Toward Ultimate Control of Radical Polymerization: Functionalized Metal–Organic Frameworks as a Robust Environment for Metal-Catalyzed Polymerizations

2018 ◽  
Vol 30 (9) ◽  
pp. 2983-2994 ◽  
Author(s):  
Hui-Chun Lee ◽  
Jongkook Hwang ◽  
Uwe Schilde ◽  
Markus Antonietti ◽  
Krzysztof Matyjaszewski ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Metal Catalyzed ◽  
Ultimate Control

scholarly journals Rotational dynamics of the organic bridging linkers in metal–organic frameworks and their substituent effects on the rotational energy barrier

RSC Advances ◽  
2019 ◽  
Vol 9 (65) ◽  
pp. 38137-38147 ◽  
Author(s):  
Srimanta Pakhira
Keyword(s):  
Radical Polymerization ◽  
Energy Barrier ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Substituent Effects ◽  
Rotational Energy ◽  
Rotational Dynamics ◽  
Fuel Storage ◽  
Metal Organic ◽  
Organic Framework

Organic bridging linkers or ligands play an important role in gas and fuel storage, CO2 capture, and controlling the radical polymerization reactions in metal–organic framework (MOF) nanochannels.

scholarly journals Homocoupling Reactions of Azoles and Their Applications in Coordination Chemistry

Molecules ◽  
2020 ◽  
Vol 25 (24) ◽  
pp. 5950
Author(s):  
Steffen B. Mogensen ◽  
Mercedes K. Taylor ◽  
Ji-Woong Lee
Keyword(s):  
Coordination Chemistry ◽  
Reaction Mechanisms ◽  
Metal Organic Frameworks ◽  
Ring System ◽  
Membered Ring ◽  
Materials Chemistry ◽  
Structural Class ◽  
Basic Nitrogen ◽  
Metal Organic ◽  
Metal Catalyzed

Pyrazole, a member of the structural class of azoles, exhibits molecular properties of interest in pharmaceuticals and materials chemistry, owing to the two adjacent nitrogen atoms in the five-membered ring system. The weakly basic nitrogen atoms of deprotonated pyrazoles have been applied in coordination chemistry, particularly to access coordination polymers and metal-organic frameworks, and homocoupling reactions can in principle provide facile access to bipyrazole ligands. In this context, we summarize recent advances in homocoupling reactions of pyrazoles and other types of azoles (imidazoles, triazoles and tetrazoles) to highlight the utility of homocoupling reactions in synthesizing symmetric bi-heteroaryl systems compared with traditional synthesis. Metal-free reactions and transition-metal catalyzed homocoupling reactions are discussed with reaction mechanisms in detail.

ChemInform Abstract: Robust and Porous β-Diketiminate-Functionalized Metal-Organic Frameworks for Earth-Abundant-Metal-Catalyzed C-H Amination and Hydrogenation.

ChemInform ◽  
2016 ◽  
Vol 47 (33) ◽  
Author(s):  
Nathan C. Thacker ◽  
Zekai Lin ◽  
Teng Zhang ◽  
James C. Gilhula ◽  
Carter W. Abney ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Earth Abundant ◽  
Metal Organic ◽  
Metal Catalyzed

Robust and Porous β-Diketiminate-Functionalized Metal–Organic Frameworks for Earth-Abundant-Metal-Catalyzed C–H Amination and Hydrogenation

2016 ◽  
Vol 138 (10) ◽  
pp. 3501-3509 ◽  
Author(s):  
Nathan C. Thacker ◽  
Zekai Lin ◽  
Teng Zhang ◽  
James C. Gilhula ◽  
Carter W. Abney ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Earth Abundant ◽  
Metal Organic ◽  
Metal Catalyzed

A visible-light responsive zirconium metal–organic framework for living photopolymerization of methacrylates

RSC Advances ◽  
2016 ◽  
Vol 6 (71) ◽  
pp. 66444-66450 ◽  
Author(s):  
Hongzhu Xing ◽  
Dashu Chen ◽  
Xingyu Li ◽  
Yue Liu ◽  
Chungang Wang ◽  
...  
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Living Radical Polymerization ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

Visible-light-induced living radical polymerization of methacrylates by using robust zirconium metal–organic frameworks.

scholarly journals Free radical and RAFT polymerization of vinyl esters in metal–organic-frameworks

2017 ◽  
Vol 8 (40) ◽  
pp. 6204-6208 ◽  
Author(s):  
Jongkook Hwang ◽  
Hui-Chun Lee ◽  
Markus Antonietti ◽  
Bernhard V. K. J. Schmidt
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Raft Polymerization ◽  
Metal Organic Frameworks ◽  
Vinyl Esters ◽  
Reversible Deactivation ◽  
Metal Organic ◽  
Reversible Deactivation Radical Polymerization ◽  
First Time

In here, the reversible deactivation radical polymerization of vinyl esters inside metal–organic frameworks is presented for the first time.

Visible-light-induced controlled radical polymerization of methacrylates mediated by zirconium-porphryinic metal–organic frameworks

2020 ◽  
Vol 44 (14) ◽  
pp. 5235-5242 ◽  
Author(s):  
Ye Zhang ◽  
Dashu Chen ◽  
Zhifen Guo ◽  
Zihao Wei ◽  
Xiucheng Zhang ◽  
...  
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Metal Organic Frameworks ◽  
Controlled Radical Polymerization ◽  
Metal Organic

Visible-light-induced controlled radical polymerization of methacrylates by using zirconium-porphryinic metal–organic frameworks.

Metal-Organic Frameworks

2021 ◽  
Author(s):  
Lars Öhrström ◽  
Francoise M. Amombo Noa
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic

Substrate templated synthesis of single-phase and uniform Zr-porphyrin-based metal–organic frameworks

2020 ◽  
Vol 7 (1) ◽  
pp. 221-231
Author(s):  
Seong Won Hong ◽  
Ju Won Paik ◽  
Dongju Seo ◽  
Jae-Min Oh ◽  
Young Kyu Jeong ◽  
...  
Keyword(s):  
Chemical Bath Deposition ◽  
Single Phase ◽  
Metal Organic Frameworks ◽  
Templated Synthesis ◽  
Pore Structures ◽  
Phase Pure ◽  
Metal Organic ◽  
Cbd Method

We successfully demonstrate that the chemical bath deposition (CBD) method is a versatile method for synthesizing phase-pure and uniform MOFs by controlling their nucleation stages and pore structures.

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