Square Wave Voltammetry of Reversible Systems at Ring Microelectrodes. 1. Theoretical Study

1994 ◽  
Vol 66 (4) ◽  
pp. 557-565 ◽  
Author(s):  
Dennis E. Tallman
Keyword(s):  
Square Wave Voltammetry ◽  
Theoretical Study ◽  
Reversible Systems ◽  
Square Wave ◽  
Wave Voltammetry

scholarly journals Protein-film voltammetry: A theoretical study of the temperature effect using square-wave voltammetry

2008 ◽  
Vol 137 (1) ◽  
pp. 49-55 ◽  
Author(s):  
Rubin Gulaboski ◽  
Milivoj Lovrić ◽  
Valentin Mirčeski ◽  
Ivan Bogeski ◽  
Markus Hoth
Keyword(s):  
Temperature Effect ◽  
Square Wave Voltammetry ◽  
Theoretical Study ◽  
Protein Film ◽  
Square Wave ◽  
Protein Film Voltammetry ◽  
Wave Voltammetry

Facile and Fast Detection of Genistein in Derris scandens by Square Wave Voltammetry using a Cobalt(II) Phthalocyanine-Modified Screen-Printed Electrochemical Sensor

2020 ◽  
Vol 16 (3) ◽  
pp. 341-348
Author(s):  
Surinya Traipop ◽  
Suchada Chuanuwatanakul ◽  
Orawon Chailapakul ◽  
Eakkasit Punrat
Keyword(s):  
Electrochemical Sensor ◽  
Square Wave Voltammetry ◽  
Silver Chloride ◽  
Reference Electrode ◽  
High Sensitivity ◽  
Plastic Substrate ◽  
Fast Analysis ◽  
Square Wave ◽  
Wave Voltammetry ◽  
Screen Printed

Background: Recently, Derris scandens, a Thai herbal medicine with anti-inflammatory activity, is widely used as beverage and supplementary food. When the traditional medicine is a choice for health therapy, the simple and reliable equipment is required to control the suitable consuming amount of the active component. Objective: To develop the electrochemical sensor for genistein determination in Derris scandens with high sensitivity and rapid operation. Methods: An in-house screen-printed electrochemical sensor consisting of a three-electrode system was developed for genistein determination. A silver/silver chloride (Ag/AgCl) reference electrode, a carbon counter electrode and a carbon working electrode were prepared on a 0.3-mm-thick plastic substrate by the screen-printing technique using conductive ink. The dimensions of each sensor were 2.5×1.0 cm. Only 50 µL of sample solution was required on this device for the determination of genistein concentration by rapid response square wave voltammetry. Results: The oxidation peak of genistein appeared with good response in acidic media at a peak potential of 0.6 V. Moreover, the signal was enhanced by modifying the conductive carbon ink with cobalt( II) phthalocyanine. Under the optimized conditions, the linear range was found to be 2.5-150 µM and the detection limit was 1.5 µM. Moreover, the small volume extraction was successfully developed without any further pre-concentration. This proposed method was applied to determine genistein in Derris scandens with satisfying results. Conclusion: The proposed method is promising as an alternative method for genistein determination with facile and fast analysis.

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