Poly(butylene succinate) biocomposite modified by amino functionalized ramie fiber fabric towards exceptional mechanical performance and biodegradability

2020 ◽  
Vol 146 ◽  
pp. 104443 ◽  
Author(s):  
Qianqian Han ◽  
Liang Zhao ◽  
Panlong Lin ◽  
Zongmin Zhu ◽  
Kun Nie ◽  
...  
Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1311 ◽  
Author(s):  
Fabio da Costa Garcia Filho ◽  
Fernanda Santos da Luz ◽  
Lucio Fabio Cassiano Nascimento ◽  
Kestur Gundappa Satyanarayana ◽  
Jaroslaw Wieslaw Drelich ◽  
...  

Natural lignocellulosic fibers and corresponding fabrics have been gaining notoriety in recent decades as reinforcement options for polymer matrices associated with industrially applied composites. These natural fibers and fabrics exhibit competitive properties when compared with some synthetics such as glass fiber. In particular, the use of fabrics made from natural fibers might be considered a more efficient alternative, since they provide multidirectional reinforcement and allow the introduction of a larger volume fraction of fibers in the composite. In this context, it is important to understand the mechanical performance of natural fabric composites as a basic condition to ensure efficient engineering applications. Therefore, it is also important to recognize that ramie fiber exhibiting superior strength can be woven into fabric, but is the least investigated as reinforcement in strong, tough polymers to obtain tougher polymeric composites. Accordingly, this paper presents the preparation of epoxy composite containing 30 vol.% Boehmeria nivea fabric by vacuum-assisted resin infusion molding technique and mechanical behavior characterization of the prepared composite. Obtained results are explained based on the fractography studies of tested samples.


2016 ◽  
Vol 23 (1) ◽  
pp. 45-52 ◽  
Author(s):  
Guijun Xian ◽  
Peng Yin ◽  
Innocent Kafodya ◽  
Hui Li ◽  
Wei-lun Wang

AbstractA durability study of a ramie fiber fabric reinforced phenolic resin (RFRP) plate under 50%, 85%, and 98% relative humidity for 6 months at room temperature was performed. Water absorption and desorption, tensile and short beam shear strengths of the RFRP plates were investigated as a function of exposure time. RFRP samples show strong hydrophilic characteristics and the saturated water content varies from 0.73% to 4.5% with relative humidity ranging from 50% to 98%. After 6 months of exposure to 98% relative humidity, an abnormal extra amount of moisture was absorbed, which may have resulted from cracks in the resin matrix or from debonding between fiber and resin due to swelling of the fibers with high moisture content. It was found that the tensile modulus is more susceptible to moisture uptake, which is ascribed to the degradation of ramie fibers with the water ingress. An approximate linearity between the mechanical properties and the moisture content is observed if the abnormal extra water uptake is neglected. Both tensile and short beam shear strengths of the RFRP samples recovered remarkably when samples were fully dried at 60°C, indicating a low degree of permanent degradation occurred due to the exposure.


2017 ◽  
Vol 26 (5) ◽  
pp. 096369351702600 ◽  
Author(s):  
Wenjing Xia ◽  
Nianqing Zhu ◽  
Zhongbin Ni ◽  
Mingqing Chen

Biodegradable composites from poly (butylene succinate-co-butylene adipate) (PBSA) and Taihu Lake (Wuxi, China) blue algae were prepared by melt blending. The property and structure of biocomposites were investigated. By adding extra amount of water to blue algae, the formulated blue algae acted as a plastic in the composites during blending, and exhibited a reinforcing effect on the PBSA matrix. With increasing blue algae content, the thermal stability of the composites decreased; the tensile strength at break and elongation at break of the composites reduced, but the Young's modulus of the composites increased. However, the composite with 30% blue algae loading still exhibited good mechanical performance (tensile strength at break of 21.3 MPa, elongation at break of 180%). The fabrication of value-added PBSA/algae composites appeared as an effective approach to reduce the secondary environmental pollution of Taihu blue algae.


2018 ◽  
Vol 6 (27) ◽  
pp. 13373-13385 ◽  
Author(s):  
Xu-Long Xie ◽  
Yue Li ◽  
Jia-Zhuang Xu ◽  
Zheng Yan ◽  
Gan-Ji Zhong ◽  
...  

The simultaneous reinforcement and toughening of poly(butylene succinate) was achieved via an oriented hierarchical structure induced by oscillation shear stress and promoted by poly(l-lactide).


2018 ◽  
Vol 89 (16) ◽  
pp. 3260-3268 ◽  
Author(s):  
Yuanming Zhang ◽  
Conger Wang ◽  
Yanhui Liu ◽  
Wei Jiang ◽  
Guangting Han

Alginate scaffold with high porosity has great potential in the field of tissue engineering due to its biocompatibility and degradability. However, the poor mechanical performance of pure alginate scaffold has limited its use in many applications. Cellulose nanofibers (CNFs) have attracted attention as reinforcing agents to fabricate composite scaffolds with alginate. In this paper, CNF obtained from raw ramie fibers was incorporated with sodium alginate to make a composite scaffold by the freeze-drying method. CNF contents of 0.025, 0.05, 0.1, 0.2, 0.4, 0.8, and 1.6% were selected to study the effect of CNF on scaffold characterization. The composite scaffold exhibited fewer pores but more compact structure than the pure alginate scaffold. Fourier transform infrared spectroscopy was used to study the changes in the functional groups between the ramie fiber and its CNF, pure alginate scaffold, and the composite scaffold. X-ray diffraction indicated that the crystallinity of scaffold increased with addition of CNF. The mechanical performance of scaffold was successfully improved by adding CNF, but the porosity and swelling ratio were decreased. Hence, by combining CNF with alginate, the porous structure, mechanical properties, and swelling behaviors could be tailored, which could expand its use in the field of tissue engineering.


Polymers ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1571 ◽  
Author(s):  
Rafiqah S. Ayu ◽  
Abdan Khalina ◽  
Ahmad Saffian Harmaen ◽  
Khairul Zaman ◽  
Tawakkal Isma ◽  
...  

In this study, a mixture of thermoplastic polybutylene succinate (PBS), tapioca starch, glycerol and empty fruit bunch fiber was prepared by a melt compounding method using an industrial extruder. Generally, insertion of starch/glycerol has provided better strength performance, but worse thermal and water uptake to all specimens. The effect of fiber loading on mechanical, morphological, thermal and physical properties was studied in focus. Low interfacial bonding between fiber and matrix revealed a poor mechanical performance. However, higher fiber loadings have improved the strength values. This is because fibers regulate good load transfer mechanisms, as confirmed from SEM micrographs. Tensile and flexural strengths have increased 6.0% and 12.2%, respectively, for 20 wt% empty fruit bunch (EFB) fiber reinforcements. There was a slightly higher mass loss for early stage thermal decomposition, whereas regardless of EFB contents, insignificant changes on decomposition temperature were recorded. A higher lignin constituent in the composite (for high natural fiber volume) resulted in a higher mass residue, which would turn into char at high temperature. This observation indirectly proves the dimensional integrity of the composite. However, as expected, with higher EFB fiber contents in the composite, higher values in both the moisture uptake and moisture loss analyses were found. The hydroxyl groups in the EFB absorbed water moisture through formation of hydrogen bonding.


ACS Omega ◽  
2018 ◽  
Vol 3 (11) ◽  
pp. 15205-15216 ◽  
Author(s):  
Alison Gowman ◽  
Tao Wang ◽  
Arturo Rodriguez-Uribe ◽  
Amar K. Mohanty ◽  
Manjusri Misra

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