Lattice strain dependent on ionic conductivity of Ce0.8+xY0.2−2xSrxO1.9 (x = 0–0.08) electrolyte

2016 ◽  
Vol 296 ◽  
pp. 85-89 ◽  
Author(s):  
X.W. Wang ◽  
J.G. Chen ◽  
Y.W. Tian ◽  
X.E. Wang ◽  
B.H. Zhang ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Lattice Strain ◽  
Strain Dependent

scholarly journals The effects of lattice strain, dislocations, and microstructure on the transport properties of YSZ films

2017 ◽  
Vol 19 (22) ◽  
pp. 14319-14336 ◽  
Author(s):  
George F. Harrington ◽  
Andrea Cavallaro ◽  
David W. McComb ◽  
Stephen J. Skinner ◽  
John A. Kilner
Keyword(s):  
Ionic Conductivity ◽  
Transport Properties ◽  
Lattice Strain

We report that lattice strain and dislocations play a negligible role on the ionic conductivity of YSZ films.

Lattice strain dependent optical transitions in Ho3+-ion doped barium strontium titanate thin films

2007 ◽  
Vol 20 (S1) ◽  
pp. 190-194 ◽  
Author(s):  
Tianjin Zhang ◽  
Animesh Jha ◽  
Shaoxiong Shen ◽  
Jun Wang ◽  
Ruikun Pan ◽  
...  
Keyword(s):  
Thin Films ◽  
Strontium Titanate ◽  
Barium Strontium Titanate ◽  
Lattice Strain ◽  
Optical Transitions ◽  
Barium Strontium ◽  
Strain Dependent

The Direct Measurement of Ionic Piezoresistance

2015 ◽  
Vol 1730 ◽  
Author(s):  
Stuart N. Cook ◽  
Harry L. Tuller
Keyword(s):  
High Temperature ◽  
Ionic Conductivity ◽  
Solid Electrolytes ◽  
Strain State ◽  
Lattice Strain ◽  
Quantitative Measure ◽  
Ionic Conductors ◽  
Novel Technique ◽  
Conducting Materials ◽  
Fundamental Understanding

ABSTRACTIonic piezoresistance, the effect of lattice strain on ionic conductivity, is an important concept that needs to be harnessed to engineer the next generation of fast ionic conductors. To date there have been many reports of strain affecting changes in the level of ionic conductivity in solid electrolytes. The fundamental understanding is, however, still lacking, with limited experimental quantification of the magnitude of the effect. Here, we propose using the ionic piezoresistive coefficient, the constant of proportionality between the strain state and the change in conductivity, as a quantitative measure of this effect and detail a novel technique we have developed to quantify this in high temperature ionically conducting materials.

Electrical Conductivity of Ceria Co-Doped with Zr and Re (Re=La,Y)

2008 ◽  
Vol 368-372 ◽  
pp. 250-252
Author(s):  
Bin Li ◽  
Zheng Hui Chen ◽  
Wei Pan
Keyword(s):  
Electrical Conductivity ◽  
Ionic Conductivity ◽  
General Formula ◽  
Single Phase ◽  
Lattice Strain ◽  
Sol Gel ◽  
Fluorite Structure ◽  
Lattice Parameter ◽  
Gel Method ◽  
Co Doped

The series of powders with the general formula of Ce0.8-xZrxLa0.2O1.9 (x=0, 0.05, 0.10, 0.15) and Ce0.8-xZrxY0.2O1.9 (x=0, 0.05, 0.10, 0.15) were synthesized by the sol-gel method. The samples sintered at 1500°C all possess the single phase with cubic fluorite structure. The lattice parameter and the ionic conductivity decrease with increasing the content of Zr. However, the ionic conductivity of ceria co-doped with Zr and La reduces with decreasing the lattice strain.

Mouse paternal-RNAs initiate pattern of metabolic disorders in a strain dependent manner

2016 ◽  
Author(s):  
Guzide Satir Basaran ◽  
Yagut Akbarova ◽  
Kezban Korkmaz ◽  
Kursad Unluhizarci ◽  
Francois Cuzin ◽  
...  
Keyword(s):  
Metabolic Disorders ◽  
Dependent Manner ◽  
Strain Dependent

Atomistic Simulation Study of Controlled Nanostructure Patterning

2003 ◽  
Vol 775 ◽  
Author(s):  
Byeongchan Lee ◽  
Kyeongjae Cho
Keyword(s):  
Diffusion Barrier ◽  
Atomistic Simulation ◽  
Degrees Of Freedom ◽  
Embedded Atom Method ◽  
Surface Kinetics ◽  
Bulk Properties ◽  
Embedded Atom ◽  
Kinetics Of ◽  
Dissociation Barrier ◽  
Strain Dependent

AbstractWe investigate the surface kinetics of Pt using the extended embedded-atom method, an extension of the embedded-atom method with additional degrees of freedom to include the nonbulk data from lower-coordinated systems as well as the bulk properties. The surface energies of the clean Pt (111) and Pt (100) surfaces are found to be 0.13 eV and 0.147 eV respectively, in excellent agreement with experiment. The Pt on Pt (111) adatom diffusion barrier is found to be 0.38 eV and predicted to be strongly strain-dependent, indicating that, in the compressive domain, adatoms are unstable and the diffusion barrier is lower; the nucleation occurs in the tensile domain. In addition, the dissociation barrier from the dimer configuration is found to be 0.82 eV. Therefore, we expect that atoms, once coalesced, are unlikely to dissociate into single adatoms. This essentially tells that by changing the applied strain, we can control the patterning of nanostructures on the metal surface.

How Certain Are the Reported Ionic Conductivities of Thiophosphate-Based Solid Electrolytes? an Interlaboratory Study

2020 ◽  
Author(s):  
Saneyuki Ohno ◽  
Tim Bernges ◽  
Johannes Buchheim ◽  
Marc Duchardt ◽  
Anna-Katharina Hatz ◽  
...  
Keyword(s):  
Standard Deviation ◽  
Ionic Conductivity ◽  
Relative Standard Deviation ◽  
Solid Electrolytes ◽  
Ionic Conductivities ◽  
Ionic Conductors ◽  
Energy Storage Devices ◽  
Activation Barriers ◽  
Storage Devices ◽  
Relative Standard

<p>Owing to highly conductive solid ionic conductors, all-solid-state batteries attract significant attention as promising next-generation energy storage devices. A lot of research is invested in the search and optimization of solid electrolytes with higher ionic conductivity. However, a systematic study of an <i>interlaboratory reproducibility</i> of measured ionic conductivities and activation energies is missing, making the comparison of absolute values in literature challenging. In this study, we perform an uncertainty evaluation via a Round Robin approach using different Li-argyrodites exhibiting orders of magnitude different ionic conductivities as reference materials. Identical samples are distributed to different research laboratories and the conductivities and activation barriers are measured by impedance spectroscopy. The results show large ranges of up to 4.5 mScm<sup>-1</sup> in the measured total ionic conductivity (1.3 – 5.8 mScm<sup>-1</sup> for the highest conducting sample, relative standard deviation 35 – 50% across all samples) and up to 128 meV for the activation barriers (198 – 326 meV, relative standard deviation 5 – 15%, across all samples), presenting the necessity of a more rigorous methodology including further collaborations within the community and multiplicate measurements.</p>

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