Supercritical CO2 extraction of Helichrysum italicum: Influence of CO2 density and moisture content of plant material

2011 ◽  
Vol 57 (2) ◽  
pp. 129-136 ◽  
Author(s):  
Jasna Ivanovic ◽  
Mihailo Ristic ◽  
Dejan Skala
Keyword(s):  
Moisture Content ◽  
Supercritical Co2 ◽  
Plant Material ◽  
Supercritical Co2 Extraction ◽  
Co2 Density

scholarly journals Supercritical CO2 Extraction of Organic Solvents from Flunisolide and Fluticasone Propionate

Pharmaceutics ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 612
Author(s):  
Lucia Baldino ◽  
Mariarosa Scognamiglio ◽  
Ernesto Reverchon
Keyword(s):  
Fluticasone Propionate ◽  
Organic Solvents ◽  
Supercritical Co2 ◽  
Supercritical Co2 Extraction ◽  
Solvent Residues ◽  
Co2 Flow ◽  
Final Residue ◽  
Work Class ◽  
Residual Organic Solvents ◽  
Co2 Density

In this work, Class 2 and Class 3 solvents contained in two corticosteroids, flunisolide (Fluni) and fluticasone propionate (Fluti), were reduced to a few ppm by supercritical CO2 extraction. The process was carried out at pressures from 80 to 200 bar, temperatures of 40 °C and 80 °C, and at a fixed CO2 flow rate of 0.7 kg/h. The results demonstrated that CO2 density is the key parameter influencing the extraction kinetics and the solvent final residue. In particular, in the range investigated, optimal pressure and temperature conditions for the extraction of residual organic solvents were found working at 200 bar and 40 °C, which corresponds to a CO2 density of 0.840 g/cm3. Operating in this way, total organic solvent residues were reduced from 13,671 ppm and 326 ppm to 12 ppm and 10 ppm for Fluni and Fluti, respectively.

scholarly journals Optimized Supercritical CO2 Extraction Enhances the Recovery of Valuable Lipophilic Antioxidants and Other Constituents from Dual-Purpose Hop (Humulus lupulus L.) Variety Ella

Antioxidants ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 918
Author(s):  
Nóra Emilia Nagybákay ◽  
Michail Syrpas ◽  
Vaiva Vilimaitė ◽  
Laura Tamkutė ◽  
Audrius Pukalskas ◽  
...  
Keyword(s):  
Supercritical Co2 ◽  
Antioxidant Properties ◽  
Extraction Yield ◽  
Biologically Active ◽  
High Yield ◽  
Acid Extraction ◽  
Supercritical Co2 Extraction ◽  
Bioactive Constituents ◽  
Total Extract

The article presents the optimization of supercritical CO2 extraction (SFE-CO2) parameters using response surface methodology (RSM) with central composite design (CCD) in order to produce single variety hop (cv. Ella) extracts with high yield and strong in vitro antioxidant properties. Optimized SFE-CO2 (37 MPa, 43 °C, 80 min) yielded 26.3 g/100 g pellets of lipophilic fraction. This extract was rich in biologically active α- and β-bitter acids (522.8 and 345.0 mg/g extract, respectively), and exerted 1481 mg TE/g extract in vitro oxygen radical absorbance capacity (ORAC). Up to ~3-fold higher extraction yield, antioxidant recovery (389.8 mg TE/g pellets) and exhaustive bitter acid extraction (228.4 mg/g pellets) were achieved under the significantly shorter time compared to the commercially used one-stage SFE-CO2 at 10–15 MPa and 40 °C. Total carotenoid and chlorophyll content was negligible, amounting to <0.04% of the total extract mass. Fruity, herbal, spicy and woody odor of extracts could be attributed to the major identified volatiles, namely β-pinene, β-myrcene, β-humulene, α-humulene, α-selinene and methyl-4-decenoate. Rich in valuable bioactive constituents and flavor compounds, cv. Ella hop SFE-CO2 extracts could find multipurpose applications in food, pharmaceutical, nutraceutical and cosmetics industries.

scholarly journals Supercritical CO2 extraction of Moroccan argan (Argania spinosa L.) oil: Extraction kinetics and solubility determination

2021 ◽  
Vol 46 ◽  
pp. 101458
Author(s):  
Adil Mouahid ◽  
Isabelle Bombarda ◽  
Magalie Claeys-Bruno ◽  
Sandrine Amat ◽  
Emmanuelle Myotte ◽  
...  
Keyword(s):  
Supercritical Co2 ◽  
Oil Extraction ◽  
Supercritical Co2 Extraction ◽  
Extraction Kinetics ◽  
Argania Spinosa ◽  
Solubility Determination

scholarly journals Supercritical CO2 Extraction of Palladium Oxide from an Aluminosilicate-Supported Catalyst Enhanced by a Combination of Complexing Polymers and Piperidine

Molecules ◽  
2021 ◽  
Vol 26 (3) ◽  
pp. 684
Author(s):  
Andrea Ruiu ◽  
Bernhard Bauer-Siebenlist ◽  
Marin Senila ◽  
W. S. Jennifer Li ◽  
Karine Seaudeau-Pirouley ◽  
...  
Keyword(s):  
Energy Saving ◽  
Supercritical Co2 ◽  
Supported Catalyst ◽  
Precious Metals ◽  
Palladium Oxide ◽  
Supercritical Co2 Extraction ◽  
Wide Range

Precious metals, in particular Pd, have a wide range of applications in industry. Due to their scarcity, precious metals have to be recycled, preferably with green and energy-saving recycling processes. In this article, palladium extraction from an aluminosilicate-supported catalyst, containing about 2 wt% (weight%) of Pd (100% PdO), with supercritical CO2 (scCO2) assisted by complexing polymers is described. Two polymers, p(FDA)SH homopolymer and p(FDA-co-DPPS) copolymer (FDA: 1,1,2,2-tetrahydroperfluorodecyl acrylate; DPPS: 4-(diphenylphosphino)styrene), were tested with regards to their ability to extract palladium. Both polymers showed relatively low extraction conversions of approximately 18% and 30%, respectively. However, the addition of piperidine as activator for p(FDA-co-DPPS) allowed for an increase in the extraction conversion of up to 60%.

Supercritical CO2 regeneration of activated carbon loaded with organic adsorbates

1997 ◽  
Vol 35 (7) ◽  
pp. 261-268 ◽  
Author(s):  
Kazuyuki Chihara ◽  
Kanji Oomori ◽  
Takao Oono ◽  
Yosuke Mochizuki
Keyword(s):  
Activated Carbon ◽  
Cost Estimation ◽  
Supercritical Co2 ◽  
Adsorption Equilibrium ◽  
Equilibrium Constants ◽  
Adsorption Dynamics ◽  
Boiling Points ◽  
Organic Adsorbates ◽  
Carbon Regeneration ◽  
Co2 Density

Supercritical CO2 regeneration is one of the possibilities for spent carbon regeneration loaded with some organics. Here, adsorption equilibrium and adsorption dynamics were evaluated for some typical organic pollutants under some supercritical CO2 conditions. A supercritical CO2 chromatograph packed with activated carbon (F-400, CAL) was used to detect the pulse responses of organics, which were analyzed by moment analysis. Adsorption equilibrium constants of some organics varied with CO2 density and their boiling points. Possibility of regeneration of each substance was discussed. Cost estimation was necessary and was the key point of this technique.

Sign in / Sign up

Export Citation Format

Share Document