chen ◽  
Hui Chen
Keyword(s):  
Transition Metal ◽  
Oxidative Addition ◽  
Closed Shell ◽  
Addition Reactions ◽  
Low Valent ◽  
Bond Activations

Tandem transmetallation and oxidative addition reactions of [Sn(R)2(Ph2PC6H4-2-S)2] with transition metal complexes of the Group 9

2004 ◽  
Vol 689 (1) ◽  
pp. 174-180 ◽  
Author(s):  
Daniel Canseco-González ◽  
Valente Gómez-Benı́tez ◽  
Oscar Baldovino-Pantaleón ◽  
Simón Hernández-Ortega ◽  
David Morales-Morales
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Oxidative Addition ◽  
Addition Reactions

Mechanistic investigations of CO-photoextrusion and oxidative addition reactions of early transition-metal carbonyls: (η5-C5H5)M(CO)4(M = V, Nb, Ta)

2016 ◽  
Vol 18 (24) ◽  
pp. 16396-16403 ◽  
Author(s):  
Shih-Hao Su ◽  
Ming-Der Su
Keyword(s):  
Transition Metal ◽  
Oxidative Addition ◽  
Addition Reactions ◽  
Metal Carbonyls ◽  
Early Transition Metal ◽  
Model Study ◽  
Transition Metal Carbonyls ◽  
Mechanistic Investigations ◽  
Group 5 ◽  
Early Transition

A model study of the photoactivation reactions of Si–H bonds in trimethylsilane by group 5 (η5-C5H5)M(CO)4(M = V, Nb and Ta;Rea-S0-M) complexes is undertaken using the M06-2X/Def2-SVPD level of theory.

Sign in / Sign up

Export Citation Format

Share Document