scholarly journals Using Comprehensive Two-Dimensional Gas Chromatography Retention Indices To Estimate Environmental Partitioning Properties for a Complete Set of Diesel Fuel Hydrocarbons

2005 ◽  
Vol 77 (22) ◽  
pp. 7172-7182 ◽  
Author(s):  
J. Samuel Arey ◽  
Robert K. Nelson ◽  
Li Xu ◽  
Christopher M. Reddy
Keyword(s):  
Gas Chromatography ◽  
Diesel Fuel ◽  
Retention Indices ◽  
Two Dimensional ◽  
Complete Set ◽  
Fuel Hydrocarbons

scholarly journals Analysis of diesel samples using comprehensive two-dimensional gas chromatography (GCXGC/TOFMS) to better understand the chemistry of their lubricating properties

2011 ◽  
Vol 30 (1) ◽  
Author(s):  
Elize Smit
Keyword(s):  
Gas Chromatography ◽  
Multivariate Statistics ◽  
Diesel Fuel ◽  
Metal Surfaces ◽  
Fuel Injection ◽  
Close Contact ◽  
Two Dimensional ◽  
Diesel Fuel Injection ◽  
Lubricating Properties

Lubricity is the ability of a substance to prevent wear in a system where metal surfaces are in close contact. Diesel fuel injection systems rely on the fuel itself for lubrication. GCXGC/ TOFMS and multivariate statistics were used to investigate which chemical classes in a diesel fuel contribute to its lubricity.

Property Prediction of Diesel Fuel Based on the Composition Analysis Data by two-Dimensional Gas Chromatography

2018 ◽  
Vol 32 (3) ◽  
pp. 3760-3774 ◽  
Author(s):  
Ramachandra Chakravarthy ◽  
Chhayakanta Acharya ◽  
Anilkumar Savalia ◽  
Ganesh N. Naik ◽  
Asit Kumar Das ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Diesel Fuel ◽  
Analysis Data ◽  
Composition Analysis ◽  
Two Dimensional ◽  
Property Prediction

scholarly journals Comprehensive two-dimensional gas chromatography (GC×GC) measurements of volatile organic compounds in the atmosphere

2003 ◽  
Vol 3 (1) ◽  
pp. 1139-1181 ◽  
Author(s):  
X. Xu ◽  
L. L. P. van Stee ◽  
J. Williams ◽  
J. Beens ◽  
M. Adahchour ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Retention Indices ◽  
Two Dimensional ◽  
Ground Station ◽  
Flame Ionization ◽  
Peak Identification ◽  
Volatile Organic

Abstract. During the MINOS campaign in August 2001 comprehensive two-dimensional gas chromatography (GC×GC) was applied to the in situ measurements of atmospheric volatile organic compounds (VOCs) at the Finokalia ground station, Crete. The measurement system employs a thermal desorption unit for on-line sampling and injection, and a GCxGC separation system equipped with a flame ionization detector (FID) for detection. The system was optimized to resolve C7−C14 organic components. Two-dimensional chromatograms from measurements of Finokalia air samples show several hundred well-separated peaks. To facilitate peak identification, cartridge samples collected at Finokalia were analyzed using the same GC×GC system coupled with a time-of-flight mass spectrometer (TOF-MS). The resulting mass spectra were deconvoluted and compared to spectra from a database for tentative peak identification. About 650 peaks have been identified in the two-dimensional plane, with significant signal/noise ratios (>100) and high spectra similarities (>800). By comparing observed retention indices with those found in the literature, 235 of the identifications have been confirmed. 150 of the confirmed compounds show up in the C7−C14 range of the chromatogram from the in situ measurement. However, at least as many peaks remain unidentified. For quantification of the GCxGC measurements, peak volumes of measured compounds have been integrated and externally calibrated using a standard gas mixture.

Regression algorithm for calculating second-dimension retention indices in comprehensive two-dimensional gas chromatography

2018 ◽  
Vol 1569 ◽  
pp. 178-185 ◽  
Author(s):  
D.M. Mazur ◽  
I.G. Zenkevich ◽  
V.B. Artaev ◽  
O.V. Polyakova ◽  
A.T. Lebedev
Keyword(s):  
Gas Chromatography ◽  
Retention Indices ◽  
Two Dimensional

scholarly journals Comprehensive two-dimensional gas chromatography (GC × GC) measurements of volatile organic compounds in the atmosphere

2003 ◽  
Vol 3 (3) ◽  
pp. 665-682 ◽  
Author(s):  
X. Xu ◽  
L. L. P. Stee ◽  
J Williams ◽  
J. Beens ◽  
M. Adahchour ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Retention Indices ◽  
Two Dimensional ◽  
Ground Station ◽  
Peak Identification ◽  
Volatile Organic ◽  
Gc X Gc

Abstract. During the MINOS campaign in August 2001 comprehensive two-dimensional gas chromatography (GC x GC) was applied to the in situ measurements of atmospheric volatile organic compounds (VOCs) at the Finokalia ground station, Crete. The measurement system employs a thermal desorption unit for on-line sampling and injection, and a GC x GC separation system equipped with a flame ionization detector (FID) for detection. The system was optimized to resolve C7-C14 organic components. Two-dimensional chromatograms from measurements of Finokalia air samples show several hundred well-separated peaks. To facilitate peak identification, cartridge samples collected at Finokalia were analyzed using the same GC x GC system coupled with a time-of-flight mass spectrometer (TOF-MS). The resulting mass spectra were deconvoluted and compared to spectra from a database for tentative peak identification. About 650 peaks have been identified in the two-dimensional plane, with significant signal/noise ratios (>100) and high spectra similarities (>800). By comparing observed retention indices with those found in the literature, 235 of the identifications have been confirmed. 150 of the confirmed compounds show up in the C7-C14 range of the chromatogram from the in situ measurement. However, at least as many peaks remain unidentified. For quantification of the GC x GC measurements, peak volumes of measured compounds have been integrated and externally calibrated using a standard gas mixture.

A multi-location peak parking approach for calculation of second dimensional retention indices for improved volatile compound identification with cryogen-free comprehensive heart-cut two-dimensional gas chromatography

2021 ◽  
Vol 13 (1) ◽  
pp. 124-132
Author(s):  
Pannipa Janta ◽  
Duangkamol Pinyo ◽  
Yamonporn Yodta ◽  
Porames Vasasiri ◽  
Meinolf Weidenbach ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Volatile Compound ◽  
Retention Indices ◽  
Two Dimensional ◽  
Compound Identification ◽  
Multidimensional Gas Chromatography ◽  
Cryogenic Trapping ◽  
Trapping Device ◽  
Peak Parking

Comprehensive heart-cut multidimensional gas chromatography (CH/C MDGC) without a cryogenic trapping device was developed with an approach for calculation of first and second dimensional retention indices (1I and 2I).

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