Measurements of PvT Properties, Saturated Densities, and Critical Parameters for 3,3,3-Trifluoropropene (HFO1243zf)

2018 ◽  
Vol 63 (10) ◽  
pp. 3818-3822 ◽  
Author(s):  
Yukihiro Higashi ◽  
Naoya Sakoda
Keyword(s):  
Critical Parameters ◽  
Pvt Properties

PVT Measurements and Critical Parameters of Water

1983 ◽  
Vol 22 ◽  
Author(s):  
H. Hanafusa ◽  
K. Kawai ◽  
H. Sato ◽  
M. Uematsu ◽  
K. Watanabe
Keyword(s):  
Vapor Pressure ◽  
Scaling Law ◽  
Density Variation ◽  
Critical Parameters ◽  
Pressure Measurements ◽  
Vapor Pressures ◽  
Constant Temperature Bath ◽  
Pvt Properties ◽  
Pvt Measurements ◽  
Vapor Pressure Measurements

ABSTRACTThe PVT properties and vapor-pressures of water have been measured in the critical region by using a constantvolume apparatus immersed in the constant-temperature bath with the procedure of varying the sample mass along a prescribed isotherm. Ninety-one PVT and five vapor-pressure measurements along 11 isotherms cover the region of temperatures 643 to 673 K and of pressures 19.7 to 38.6 MPa, which corresponds to a density variation from 108 to 618 kg/m3. The experimental uncertainties of temperature, pressure and density are estimated 4 mK, 5 kPa and 0.04%, respectively. Based on these measurements, the critical parameters of water are proposed to be 647.061 K, 22.041 MPa and 322.4 kg/m3 by the scaling law analysis.

PVT properties, vapor pressures and critical parameters of HFC-32

1995 ◽  
Vol 111 (2) ◽  
pp. 273-286 ◽  
Author(s):  
Yi-Dong Fu ◽  
Li-Zhong Han ◽  
Ming-Shan Zhu
Keyword(s):  
Critical Parameters ◽  
Vapor Pressures ◽  
Pvt Properties

New Insights into the Nature of the Band Gap of CuGeO3 Nanoparticles: Synthesis, Electronic Structure, and Optical and Photocatalytic Properties

2019 ◽  
Author(s):  
Victor Y. Suzuki ◽  
Luís Henrique Cardozo Amorin ◽  
Natália H. de Paula ◽  
Anderson R. Albuquerque ◽  
Julio Ricardo Sambrano ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Band Gap ◽  
Material Design ◽  
Photocatalytic Properties ◽  
Critical Parameters ◽  
Synthetic Approach ◽  
Microwave Assisted ◽  
Theoretical Approaches ◽  
Nanoparticles Synthesis ◽  
First Time

<p>We report, for the first time, new insights into the nature of the band gap of <a>CuGeO<sub>3</sub> </a>(CGO) nanocrystals synthesized from a microwave-assisted hydrothermal method in the presence of citrate. To the best of our knowledge, this synthetic approach has the shortest reaction time and it works at the lowest temperatures reported in the literature for the preparation of these materials. The influence of the surfactant on the structural, electronic, optical, and photocatalytic properties of CGO nanocrystals is discussed by a combination of experimental and theoretical approaches, and that results elucidates the nature of the band gap of synthetized CGO nanocrystals. We believe that this particular strategy is one of the most critical parameters for the development of innovative applications and that result could shed some light on the emerging material design with entirely new properties.</p> <p><b> </b></p>

Fundamental Considerations for CDM Failure in 90nm Products

2006 ◽  
Author(s):  
Nobuyuki Wakai ◽  
Yuji Kobira ◽  
Hidemitsu Egawa ◽  
Masayoshi Tsutsumi
Keyword(s):  
Breakdown Voltage ◽  
High Speed ◽  
Gate Oxide ◽  
Critical Parameters ◽  
Protection Device ◽  
Oxide Breakdown ◽  
Technology Products ◽  
Charged Device ◽  
Device Size ◽  
Fundamental Consideration

