Undiscovered Mechanism for Pyrogenic Carbonaceous Matter-Mediated Abiotic Transformation of Azo Dyes by Sulfide

2019 ◽  
Vol 53 (8) ◽  
pp. 4397-4405 ◽  
Author(s):  
Han-Qing Zhao ◽  
Shi-Qi Huang ◽  
Wen-Qing Xu ◽  
Yi-Ran Wang ◽  
Yi-Xuan Wang ◽  
...  
Keyword(s):  
Azo Dyes ◽  
Carbonaceous Matter ◽  
Abiotic Transformation

Synthesis and Characterization of Some New Esters Containing Heterocyclic and Derived From Azo Dyes

2019 ◽  
Vol 9 (02) ◽  
Author(s):  
Zena G. Alrecabi ◽  
Zainab Amer ◽  
Naeemah Al-Lami
Keyword(s):  
Schiff Base ◽  
13C Nmr ◽  
Azo Dyes ◽  
Spectral Methods ◽  
Anthranilic Acid ◽  
Heterocyclic Compounds ◽  
Synthesis And Characterization ◽  
Cooh Group ◽  
Molecular Weights

This study including prepared new colored esters containing heterocyclic with high molecular weights. In the first part of work we synthesized azo dyes [1,2] from the reaction p-toluidine with β-naphthol and o-nitro phenol, thin we synthesized Schiff bases [3,4] by the reaction anthranilic acid with benzaldehyde and dimethyl benzaldehyde. The reaction azo dyes (contain OH group) with Schiff base (contain COOH group) these led to produce the new colored esters [A1-A4]. The second part of work was modification the (C=N-) group in esters to heterocyclic compounds by reacting with phenyl iso cyanide to produce new β-lactam [B1-B4] and with anthranilic acid to get new hydroquinazoline [C1-C4]. All these compounds were characterized by physical properties and spectral methods FTIR, 1H-NMR and 13C-NMR.

Use of a sequencing batch biofilter for degradation of azo dyes (acids and bases)

2000 ◽  
Vol 42 (5-6) ◽  
pp. 329-336 ◽  
Author(s):  
M. Quezada ◽  
I. Linares ◽  
G. Buitrón
Keyword(s):  
Azo Dyes ◽  
Azo Dye ◽  
Degradation Rate ◽  
Removal Rate ◽  
Textile Effluent ◽  
Colour Removal ◽  
Substrate Degradation ◽  
Acids And Bases ◽  
Removal Efficiencies ◽  
Basic Red 46

The degradation of azo dyes in an aerobic biofilter operated in an SBR system was studied. The azo dyes studied were Acid Red 151 and a textile effluent containing basic dyes (Basic Blue 41, Basic Red 46 and 16 and Basic Yellow 28 and 19). In the case of Acid Red 151 a maximal substrate degradation rate of 288 mg AR 151/lliquid·d was obtained and degradation efficiencies were between 60 and 99%. Mineralization studies showed that 73% (as carbon) of the initial azo dye was transformed to CO2 by the consortia. The textile effluent was efficiently biodegraded by the reactor. A maximal removal rate of 2.3 kg COD/lliquid·d was obtained with removal efficiencies (as COD) varying from 76 to 97%. In all the cycles the system presented 80% of colour removal.

Inhibitory effects of the Food Azo Dyes on Pig Liver Carboxylesterase Activity

2015 ◽  
Vol 11 (2) ◽  
pp. 147-152
Author(s):  
Wafaa Lemerini ◽  
Zoheir Arrar ◽  
Kajima Joseph ◽  
Zoheir Dahmani ◽  
Wassila Drici ◽  
...  
Keyword(s):  
Azo Dyes ◽  
Inhibitory Effects ◽  
Pig Liver

Ion-Associates of N,N-Diethyllysergamide with Some Sulfophthaleins and Azo Dyes

1994 ◽  
Vol 59 (3) ◽  
pp. 575-581 ◽  
Author(s):  
Zdeněk Skaličan ◽  
Zbyněk Kobliha ◽  
Emil Halámek
Keyword(s):  
Azo Dyes ◽  
Limits Of Detection ◽  
Extraction Constants ◽  
Cresol Red ◽  
Extraction Spectrophotometry

Ion-associates of N,N-diethyllysergamide with the sulfophthaleins: Bromoxylenol Blue, Eriochrome Cyanine R, Xylenol Blue, and Cresol Red, and the azo dyes: Acid Black I and Orange-I were studied by extraction spectrophotometry. The extraction recoveries, distribution ratios, conditional extraction constants and limits of detection and determination were calculated.

Ce(IV)-mediated formation of benzenediazonium ion from a non-aminoazo dye, 1-phenylazo-2-hydroxy-naphthalene (Sudan I) and its binding to DNA

1989 ◽  
Vol 54 (7) ◽  
pp. 2021-2026
Author(s):  
Marie Stiborová ◽  
Befekadu Asfaw ◽  
Pavel Anzenbacher
Keyword(s):  
Azo Dyes ◽  
Acidic Medium ◽  
Model System ◽  
Calf Thymus Dna ◽  
Suitable Model ◽  
Principal Product ◽  
Calf Thymus ◽  
Sudan I ◽  
A Minor

Ce(IV) ions in acidic medium convert a carcinogenic non-aminoazo dye, 1-phenylazo-2-hydroxy-naphthalene (Sudan I) into an ultimate carcinogen, which binds to calf thymus DNA. The principal product of Sudan I oxidation by the Ce(IV) system is the benzenediazonium ion. A minor product is the dihydroxyderivative of Sudan I, 1-(4-hydroxyphenylazo)-2,6-dihydroxynaphthalene. Other minor coloured products (yellow and brown) were not identified. The principal product (the benzenediazonium ion) is responsible for the carcinogenicity of Sudan I, as it covalently binds to DNA. Ce(IV) ions in acidic medium represent a suitable model system, which imitates the activation route of carcinogenic azo dyes.

scholarly journals NMR spectroscopic investigation of benzothiazolylacetonitrile azo dyes: CR7 substitution effect and semiempirical study

2021 ◽  
Vol 3 ◽  
pp. 100088
Author(s):  
H.M. Alsoghier ◽  
M. Abdellah ◽  
H.M. Rageh ◽  
H.M.A. Salman ◽  
M.A. Selim ◽  
...  
Keyword(s):  
Azo Dyes ◽  
Spectroscopic Investigation ◽  
Substitution Effect
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