Catalytically active hybrid polyurethane with tetraaniline pendant groups: Synthesis, properties and self assembly

Polymer ◽  
2015 ◽  
Vol 77 ◽  
pp. 334-344 ◽  
Author(s):  
Ravi Arukula ◽  
Chepuri R.K. Rao ◽  
Ramanuj Narayan ◽  
B. Sreedhar
2016 ◽  
Vol 52 (10) ◽  
pp. 2133-2136 ◽  
Author(s):  
Krunoslav Užarević ◽  
Timothy C. Wang ◽  
Su-Young Moon ◽  
Athena M. Fidelli ◽  
Joseph T. Hupp ◽  
...  

Mechanochemistry and accelerated aging are new routes to zirconium metal–organic frameworks, yielding UiO-66 and catalytically active UiO-66-NH2 accessible on the gram scale through mild solid-state self-assembly, without strong acids, high temperatures or excess reactants.


2019 ◽  
Vol 141 (26) ◽  
pp. 10350-10360 ◽  
Author(s):  
Rosa Adam ◽  
Marta Mon ◽  
Rossella Greco ◽  
Lucas H. G. Kalinke ◽  
Alejandro Vidal-Moya ◽  
...  

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Long Cui ◽  
Yan-Fang Geng ◽  
Chanel F. Leong ◽  
Qian Ma ◽  
Deanna M. D’Alessandro ◽  
...  

2015 ◽  
Vol 17 (24) ◽  
pp. 15579-15588 ◽  
Author(s):  
Andrew Booth ◽  
Inmaculada C. Pintre ◽  
Yue Lin ◽  
Julie E. Gough ◽  
Simon J. Webb

The self-assembly of avidin, biotinylated vesicles and biotinylated (3-aminopropyl)triethoxysilane-coated magnetite nanoparticles gave a nanomaterial able to magnetically release catalytically active enzymes from vesicular compartments.


Langmuir ◽  
2009 ◽  
Vol 25 (19) ◽  
pp. 11857-11861 ◽  
Author(s):  
Christophe Danumah ◽  
Rachel L. Beingessner ◽  
Azizul Haque ◽  
Fuqiang Ban ◽  
Jeremy P. Richards ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (105) ◽  
pp. 86564-86571 ◽  
Author(s):  
Qian Wang ◽  
Xingjuan Zhao ◽  
Yong-Ill Lee ◽  
Hong-Guo Liu

A catalytically active multilayer film of PB-b-P2VP doped with Au nanoparticles was fabricated through liquid/liquid interfacial mass transfer, self-assembly in an aqueous phase and adsorption at the air/liquid interface.


2019 ◽  
Vol 2 (8) ◽  
pp. 3639-3647 ◽  
Author(s):  
Valeria Castelletto ◽  
Charlotte J. C. Edwards-Gayle ◽  
Ian W. Hamley ◽  
Juliane N. B. D. Pelin ◽  
Wendel A. Alves ◽  
...  

Synlett ◽  
2021 ◽  
Author(s):  
Joaquim Crusats ◽  
Albert Moyano

In order to explain the origin of the single-handedness of the molecules of life (biological homochirality), the appearence of an initial enantiomeric imbalance by spontaneous mirror-symmetry breaking (SMSB) in prebiotic reactions is usually assumed, but examples of its experimental realization are very scarce. SMSB in the self-assembly of achiral molecules is much more common, and the chirality sign of the resulting supramolecular system can be controlled by the action of macroscopic chiral forces. We have proposed a new mechanism for the generation of net chirality in molecular systems, in which the SMSB takes place in the formation of chiral supramolecular dissipative structures from achiral monomers, leading to asymmetric imbalances in their composition that are subsequently transferred to a standard enantioselective catalytic reaction, dodging in this way the highly limiting requirement of finding suitable reactions in solution that show enantioselective autocatalysis. We propose the name “absolute asymmetric catalysis” for this approach, in which an achiral monomer is converted to a nonracemic chiral aggregate that is generated with SMSB and that is catalytically active. We present in this Account a step-by-step narrative of the development of this prebiotically plausible, alternative mechanism for the emergence of net chirality in molecular reactions.


2015 ◽  
Vol 290 (44) ◽  
pp. 26801-26810 ◽  
Author(s):  
Kourosh Honarmand Ebrahimi ◽  
Peter-Leon Hagedoorn ◽  
Wilfred R. Hagen

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