scholarly journals Calculating the Partition Coefficients of Organic Solvents in Octanol/Water and Octanol/Air

2019 ◽  
Vol 59 (5) ◽  
pp. 2257-2263 ◽  
Author(s):  
Miroslava A. Nedyalkova ◽  
Sergio Madurga ◽  
Marek Tobiszewski ◽  
Vasil Simeonov
2007 ◽  
Vol 70 (20) ◽  
pp. 1745-1751 ◽  
Author(s):  
Deirdre A. Mahle ◽  
Jeffery M. Gearhart ◽  
Claude C. Grigsby ◽  
David R. Mattie ◽  
Hugh A. Barton ◽  
...  

1996 ◽  
Vol 61 (8) ◽  
pp. 1177-1181 ◽  
Author(s):  
Alena Tokárová ◽  
Oldřich Navrátil ◽  
Petr Sládek

The distribution of scandium and hafnium between 0.1 or 1.0 mol l-1 HNO3 and solutions of monoalkyl methanephosphonates (HA; alkyl = methyl, propyl, butyl, isobutyl, pentyl, 2-methylbutyl, cyclohexyl, 1,2,2-trimethylpropyl) in chloroform and 1,1,2,2-tetrachloroethane has been studied. The organic solvents mentioned allow to obtain the optimum values of partition coefficients of the two metals. The corresponding extraction constants of the ScA3(HA)x and Hf(NO3)4(HA)4 complexes have been calculated.


1986 ◽  
Vol 41 (12) ◽  
pp. 1580-1582 ◽  
Author(s):  
Cyril Párkányi ◽  
Dah-Chung Shieh

AbstractPartition coefficients of sixteen biologically important pyrimidines and purines between an organic phase and water have been determined and the best organic solvents for their extraction have been suggested.


1998 ◽  
Vol 64 (5) ◽  
pp. 1929-1932 ◽  
Author(s):  
Noriyuki Doukyu ◽  
Rikizo Aono

ABSTRACT Extracellular cholesterol oxidase of Pseudomonas sp. strain ST-200 was purified from the culture supernatant. This oxidase contained bound flavin and was categorized as a 3β-hydroxysteroid oxidase, converting 3β-hydroxyl groups to keto groups. The molecular mass was 60 kDa. The enzyme was stable at pH 4 to 11 and active at pH 5.0 to 8.5, showing optimal activity at pH 7 at 60�C. The Michaelis constant of the ST-200 cholesterol oxidase was lower than those of commercially available oxidases. The cholesterol oxidation rate was enhanced 3- to 3.5-fold in the presence of organic solvents, with log P ow values (partition coefficients of the organic solvent betweenn-octanol and water), in the range of 2.1 to 4.2, compared with that in the absence of organic solvents.


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