Recovery of cis,cis-muconic acid from organic phase after reactive extraction

2016 ◽  
Vol 169 ◽  
pp. 1-8 ◽  
Author(s):  
Jannick Gorden ◽  
Tim Zeiner ◽  
Gabriele Sadowski ◽  
Christoph Brandenbusch
Keyword(s):  
Organic Phase ◽  
Reactive Extraction ◽  
Muconic Acid

Reactive extraction of cis,cis-muconic acid

2015 ◽  
Vol 393 ◽  
pp. 78-84 ◽  
Author(s):  
Jannick Gorden ◽  
Tim Zeiner ◽  
Christoph Brandenbusch
Keyword(s):  
Reactive Extraction ◽  
Muconic Acid

scholarly journals THE EFFECT OF CONCENTRATION OF CARRIER, pH AND TIME OF EXTRACTION ON SEPARATION'S FACTOR OF PENICILLIN G - PHENYL ACETATE BY REACTIVE EXTRACTION

2010 ◽  
Vol 7 (2) ◽  
pp. 185-189
Author(s):  
Imam Santoso ◽  
Buchari Buchari ◽  
M. Bachri Amran ◽  
Aminudin Sulaeman
Keyword(s):  
Aqueous Solution ◽  
Optimum Condition ◽  
Organic Phase ◽  
Separation Factor ◽  
Butyl Acetate ◽  
Reactive Extraction ◽  
Penicillin G ◽  
Phenyl Acetate ◽  
Second Phase ◽  
Phase Water

The aim of this research is to study the effect of concentration carrier, pH and time of extraction on separation's factor of penicillin g - phenyl acetate by reactive extraction technique. The 10 mL  aqueous  solution with variation of  pH : 5, 6 contains 0.001 M penicillin G and 0.001 M phenyl acetate has been extracted with 10 mL n-butyl acetate contains dioctylamine as carrier. Variation concentration  of carrier were 0.000; 0.002; 0.004; 0.006 and 0.008 M. Variation time of extraction were 1, 5, 10, 15 and 20 min. The penicillin G and phenyl acetate that dissolved in organic phase ha been  reextracted with 10 mL aqueous with variation of pH : 7, 8. The optimum condition obtained as follow : concentration dioctylamine was 0.002M ; pH the first phase water was 5 and the second phase water was 8 ; and the time of extraction was 10 min.   Keywords: Separation factor, Reactive extraction

Three-Phase Electrochemistry of a Highly Lipophilic Neutral Ru-Complex Having a Tridentate Bis(benzimidazolate)pyridine Ligand

2020 ◽  
Author(s):  
Vishwanath R.S ◽  
Masa-aki Haga ◽  
Takumi Watanabe ◽  
Emilia Witkowska Nery ◽  
Martin Jönsson-Niedziolka
Keyword(s):  
Redox Potential ◽  
Organic Phase ◽  
Electron Donor ◽  
Ion Transfer ◽  
Neutral Complex ◽  
Pyridine Ligand ◽  
Electrochemical Testing ◽  
Ru Complex ◽  
Three Phase ◽  
Exceptional Stability

Here we describe the synthesis and electrochemical testing of a heteroleptic bis(tridentate) ruthenium(II) complex [Ru<sup>II</sup>(LR)(L)]<sup>0</sup> (LR =2,6-bis(1-(2-octyldodecan)benzimidazol-2-yl)pyridine, L = 2,6-bis(benzimidazolate)pyridine). It is a neutral complex which undergoes a quasireversible oxidation and reduction at relatively low potential. The newly synthetized compound was used for studies of ion-transfer at the three-phase junction because of the sensitivity of this method to cation expulsion. The [Ru<sup>II</sup>(LR)(L)]<sup>0</sup> shows exceptional stability during cycling and is sufficiently lipophilic even after oxidation to persist in the organic phase also using very hydrophilic anions such as Cl<sup>−</sup>. Given its low redox potential and strong lipophilicity this compound will be of interest as an electron donor in liquid-liquid electrochemistry.

Three-Phase Electrochemistry of a Highly Lipophilic Neutral Ru-Complex Having a Tridentate Bis(benzimidazolate)pyridine Ligand

2020 ◽  
Author(s):  
Vishwanath R.S ◽  
Masa-aki Haga ◽  
Takumi Watanabe ◽  
Emilia Witkowska Nery ◽  
Martin Jönsson-Niedziolka
Keyword(s):  
Redox Potential ◽  
Organic Phase ◽  
Electron Donor ◽  
Ion Transfer ◽  
Neutral Complex ◽  
Pyridine Ligand ◽  
Electrochemical Testing ◽  
Ru Complex ◽  
Three Phase ◽  
Exceptional Stability

Here we describe the synthesis and electrochemical testing of a heteroleptic bis(tridentate) ruthenium(II) complex [Ru<sup>II</sup>(LR)(L)]<sup>0</sup> (LR =2,6-bis(1-(2-octyldodecan)benzimidazol-2-yl)pyridine, L = 2,6-bis(benzimidazolate)pyridine). It is a neutral complex which undergoes a quasireversible oxidation and reduction at relatively low potential. The newly synthetized compound was used for studies of ion-transfer at the three-phase junction because of the sensitivity of this method to cation expulsion. The [Ru<sup>II</sup>(LR)(L)]<sup>0</sup> shows exceptional stability during cycling and is sufficiently lipophilic even after oxidation to persist in the organic phase also using very hydrophilic anions such as Cl<sup>−</sup>. Given its low redox potential and strong lipophilicity this compound will be of interest as an electron donor in liquid-liquid electrochemistry.

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