Free-Molecular-Flow Modulated Synthesis of Hexagonal Boron Nitride Monolayers

2019 ◽  
Vol 19 (12) ◽  
pp. 7007-7014 ◽  
Author(s):  
Weijun Wang ◽  
Run Shi ◽  
Jingwei Wang ◽  
Nan Shen ◽  
Yu Wang ◽  
...  
2016 ◽  
Vol 47 (4) ◽  
pp. 367-388 ◽  
Author(s):  
Alexander Ivanovich Erofeev ◽  
Alexander Petrovich Nikiforov ◽  
Sergei Borisovich Nesterov ◽  
Ramul'ya Amirovna Nezhmetdinova

2019 ◽  
Author(s):  
Matěj Velický ◽  
Sheng Hu ◽  
Colin R. Woods ◽  
Peter S. Toth ◽  
Viktor Zólyomi ◽  
...  

Marcus-Hush theory of electron transfer is one of the pillars of modern electrochemistry with a large body of supporting experimental evidence presented to date. However, some predictions, such as the electrochemical behavior at microdisk electrodes, remain unverified. Herein, we present a study of electron tunneling across a hexagonal boron nitride barrier between a graphite electrode and redox levels in a liquid solution. This was achieved by the fabrication of microdisk electrodes with a typical diameter of 5 µm. Analysis of voltammetric measurements, using two common redox mediators, yielded several electrochemical parameters, including the electron transfer rate constant, limiting current, and transfer coefficient. They show a significant departure from the Butler-Volmer behavior in a clear manifestation of the Marcus-Hush theory of electron transfer. In addition, our system provides a novel experimental platform, which could be applied to address a number of scientific problems such as identification of reaction mechanisms, surface modification, or long-range electron transfer.


Shinku ◽  
1990 ◽  
Vol 33 (3) ◽  
pp. 98-100
Author(s):  
N. LIU ◽  
S. J. PANG

Polymers ◽  
2018 ◽  
Vol 10 (2) ◽  
pp. 206 ◽  
Author(s):  
Elisseos Verveniotis ◽  
Yuji Okawa ◽  
Kenji Watanabe ◽  
Takashi Taniguchi ◽  
Takaaki Taniguchi ◽  
...  

2021 ◽  
Vol 125 (6) ◽  
pp. 1325-1335 ◽  
Author(s):  
Cesar Jara ◽  
Tomáš Rauch ◽  
Silvana Botti ◽  
Miguel A. L. Marques ◽  
Ariel Norambuena ◽  
...  

ACS Photonics ◽  
2021 ◽  
Author(s):  
Prince Khatri ◽  
Ralph Nicholas Edward Malein ◽  
Andrew J. Ramsay ◽  
Isaac J. Luxmoore

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