Cyclometalated Platinum(II) β-Diketonate Complexes as Single Dopants for High-Efficiency White OLEDs: The Relationship between Intermolecular Interactions in the Solid State and Electroluminescent Efficiency

2020 ◽  
Vol 20 (9) ◽  
pp. 6129-6138
Author(s):  
Jisu Kang ◽  
Rena Zaen ◽  
Ki-Min Park ◽  
Kyung Hyung Lee ◽  
Jun Yeob Lee ◽  
...  
2010 ◽  
Vol 41 (1) ◽  
pp. 778 ◽  
Author(s):  
Tukaram K. Hatwar ◽  
Jeffrey P. Spindler ◽  
Marina Kondakova ◽  
David Giesen ◽  
Joseph Deaton ◽  
...  

2009 ◽  
Vol 1212 ◽  
Author(s):  
Sean Xia ◽  
Peter Levermore ◽  
Vadim Adamovich ◽  
Chun Lin ◽  
Raymond C. Kwong ◽  
...  

AbstractWhite OLEDs (WOLEDTMs) fabricated using energy efficient phosphorescent OLED (PHOLEDTM) technology open up exciting new ways to develop efficient white lighting. WOLEDs have the potential to transform the lighting industry. In this presentation, phosphorescent WOLEDs with high conductivity transport layers will be discussed. White light can be generated by partial energy transfer from blue to green and red. Single WOLED stacks are demonstrated that match the Energy Star® lighting color criteria for 2700K and 3000K with high efficiency (˜80 lm/W) and high color rendering indices (˜80). Both devices had operational lifetimes (LT70%) over 30,000 hours measured from an initial luminance of 1,000 cd/m2. Different techniques to improve optical outcoupling will also be discussed.


2018 ◽  
Vol 123 (14) ◽  
pp. 9311-9322 ◽  
Author(s):  
Rohit Bhowal ◽  
Suprakash Biswas ◽  
Athulbabu Thumbarathil ◽  
Apurba L. Koner ◽  
Deepak Chopra

Author(s):  
Hagos Tesfay Kidanu ◽  
Chin-Ti Chen

Two platinum complexes PBSNND and AtFNND have been used to achieve high efficiency (EQEmax of 12.9% and 13.7%) hybrid white OLEDs with an ultrathin and singly doped phosphorescence emitting layer, respectively.


Author(s):  
P. G. Kotula ◽  
D. D. Erickson ◽  
C. B. Carter

High-resolution field-emission-gun scanning electron microscopy (FESEM) has recently emerged as an extremely powerful method for characterizing the micro- or nanostructure of materials. The development of high efficiency backscattered-electron detectors has increased the resolution attainable with backscattered-electrons to almost that attainable with secondary-electrons. This increased resolution allows backscattered-electron imaging to be utilized to study materials once possible only by TEM. In addition to providing quantitative information, such as critical dimensions, SEM is more statistically representative. That is, the amount of material that can be sampled with SEM for a given measurement is many orders of magnitude greater than that with TEM.In the present work, a Hitachi S-900 FESEM (operating at 5kV) equipped with a high-resolution backscattered electron detector, has been used to study the α-Fe2O3 enhanced or seeded solid-state phase transformations of sol-gel alumina and solid-state reactions in the NiO/α-Al2O3 system. In both cases, a thin-film cross-section approach has been developed to facilitate the investigation. Specifically, the FESEM allows transformed- or reaction-layer thicknesses along interfaces that are millimeters in length to be measured with a resolution of better than 10nm.


1994 ◽  
Author(s):  
Todd S. Rose ◽  
James S. Swenson ◽  
Renny A. Fields

Compounds ◽  
2021 ◽  
Vol 1 (2) ◽  
pp. 58-74
Author(s):  
Emmanuel Aubert ◽  
Emmanuel Wenger ◽  
Paola Peluso ◽  
Victor Mamane

Non-symmetrical chiral 4,4′-bipyridines have recently found interest in organocatalysis and medicinal chemistry. In this regard, the development of efficient methods for their synthesis is highly desirable. Herein, a series of non-symmetrical atropisomeric polyhalogenated 4,4′-bipyridines were prepared and further functionalized by using cross-coupling reactions. The desymmetrization step is based on the N-oxidation of one of the two pyridine rings of the 4,4′-bipyridine skeleton. The main advantage of this methodology is the possible post-functionalization of the pyridine N-oxide, allowing selective introduction of chlorine, bromine or cyano groups in 2- and 2′-postions of the chiral atropisomeric 4,4′-bipyridines. The crystal packing in the solid state of some newly prepared derivatives was analyzed and revealed the importance of halogen bonds in intermolecular interactions.


Energies ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 1200
Author(s):  
Yong-Joon Jun ◽  
Seung-ho Ahn ◽  
Kyung-Soon Park

The Green Remodeling Project under South Korea’s Green New Deal policy is a government-led project intended to strengthen the performance sector directly correlated with energy performance among various elements of improvement applicable to building remodeling by replacing insulation materials, introducing new and renewable energy, introducing high-efficiency equipment, etc., with public buildings taking the lead in green remodeling in order to induce energy efficiency enhancement in private buildings. However, there is an ongoing policy that involves the application of a fragmentary value judgment criterion, i.e., whether to apply technical elements confined to the enhancement of the energy performance of target buildings and the prediction of improvement effects according thereto, thus resulting in the phenomenon of another important value criterion for green remodeling, i.e., the enhancement of the occupant (user) comfort performance of target buildings as one of its purposes, being neglected instead. In order to accurately grasp the current status of these problems and to promote ‘expansion of the value judgment criteria for green remodeling’ as an alternative, this study collected energy usage data of buildings actually used by public institutions and then conducted a total analysis. After that, the characteristics of energy usage were analyzed for each of the groups of buildings classified by year of completion, thereby carrying out an analysis of the correlation between the non-architectural elements affecting the actual energy usage and the actual energy usage data. The correlation between the improvement performance of each technical element and the actual improvement effect was also analyzed, thereby ascertaining the relationship between the direction of major policy strategies and the actual energy usage. As a result of the relationship analysis, it was confirmed that the actual energy usage is more affected by the operating conditions of the relevant building than the application of individual strategic elements such as the performance of the envelope insulation and the performance of the high-efficiency system. In addition, it was also confirmed that the usage of public buildings does not increase in proportion to their aging. The primary goal of reducing energy usage in target buildings can be achieved if public sector (government)-led green remodeling is pushed ahead with in accordance with biased value judgment criteria, just as in the case of a campaign to refrain from operating cooling facilities in aging public buildings. However, it was possible to grasp through the progress of this study that the remodeling may also result in the deterioration of environmental comfort and stability, such as the numerical value of the indoor thermal environment. The results of this study have the significance of providing basic data for pushing ahead with a green remodeling policy in which the value judgment criteria for aging existing public buildings are more expanded, and it is necessary to continue research in such a direction that the quantitative purpose of green remodeling, which is to reduce energy usage in aging public buildings, and its qualitative purpose, which is to enhance their environmental performance for occupants’ comfort, can be mutually balanced and secured at the same time.


2012 ◽  
Vol 40 (10) ◽  
pp. 2569-2577 ◽  
Author(s):  
Seung-Bok Ok ◽  
Hong-Je Ryoo ◽  
Sung-Roc Jang ◽  
Suk-Ho Ahn ◽  
Gennadi Goussev

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