Sol-gel-processed amorphous lithium ion electrolyte thin films: Structural evolution, theoretical considerations, and ion transport processes

2016 ◽  
Vol 287 ◽  
pp. 60-70 ◽  
Author(s):  
Zhangfeng Zheng ◽  
Shidong Song ◽  
Yan Wang
Keyword(s):  
Thin Films ◽  
Ion Transport ◽  
Sol Gel ◽  
Structural Evolution ◽  
Lithium Ion ◽  
Transport Processes ◽  
Theoretical Considerations

Sol–gel derived Li–La–Zr–O thin films as solid electrolytes for lithium-ion batteries

2014 ◽  
Vol 2 (33) ◽  
pp. 13277 ◽  
Author(s):  
Ru-Jun Chen ◽  
Mian Huang ◽  
Wen-Ze Huang ◽  
Yang Shen ◽  
Yuan-Hua Lin ◽  
...  
Keyword(s):  
Thin Films ◽  
Lithium Ion Batteries ◽  
Solid Electrolytes ◽  
Sol Gel ◽  
Lithium Ion

Heat-activated structural evolution of sol-gel-derived ZnO thin films

2008 ◽  
Vol 310 (4) ◽  
pp. 816-823 ◽  
Author(s):  
M.W. Zhu ◽  
J.H. Xia ◽  
R.J. Hong ◽  
H. Abu-Samra ◽  
H. Huang ◽  
...  
Keyword(s):  
Thin Films ◽  
Sol Gel ◽  
Structural Evolution ◽  
Zno Thin Films

scholarly journals Structural evolution and hydrogen sulfide sensing properties of NiTiO3–TiO2 sol–gel thin films containing Au nanoparticles

2011 ◽  
Vol 176 (9) ◽  
pp. 716-722 ◽  
Author(s):  
Enrico Della Gaspera ◽  
Mattia Pujatti ◽  
Massimo Guglielmi ◽  
Michael L. Post ◽  
Alessandro Martucci
Keyword(s):  
Thin Films ◽  
Hydrogen Sulfide ◽  
Au Nanoparticles ◽  
Sol Gel ◽  
Structural Evolution ◽  
Sensing Properties ◽  
Tio2 Sol

Chemical and Structural Evolution of Sol-Gel-Derived Hydroxyapatite Thin Films under Rapid Thermal Processing

1996 ◽  
Vol 79 (4) ◽  
pp. 837-842 ◽  
Author(s):  
Stephen W. Russell ◽  
Karen A. Luptak ◽  
Carlos Tres A. Suchicital ◽  
Terry L. Alford ◽  
Vincent B. Pizziconi
Keyword(s):  
Thin Films ◽  
Thermal Processing ◽  
Sol Gel ◽  
Rapid Thermal Processing ◽  
Structural Evolution

Growth of nanotubes in sol-gel-derived V2O5 powders and films prepared under acidic conditions

2009 ◽  
Vol 24 (2) ◽  
pp. 475-481 ◽  
Author(s):  
R. Ceccato ◽  
S. Dirè ◽  
T. Barone ◽  
G. De Santo ◽  
E. Cazzanelli
Keyword(s):  
Thin Films ◽  
Sol Gel ◽  
Structural Evolution ◽  
Nanocrystalline Phase ◽  
X Ray Diffraction ◽  
Α Phase ◽  
Heat Treated ◽  
Acidic Conditions ◽  
Hydrolysis Conditions

The structural evolution with temperature of some V2O5 gels and thin films is presented, and the role of the hydrolysis conditions is investigated. Several techniques, i.e., x-ray diffraction, differential thermal analysis, infrared, and temperature-dependent Raman spectroscopy, have been used to follow the thermal behavior of the samples. When the bulk xerogels begin to change from a nanocrystalline phase to the orthorhombic α-V2O5, in the temperature range 280 to 300 °C, a growth of vanadium oxide nanotubes also occurs, while at higher temperatures the crystallization into the α phase prevails. A slightly different evolution is observed for heat treated thin films, which show a structure containing polyvanadate chains near room temperature. They also present a growth of nanotubes for intermediate temperatures and a complete crystallization into the α phase when the temperature is further increased.

