Influence of gradient strength and composition profile on the onset of the cloud point transition in hydroxyethyl methacrylate/dimethylaminoethyl methacrylate gradient copolymers

Polymer ◽  
2012 ◽  
Vol 53 (5) ◽  
pp. 1131-1137 ◽  
Author(s):  
Keith C. Gallow ◽  
Young K. Jhon ◽  
Jan Genzer ◽  
Yueh-Lin Loo
Keyword(s):  
Cloud Point ◽  
Composition Profile ◽  
Hydroxyethyl Methacrylate ◽  
Gradient Copolymers ◽  
Dimethylaminoethyl Methacrylate ◽  
Gradient Strength

scholarly journals Phase Behavior of Gradient Copolymer Melts with Different Gradient Strengths Revealed by Mesoscale Simulations

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2462
Author(s):  
Pavel Beránek ◽  
Paola Posocco ◽  
Zbyšek Posel
Keyword(s):  
Self Assembly ◽  
Diblock Copolymers ◽  
Block Size ◽  
The Self ◽  
Gradient Copolymers ◽  
Gradient Copolymer ◽  
Gradient Strength ◽  
Monomer Sequence ◽  
Copolymer Melts ◽  
Weak Gradient

Design and preparation of functional nanomaterials with specific properties requires precise control over their microscopic structure. A prototypical example is the self-assembly of diblock copolymers, which generate highly ordered structures controlled by three parameters: the chemical incompatibility between blocks, block size ratio and chain length. Recent advances in polymer synthesis have allowed for the preparation of gradient copolymers with controlled sequence chemistry, thus providing additional parameters to tailor their assembly. These are polydisperse monomer sequence, block size distribution and gradient strength. Here, we employ dissipative particle dynamics to describe the self-assembly of gradient copolymer melts with strong, intermediate, and weak gradient strength and compare their phase behavior to that of corresponding diblock copolymers. Gradient melts behave similarly when copolymers with a strong gradient are considered. Decreasing the gradient strength leads to the widening of the gyroid phase window, at the expense of cylindrical domains, and a remarkable extension of the lamellar phase. Finally, we show that weak gradient strength enhances chain packing in gyroid structures much more than in lamellar and cylindrical morphologies. Importantly, this work also provides a link between gradient copolymers morphology and parameters such as chemical incompatibility, chain length and monomer sequence as support for the rational design of these nanomaterials.

Cloud point suppression in dilute solutions of model gradient copolymers with prespecified composition profiles

2011 ◽  
Vol 49 (9) ◽  
pp. 629-637 ◽  
Author(s):  
Keith C. Gallow ◽  
Young K. Jhon ◽  
Wei Tang ◽  
Jan Genzer ◽  
Yueh-Lin Loo
Keyword(s):  
Cloud Point ◽  
Dilute Solutions ◽  
Gradient Copolymers ◽  
Composition Profiles
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