Chain extension of virgin and recycled polyethylene terephthalate

2016 ◽  
Vol 50 ◽  
pp. 26-32 ◽  
Author(s):  
Albaniza A. Tavares ◽  
Diêgo F.A. Silva ◽  
Poliana S. Lima ◽  
Daniela L.A.C.S. Andrade ◽  
Suédina M.L. Silva ◽  
...  
Keyword(s):  
Polyethylene Terephthalate ◽  
Chain Extension ◽  
Recycled Polyethylene

scholarly journals Mechanical Recycling of Partially Bio-Based and Recycled Polyethylene Terephthalate Blends by Reactive Extrusion with Poly(styrene-co-glycidyl methacrylate)

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 174 ◽  
Author(s):  
Sergi Montava-Jorda ◽  
Diego Lascano ◽  
Luis Quiles-Carrillo ◽  
Nestor Montanes ◽  
Teodomiro Boronat ◽  
...  
Keyword(s):  
Polyethylene Terephthalate ◽  
Glycidyl Methacrylate ◽  
Random Copolymer ◽  
Reactive Extrusion ◽  
Free Food ◽  
Extrusion Process ◽  
Chain Extension ◽  
Mechanical Resistance ◽  
Mechanical Recycling ◽  
Recycled Polyethylene

In the present study, partially bio-based polyethylene terephthalate (bio-PET) was melt-mixed at 15–45 wt% with recycled polyethylene terephthalate (r-PET) obtained from remnants of the injection blowing process of contaminant-free food-use bottles. The resultant compounded materials were thereafter shaped into pieces by injection molding for characterization. Poly(styrene-co-glycidyl methacrylate) (PS-co-GMA) was added at 1–5 parts per hundred resin (phr) of polyester blend during the extrusion process to counteract the ductility and toughness reduction that occurred in the bio-PET pieces after the incorporation of r-PET. This random copolymer effectively acted as a chain extender in the polyester blend, resulting in injection-molded pieces with slightly higher mechanical resistance properties and nearly the same ductility and toughness than those of neat bio-PET. In particular, for the polyester blend containing 45 wt% of r-PET, elongation at break (εb) increased from 10.8% to 378.8% after the addition of 5 phr of PS-co-GMA, while impact strength also improved from 1.84 kJ·m−2 to 2.52 kJ·m−2. The mechanical enhancement attained was related to the formation of branched and larger macromolecules by a mechanism of chain extension based on the reaction of the multiple glycidyl methacrylate (GMA) groups present in PS-co-GMA with the hydroxyl (–OH) and carboxyl (–COOH) terminal groups of both bio-PET and r-PET. Furthermore, all the polyester blend pieces showed thermal and dimensional stabilities similar to those of neat bio-PET, remaining stable up to more than 400 °C. Therefore, the use low contents of the tested multi-functional copolymer can successfully restore the properties of bio-based but non-biodegradable polyesters during melt reprocessing with their recycled petrochemical counterparts and an effective mechanical recycling is achieved.

A novel recycled polyethylene terephthalate/polyamide 11 (rPET/PA11) thermoplastic blend

2021 ◽  
pp. 147776062110010
Author(s):  
Zahid Iqbal Khan ◽  
Zurina Binti Mohamad ◽  
Abdul Razak Bin Rahmat ◽  
Unsia Habib ◽  
Nur Amira Sahirah Binti Abdullah
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Flexural Strength ◽  
Polyethylene Terephthalate ◽  
Practical Implication ◽  
Polyamide 11 ◽  
Recycled Polyethylene ◽  
Twin Screw ◽  
Electron Microscopy Analysis ◽  
The Impact

This work explores a novel blend of recycled polyethylene terephthalate/polyamide 11 (rPET/PA11). The blend of rPET/PA11 was introduced to enhance the mechanical properties of rPET at various ratios. The work’s main advantage was to utilize rPET in thermoplastic form for various applications. Three different ratios, i.e. 10, 20 and 30 wt.% of PA11 blend samples, were prepared using a twin-screw extruder and injection moulding machine. The mechanical properties were examined in terms of tensile, flexural and impact strength. The tensile strength of rPET was improved more than 50%, while the increase in tensile strain was observed 42.5% with the addition of 20 wt.% of PA11. The improved properties of the blend were also confirmed by the flexural strength of the blends. The flexural strength was increased from 27.9 MPa to 48 MPa with the addition of 30 wt.% PA11. The flexural strain of rPET was found to be 1.1%. However, with the addition of 10, 20 and 30 wt.% of PA11, the flexural strain was noticed as 1.7, 2.1, and 3.9% respectively. The impact strength of rPET/PA11 at 20 wt.% PA11 was upsurged from 110.53 to 147.12 J/m. Scanning electron microscopy analysis revealed a dispersed PA11 domain in a continuous rPET matrix morphology of the blends. This work practical implication would lead to utilization of rPET in automobile, packaging, and various industries.

scholarly journals Examining Polyethylene Terephthalate (PET) as Artificial Coarse Aggregates in Concrete

2020 ◽  
Vol 6 (12) ◽  
pp. 2416-2424
Author(s):  
Erniati Bachtiar ◽  
Mustaan Mustaan ◽  
Faris Jumawan ◽  
Meldawati Artayani ◽  
Tahang Tahang ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Flexural Strength ◽  
Polyethylene Terephthalate ◽  
Coarse Aggregate ◽  
Fresh Concrete ◽  
Coarse Aggregates ◽  
Volume Weight ◽  
Concrete Mixtures ◽  
Strength Tests ◽  
Recycled Polyethylene

This study aims to examine the effect of recycled Polyethylene Terephthalate (PET) artificial aggregate as a substitute for coarse aggregate on the compressive strength and flexural strength, and the volume weight of the concrete. PET plastic waste is recycled by heating to a boiling point of approximately 300°C. There are five variations of concrete mixtures, defined the percentage of PET artificial aggregate to the total coarse aggregate, by 0, 25, 50, 75 and 100%. Tests carried out on fresh concrete mixtures are slump, bleeding, and segregation tests. Compressive and flexural strength tests proceeded based on ASTM 39/C39M-99 and ASTM C293-79 standards at the age of 28 days. The results showed that the use of PET artificial aggregate could improve the workability of the concrete mixture. The effect of PET artificial aggregate as a substitute for coarse aggregate on the compressive and flexural strength of concrete is considered very significant. The higher the percentage of PET plastic artificial aggregate, the lower the compressive and flexural strength, and the volume weight, of the concrete. Substitution of 25, 50, 75 and 100% of PET artificial aggregate gave decreases in compressive strength of 30.06, 32.39, 41.73 and 44.06% of the compressive strength of the standard concrete (18.20 MPa), respectively. The reductions in flexural strength were by respectively 19.03, 54.50, 53.95 and 61.00% of the standard concrete's flexural strength (3.59 MPa). The reductions in volume weight of concrete were by respectively 8.45, 17.71, 25.07 and 34.60% of the weight of the standard concrete volume of 2335.4 kg/m3 Doi: 10.28991/cej-2020-03091626 Full Text: PDF

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