Maximum Removal Efficiency of Barium, Strontium, Radium, and Sulfate with Optimum AMD-Marcellus Flowback Mixing Ratios for Beneficial Use in the Northern Appalachian Basin

2020 ◽  
Vol 54 (8) ◽  
pp. 4829-4839 ◽  
Author(s):  
Bonnie McDevitt ◽  
Michael Cavazza ◽  
Richard Beam ◽  
Eric Cavazza ◽  
William D. Burgos ◽  
...  
2011 ◽  
Vol 340 ◽  
pp. 236-240
Author(s):  
Jian Feng Ma ◽  
Jian Ming Yu ◽  
Bing Ying Cui ◽  
Ding Long Li ◽  
Juan Dai

Inorganic-organic-bentonite was synthesized by modification of bentonite by Hydroxy-iron and surfactant, which could be applied in dye removal by adsorption and catalysis. The removal of acid dye Orange II was studied at various factors such as time and pH of solution. The results showed that the inorganic-organic-bentonite could efficiently remove the dye with efficiency of 96.22%. The maximum adsorption capacity is 76 mg/g. The pH of solution has significant effect on both adsorption and catalysis. When pH was 4, the maximum removal efficiency of adsorption and catalysis were 97.57% and 87.23%, respectively. After degradation, the secondary pollution was diminished and the bentonite could be reused.


2017 ◽  
Vol 76 (6) ◽  
pp. 1466-1473 ◽  
Author(s):  
M. H. Salmani ◽  
M. Mokhtari ◽  
Z. Raeisi ◽  
M. H. Ehrampoush ◽  
H. A. Sadeghian

Wastewater containing pharmaceutical residual components must be treated before being discharged to the environment. This study was conducted to investigate the efficiency of tungsten-carbon nanocomposite in diclofenac removal using design of experiment (DOE). The 27 batch adsorption experiments were done by choosing three effective parameters (pH, adsorbent dose, and initial concentration) at three levels. The nanocomposite was prepared by tungsten oxide and activated carbon powder in a ratio of 1 to 4 mass. The remaining concentration of diclofenac was measured by a spectrometer with adding reagents of 2, 2′-bipyridine, and ferric chloride. Analysis of variance (ANOVA) was applied to determine the main and interaction effects. The equilibrium time for removal process was determined as 30 min. It was observed that the pH had the lowest influence on the removal efficiency of diclofenac. Nanocomposite gave a high removal at low concentration of 5.0 mg/L. The maximum removal for an initial concentration of 5.0 mg/L was 88.0% at contact time of 30 min. The results of ANOVA showed that adsorbent mass was among the most effective variables. Using DOE as an efficient method revealed that tungsten-carbon nanocomposite has high efficiency in the removal of residual diclofenac from the aqueous solution.


2021 ◽  
Vol 900 (1) ◽  
pp. 012003
Author(s):  
M Balintova ◽  
Z Kovacova ◽  
S Demcak ◽  
Y Chernysh ◽  
N Junakova

Abstract Removal of heavy metals from the environment is important for living beings. The present work investigates the applicability of the natural and MnO2 - coated zeolite as sorbent for the removal of copper from synthetic solutions. Batch experiments were carried out to identify the influence of initial pH and concentration in the process of adsorption. A maximum removal efficiency of Cu(II) was observed in 10 mg/L for natural (95.6%) and modified (96.4%) zeolite, where the values was almost identical, but at concentration of 500 mg/L was the removal efficiency of modified zeolite three times higher. Based on the correlation factors R2, the Langmuir isotherms better describe the decontamination process than Freundlich. The optimum pH value was set at 5.0.


Author(s):  
Negar Jafari ◽  
Afshin Ebrahimi ◽  
Karim Ebrahimpour ◽  
Ali Abdolahnejad

Introduction: Microcystin-leucine arginine (MC-LR) is a toxin with harmful effects on the liver, kidney, heart, and gastrointestinal tract. So, effective removal of MC-LR from water resources is of great importance. The aim of this study was to remove microcystin-LR (MC-LR) from aqueous solution by Titanium Dioxide (TiO2). Materials and Methods: In the present study, TiO2, as a semiconductor, was used for photodegradation of MC-LR under ultraviolet light (UV). The Response Surface Methodology was applied to investigate the effects of operating variables such as pH (A), contact time (B), and catalyst dose (B) on the removal of MC-LR. The MC-LR concentration was measured by high-performance liquid chromatography (HPLC). Results: The results showed that single variables such as A, B, and C had significant effects on MC-LR removal (pvalue < 0.05). In other words, increase of the contact time and catalyst dose had a positive effect on enhancing the removal efficiency of MC-LR, but the effect of pH was negative. The analysis of variance showed that BC, A2, and C2 variables had a significant effect on the MC-LR removal (pvalue < 0.05). Finally, the maximum removal efficiency of MC-LR was 95.1%, which occurred at pH = 5, contact time = 30 minutes, and catalyst dose = 1 g/l. Conclusion: According to the findings, TiO2, as a photocatalyst, had an appropriate effect on degradation of the MC-LR.


2019 ◽  
Vol 6 (1) ◽  
pp. 41-48 ◽  
Author(s):  
Abdul Aziz Hamidi ◽  
Syed Zainal Sharifah Farah Fariza ◽  
Alazaiza Motasem Y.D

Landfill leachate is highly polluted and generated as a result of water infiltration through solid waste produced domestically and industrially. This study investigated the applicability of the response surface methodology (RSM) to optimize the removal performances of chemical oxygen demand (COD), color, and suspended solids (SS) from landfill leachate by coagulation process using Tin tetrachloride pentahydrate. The leachate samples were collected from Alor Pongsu Landfill (APLS) in Perak, Malaysia. Before starting the experiments, general characterization was carried out for raw leachate samples to investigate their physical and chemical properties. The effects of the dosage and pH of SnCl4 on the removal performances were evaluated as well. An ideal experimental design was performed based on the central composite design (CCD) by RSM. In addition, this RSM was used to evaluate the effects of process variables and their interaction toward the attainment of their optimum conditions. The statistical design of the experiments and data analysis was resolved using the Design-Expert software. Further, the range of coagulant dosage and pH was selected based on a batch study which was conducted at 13000 mg/L to 17000 mg/L of SnCl4 and pH ranged from 6 to 10. The results showed that the optimum pH and dosage of SnCl4 were 7.17 and 15 g/L, respectively, where the maximum removal efficiency was 67.7% for COD and 100% for color and SS. The results were in agreement with the experimental data with a maximum removal efficiency of 67.84 %, 98.6 %, and 99.3%, for COD, color, and SS, respectively. Overall, this study verified that the RSM method was viable for optimizing the operational condition of the coagulation-flocculation process.


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