Abstract Fundamental consideration for CDM (Charged Device Model) breakdown was investigated with 90nm technology products and others. According to the result of failure analysis, it was found that gate oxide breakdown was critical failure mode for CDM test. High speed triggered protection device such as ggNMOS and SCR (Thyristor) is effective method to improve its CDM breakdown voltage and an improvement for evaluated products were confirmed. Technological progress which is consisted of down-scaling of protection device size and huge number of IC pins of high function package makes technology vulnerable and causes significant CDM stress. Therefore, it is expected that CDM protection designing tends to become quite difficult. In order to solve these problems in the product, fundamental evaluations were performed. Those are a measurement of discharge parameter and stress time dependence of CDM breakdown voltage. Peak intensity and rise time of discharge current as critical parameters are well correlated their package capacitance. Increasing stress time causes breakdown voltage decreasing. This mechanism is similar to that of TDDB for gate oxide breakdown. Results from experiences and considerations for future CDM reliable designing are explained in this report.

Fuzzy control of coagulation reaction through streaming current monitoring

1997 ◽  
Vol 36 (4) ◽  
pp. 127-134 ◽  
Author(s):  
J. C. Liu ◽  
M. D. Wu
Keyword(s):  
Fuzzy Logic Controller ◽  
Treatment Plant ◽  
Control Process ◽  
Water Treatment Plant ◽  
Critical Parameters ◽  
Flow Mode ◽  
Raw Water ◽  
Streaming Current ◽  
On Line ◽  
Current Monitoring

A fuzzy logic controller (FLC) incorporating the streaming current detector (SDC) was utilized in the automatic control of the coagulation reaction. Kaolinite was used to prepare synthetic raw water, and ferric chloride was used as the coagulant. The control set point was decided at a streaming current (SC) of −0.05 and pH of 8.0 from jar tests, zeta potential and streaming current measurements. A bench-scale water treatment plant with rapid mix, flocculation, and sedimentation units, operated in a continuous-flow mode, was utilized to simulate the reaction. Two critical parameters affecting the coagulation reaction, i.e., pH and streaming current, were chosen as process outputs; while coagulant dose and base dose were chosen as control process inputs. They were on-line monitored and transduced through a FLC. With raw water of initial turbidity of 110 NTU, residual turbidity of lower than 10 NTU before filtration was obtained. Results show that this combination functions satisfactorily for coagulation control.

Influence of viscosity temperature dependence on the spectral characteristics of the thermoviscous liquids flow stability equation

2019 ◽  
Vol 14 (1) ◽  
pp. 52-58 ◽  
Author(s):  
A.D. Nizamova ◽  
V.N. Kireev ◽  
S.F. Urmancheev
Keyword(s):  
Reynolds Number ◽  
Spectral Characteristics ◽  
Wave Number ◽  
Critical Parameters ◽  
Fluid Viscosity ◽  
Flat Channel ◽  
Stability Equation ◽  
The Stability ◽  
Thermoviscous Fluid ◽  
Sommerfeld Equation

The flow of a viscous model fluid in a flat channel with a non-uniform temperature field is considered. The problem of the stability of a thermoviscous fluid is solved on the basis of the derived generalized Orr-Sommerfeld equation by the spectral decomposition method in Chebyshev polynomials. The effect of taking into account the linear and exponential dependences of the fluid viscosity on temperature on the spectral characteristics of the hydrodynamic stability equation for an incompressible fluid in a flat channel with given different wall temperatures is investigated. Analytically obtained profiles of the flow rate of a thermovisible fluid. The spectral pictures of the eigenvalues of the generalized Orr-Sommerfeld equation are constructed. It is shown that the structure of the spectra largely depends on the properties of the liquid, which are determined by the viscosity functional dependence index. It has been established that for small values of the thermoviscosity parameter the spectrum compares the spectrum for isothermal fluid flow, however, as it increases, the number of eigenvalues and their density increase, that is, there are more points at which the problem has a nontrivial solution. The stability of the flow of a thermoviscous fluid depends on the presence of an eigenvalue with a positive imaginary part among the entire set of eigenvalues found with fixed Reynolds number and wavenumber parameters. It is shown that with a fixed Reynolds number and a wave number with an increase in the thermoviscosity parameter, the flow becomes unstable. The spectral characteristics determine the structure of the eigenfunctions and the critical parameters of the flow of a thermally viscous fluid. The eigenfunctions constructed in the subsequent works show the behavior of transverse-velocity perturbations, their possible growth or decay over time.

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