Determination of Chemical Valence State by X-ray Emission Analysis Using Electron Beam Instruments:  Pitfalls and Promises

1999 ◽  
Vol 71 (14) ◽  
pp. 2714-2724 ◽  
Author(s):  
John T. Armstrong
2019 ◽  
Vol 34 (7) ◽  
pp. 1497-1502 ◽  
Author(s):  
Malte Wansleben ◽  
Claudia Zech ◽  
Cornelia Streeck ◽  
Jan Weser ◽  
Christoph Genzel ◽  
...  

Liquid-metal jet X-ray sources promise to deliver high photon fluxes, which are unprecedented for laboratory based X-ray sources, because the regenerating liquid-metal anode is less sensitive to damage caused by an increased electron beam power density.


1984 ◽  
Vol 39 (5) ◽  
pp. 643-648 ◽  
Author(s):  
Hans-Friedrich Klein ◽  
Joachim Groß ◽  
Hubert Witty ◽  
Dietmar Neugebauer

Mononuclear cobalt(0) complexes containing diolefin and trimethylphosphane ligands Co(cycloocta-1,5-diene)(PMe3)2 and Co[(CH2=CHMe2Si)2O](PMe3)2 are obtained from CoCl2 by reaction with magnesium in the presence of the ligands or by substitution of cobalt(olefin)tris- (trimethylphosphane) with diolefin. Chemical and spectroscopic properties confirm the para- magnetic valence state of the compounds in solution. An X-Ray crystal structure determination of Co[(CH2=CHMe2Si)2O](PMe3)2 shows a tetrahedral arrangement of ligand functions around the cobalt atom. With butadiene a diamagnetic dinuclear complex [Co(C4H6)(PMe3)3]2 is obtained containing π-allyl co-ordination of two Co(PMe3)3 units to a linear dimer of butadiene


1985 ◽  
Vol 34 (12) ◽  
pp. 766-771 ◽  
Author(s):  
Yoshiko MIYAGAWA ◽  
Kazuo SAITO ◽  
Hiroaki NIWA ◽  
Toshio ISHIZUKA ◽  
Soji MIYAGAWA

1977 ◽  
Vol 49 (3) ◽  
pp. 432-435 ◽  
Author(s):  
Arthur. Mittler ◽  
Barry K. Barnes ◽  
Robert. Litman ◽  
Frantz. Holton ◽  
Eugene F. Barry

Author(s):  
A. N. Artemiev ◽  
A. A. Snigirev ◽  
V. N. Korchuganov ◽  
A. G. Valentinov ◽  
V. V. Kvardakov ◽  
...  

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