Electro-conductive composite fibers by melt spinning of polypropylene/polyamide/carbon nanotubes

2011 ◽  
Vol 161 (15-16) ◽  
pp. 1731-1737 ◽  
Author(s):  
Saleh Hooshmand ◽  
Azadeh Soroudi ◽  
Mikael Skrifvars
2012 ◽  
Vol 217-219 ◽  
pp. 567-570
Author(s):  
Dan Wang ◽  
Ke Qing Han ◽  
Wen Hui Zhang ◽  
Bin Yan ◽  
Yin Cai Tian ◽  
...  

Polyacrylonitrile(PAN)/multi-walled carbon nanotubes (MWNTs) composite fibers were prepared by melt spinning using ionic liquids (ILs) as a plasticizer. The effects of different MWNTs contents on the morphology, mechanical and conductive properties of the composite fibers were discussed. The results showed that property improvements have occurred with the adding of MWNTs. When the content of MWNTs reached 10%, the conductivity of PAN/MWNTs was 8.65×10-3 S/cm.


2020 ◽  
Vol 2020 ◽  
pp. 1-10
Author(s):  
Wenwen Yu ◽  
Fei Yang ◽  
Lei Wang ◽  
Yongli Liu ◽  
Jiangao Shi

The starch-based fishing composite fibers were prepared by one-step reactive extrusion and melt spinning. The effects of starch contents on the microstructural, thermal, dynamic mechanical, and mechanical properties of starch-based composite fibers were studied. And the degradation behaviors in soil of the fibers were also investigated. The compatibility between starch and HDPE is improved significantly by grafting maleic anhydride (MA) using one-step reactive blending extrusion. As the starch content increased, the melting temperature and the crystallinity of the fibers gradually decreased due to fluffy internal structures. Dynamic mechanical analysis showed that the transition peak α in the high-temperature region was gradually weakened and narrowed with increasing starch content; moreover, a shoulder appeared on the low-temperature side of the α peak was assigned to the β-relaxation related to starch phase. In addition, the mechanical results showed the significant decrease in the breaking strength and increase in the elongation at break of the starch-based composite fibers as the starch content increased. After degradation in soil for 5 months, the surface of the composite fibers had been deteriorated, while flocculent layers were observed and a large number of microfibers appeared. And the weight loss rate of the starch-based composite fibers (5.2~34.8%) significantly increased with increasing starch content (50~90 wt%).


2017 ◽  
Vol 58 (1) ◽  
pp. 37-45 ◽  
Author(s):  
Yizhe Wei ◽  
Dengpan Lai ◽  
Liming Zou ◽  
Xinlong Ling ◽  
Hongwei Lu ◽  
...  

2021 ◽  
pp. 004051752110134
Author(s):  
Jian Xing ◽  
Shunhua Dai ◽  
Zhong Chen ◽  
Yongkang Wang ◽  
Zhenghua Zhang ◽  
...  

Masterbatches of polyphenylene sulfide (PPS)/organic montmorillonite (MMT) composites were produced via melt blending. A self-made spinning equipment was then used to produce the PPS/organic MMT composite fibers by melt spinning directly from the masterbatches. X-ray diffractometer and transmission electron microscope were used to examine the dispersibility of organic MMT. The morphology, tensile property, crystallization behavior, and oxidative stability of PPS fibers were investigated. The results indicated that organic MMT could be uniformly distributed in the PPS matrix to form a mixed dispersion of intercalated and exfoliated structure and influence the longitudinal surface morphology of fibers to become rough. The roughness of composite fibers surface was proportional to the content of organic MMT. The organic MMT nanolayers could act as the heterogeneous nucleating agents to improve the crystallization, and the crystallity of composite fibers increased with the increase of organic MMT content. The breaking strength of composite fibers first increased and then decreased by increasing the amount of organic MMT. After the oxidation treatment, the breaking strength of neat PPS fibers and composite fibers declined, but the degree of breaking strength loss for composite fibers is lower than that of neat PPS fibers. The dynamic oxidation induction temperature of composite fibers also showed a significant increase by adding organic MMT. Moreover, the addition of organic MMT could limit the chemical combination of element sulfur and oxygen, retard the generation of sulfoxide groups, and induce the conversion of sulfur atoms from C-S bond to sulfone for improving oxidative stability.


2011 ◽  
Vol 6 (3) ◽  
pp. 155892501100600 ◽  
Author(s):  
Eric Devaux ◽  
Carole Aubry ◽  
Christine Campagne ◽  
Maryline Rochery

Polylactide (PLA) was mixed with 4 wt.% of carbon nanotubes (CNTs) to produce electrical conductive multifilament yarns by melt spinning process for humidity detection. Thanks to a variation of electrical conductivity, this flexible sensor could detect the moisture presence. The introduction of plasticizer was necessary to ensure higher fluidity and drawability of the blend during the spinning process. The plasticizer modifies the crystallinity and the mechanical properties of the yarns. The effectiveness of this sensor (PLA/4 wt.% CNTs fibres) sensitive to humidity, is optimal when the spinning conditions are adapted. In this way, the temperature and the rate of the drawing roll were reduced. The influence of these parameters on the crystallinity, the mechanical properties and the sensitivity of the yarns were studied. Once the appropriate spinning conditions found, one humidity sensitive yarn was processed and the repeatability and efficient reversibility of its sensitivity were highlighted.


2018 ◽  
Vol 1 (2) ◽  
pp. 160-168 ◽  
Author(s):  
Caitlyn M. Clarkson ◽  
Sami M. El Awad Azrak ◽  
Reaz Chowdhury ◽  
Shoumya Nandy Shuvo ◽  
James Snyder ◽  
...  

2008 ◽  
Vol 19 (24) ◽  
pp. 245703 ◽  
Author(s):  
Vijaya K Rangari ◽  
Mohammed Yousuf ◽  
Shaik Jeelani ◽  
Merlyn X Pulikkathara ◽  
Valery N Khabashesku

2012 ◽  
Vol 7 (3) ◽  
pp. 155892501200700 ◽  
Author(s):  
Alexis Laforgue ◽  
Michel F. Champagne ◽  
Jean Dumas ◽  
Lucie Robitaille

Polypropylene-multiwalled carbon nanotube (PP-CNT) composites were spun into fibers using melt-spinning methods. The CNT content was varied by diluting the commercial masterbatch with a low viscosity PP homopolymer grade. The conductivity, as well as the mechanical properties, of the fibers were systematically tested in order to find the optimal formulation. Post-stretching was used to improve the mechanical properties of the fibers as well as to decrease the fiber diameters. Fibers having a conductivity of 0.4 S/cm, a Young's modulus of 5.4 GPa and a tensile strength of 250 MPa were obtained after a three-fold stretching. Trilayer coaxial fibers similar to data transfer coaxial cables (two conductive layers separated by an insulating layer) were then produced in a one-step melt-spinning method using a specially designed die, followed by solid state post-stretching.


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