The flame-retardant material – 1. Studies on thermal characteristics and flame retardance behavior of phosphorus-containing copolymer of methyl methacrylate with 2-methacryloxyethyl phenyl phosphate

2006 ◽  
Vol 91 (11) ◽  
pp. 2683-2690 ◽  
Author(s):  
Guo-An Wang ◽  
Cheng-Chien Wang ◽  
Chuh-Yung Chen
Keyword(s):  
Methyl Methacrylate ◽  
Flame Retardant ◽  
Thermal Characteristics ◽  
Flame Retardance ◽  
Phenyl Phosphate ◽  
Phosphorus Containing

Flame retardance of poly(methyl methacrylate) modified with phosphorus-containing compounds

2002 ◽  
Vol 77 (2) ◽  
pp. 227-233 ◽  
Author(s):  
Dennis Price ◽  
Kelly Pyrah ◽  
T.Richard Hull ◽  
G.John Milnes ◽  
John R Ebdon ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Flame Retardance ◽  
Poly Methyl Methacrylate ◽  
Phosphorus Containing

Enhanced Thermal Stability and Flame Retardancy of a Novel Transparent Poly(Methyl Methacrylate)-Based Copolymer

2014 ◽  
Vol 911 ◽  
pp. 423-427
Author(s):  
Sai Hua Jiang ◽  
Siu Ming Lo ◽  
Yuan Hu
Keyword(s):  
Thermal Stability ◽  
Methyl Methacrylate ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Chemical Structure ◽  
Poly Methyl Methacrylate ◽  
H Nmr ◽  
Char Formation ◽  
Phosphorus Containing ◽  
Thermal Stability Of

A novel poly (methyl methacrylate) (PMMA) based copolymer was synthesized by bulk copolymerization of methyl methacrylate (MMA) and a phosphorus-containing monomer, acryloxyethyl phenoxy phosphorodiethyl amidate (AEPPA). The chemical structure of AEPPA was confirmed by FTIR,1H NMR and31P NMR. The structure of copolymers was characterized using FTIR. TGA results indicate that the thermal stability of copolymers was remarkably enhanced with the addition of APEEA. LOI and MCC results suggest that the flame retardancy of copolymers was also improved. Detailed flame-retardant mechanism is proposed. The char formation during degradation caused by APEEA plays a key role in the property improvements.

RAFT copolymerization of a phosphorus-containing monomer with α-hydroxy phosphonate and methyl methacrylate

RSC Advances ◽  
2016 ◽  
Vol 6 (41) ◽  
pp. 34659-34665 ◽  
Author(s):  
Chun Tian ◽  
Tianchi Xu ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
Xiulin Zhu
Keyword(s):  
Methyl Methacrylate ◽  
Flame Retardant ◽  
Phosphorus Containing ◽  
Flame Retardant Properties

RAFT copolymerization of a phosphorus-containing monomer with α-hydroxy phosphonate PHMA and MMA was successfully conducted and the resultant well-defined copolymer material shows good superior flame-retardant properties and hydrophilicity.

scholarly journals The Preparation, Thermal Properties, and Fire Property of a Phosphorus-Containing Flame-Retardant Styrene Copolymer

Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 127 ◽  
Author(s):  
Yu Sun ◽  
Yazhen Wang ◽  
Li Liu ◽  
Tianyuan Xiao
Keyword(s):  
Thermal Properties ◽  
Thermogravimetric Analysis ◽  
Flame Retardant ◽  
Oxygen Index ◽  
Limiting Oxygen Index ◽  
Chemical Structures ◽  
1H Nuclear Magnetic Resonance ◽  
Phosphorus Containing ◽  
Ft Ir ◽  
Ft Ir Spectroscopy

A 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) acrylate, (6-oxidodibenzo [c,e][1,2] oxaphosphinin-6-yl) methyl acrylate (DOPOAA), has been prepared. Copolymers of styrene (St) and DOPOAA were prepared by emulsion polymerization. The chemical structures of copolymers containing levels of DOPOAA were verified using Fourier transform infrared (FT-IR) spectroscopy and 1H nuclear magnetic resonance (1H-NMR) spectroscopy. The thermal properties and flame-retardant behaviors of DOPO-containing monomers and copolymers were observed using thermogravimetric analysis and micro calorimetry tests. From thermogravimetric analysis (TGA), it was found out that the T5% for decomposition of the copolymer was lower than that of polystyrene (PS), but the residue at 700 °C was higher than that of PS. The results from micro calorimetry (MCC) tests indicated that the rate for the heat release of the copolymer combustion was lower than that for PS. The limiting oxygen index (LOI) for combustion of the copolymer rose with increasing levels of DOPOAA. These data indicate that copolymerization of the phosphorus-containing flame-retardant monomer, DOPOAA, into a PS segment can effectively improve the thermal stability and flame retardancy of the copolymer.

scholarly journals Preparation and characterization of polydopamine/melamine microencapsulated red phosphorus and its flame retardance in epoxy resin

RSC Advances ◽  
2021 ◽  
Vol 11 (33) ◽  
pp. 20391-20402
Author(s):  
Chen Cheng ◽  
Yanling Lu ◽  
Weining Ma ◽  
Shaojie Li ◽  
Jun Yan ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Epoxy Resin ◽  
Shell Structure ◽  
Composite Shell ◽  
Intumescent Flame Retardant ◽  
Smoke Suppression ◽  
Flame Retardance ◽  
Red Phosphorus ◽  
Composite Shell Structure

Red phosphorus was coated by a polydopamine/melamine composite shell structure, which constituted an intumescent flame retardant with superior flame retardance and smoke suppression performance for epoxy resin.

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