scholarly journals Sol–gel-processed amorphous inorganic lithium ion electrolyte thin films: sol chemistry

RSC Advances ◽  
2017 ◽  
Vol 7 (48) ◽  
pp. 30160-30165 ◽  
Author(s):  
Zhangfeng Zheng ◽  
Yubin Zhang ◽  
Shidong Song ◽  
Yan Wang
Keyword(s):  
Thin Films ◽  
Sol Gel ◽  
Lithium Ion ◽  
Alkoxide Route

The acetate–alkoxide route is not suitable for the preparation of a sol–gel-processed amorphous inorganic lithium ion electrolyte.

scholarly journals Water-Free Titania-Bronze Thin Films with Superfast Lithium-Ion Transport

2014 ◽  
Vol 26 (43) ◽  
pp. 7365-7370 ◽  
Author(s):  
Kui Zhang ◽  
Michael B. Katz ◽  
Baihai Li ◽  
Sung Joo Kim ◽  
Xianfeng Du ◽  
...  
Keyword(s):  
Thin Films ◽  
Ion Transport ◽  
Lithium Ion

Structural influence of porous FeOx@C nanorods on their performance as anodes of lithium-ion batteries

2015 ◽  
Vol 3 (36) ◽  
pp. 18649-18656 ◽  
Author(s):  
Xueying Li ◽  
Zhiyun Zhang ◽  
Jing Li ◽  
Yuanyuan Ma ◽  
Yongquan Qu
Keyword(s):  
Ion Transport ◽  
Charge Transport ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Mechanical Stresses ◽  
Transport Processes ◽  
Carbon Shell ◽  
Thin Shells ◽  
Lithium Diffusion ◽  
Structural Influence

Compared to the mesoporous FeOx-AN@C, FeOx-HY@C with large internal voids, porous thin shells and an elastic carbon shell, as the anode of lithium ion batteries, can effectively buffer volume swing and mechanical stresses, synchronize lithium diffusion and charge transport processes, and facilitate lithium ion transport.

Preparation of High Lithium Ion Conducting LiLnSiO4(Ln = La, Sm) Thin Films by Sol-Gel Method

1997 ◽  
Vol 26 (7) ◽  
pp. 657-658
Author(s):  
Mineo Sato ◽  
Hirokazu Ueda ◽  
Yoichi Ohara ◽  
Kazuyoshi Uematsu ◽  
Kenji Toda
Keyword(s):  
Thin Films ◽  
Sol Gel ◽  
Lithium Ion ◽  
Gel Method ◽  
Sol Gel Method ◽  
Ion Conducting

Preparation of Lithium Ion Conductive Li4.2Al0.2Si0.8O4 Thin Films Using Sol-Gel Process

2006 ◽  
Vol 301 ◽  
pp. 91-94
Author(s):  
Yasuhiro Isshiki ◽  
Kaoru Dokko ◽  
Jun Ichi Hamagami ◽  
Takashi Takei ◽  
Kiyoshi Kanamura
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
High Temperatures ◽  
Room Temperature ◽  
Sol Gel ◽  
Lithium Ion ◽  
Heat Treated ◽  
Sol Gel Process ◽  
Li Ion ◽  
Spin Coater

Thin films of lithium ion conductive ceramic Li4+xAlxSi1-xO4 were fabricated on Au substrate using sol-gel process. The sol of Li-Al-Si-O was spread on Au substrate using a spin coater, and it was gelated at room temperature. The gel was calcinated at 400 °C and heat-treated at high temperatures between 500 °C and 800 °C in air. The addition of poly(vinylpyrrolidone) (PVP) was effective in stabilizing the sol. Furthermore, the morphology of the obtained thin film was changed by the PVP additive. Li4+xAlxSi1-xO4 thin film prepared at 800 °C exhibited a Li+ ion conductivity of 10-8 S cm-1 at room temperature.

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