Mixed ligand metal-complexes of tridentate N, N, S pyrazole containing Schiff base and 2-amino-1-ethylbenzimidazole: Synthesis, structure, spectroscopic studies and quantum-chemical calculations

Polyhedron ◽  
2017 ◽  
Vol 133 ◽  
pp. 245-256 ◽  
Author(s):  
V.G. Vlasenko ◽  
D.A. Garnovskii ◽  
G.G. Aleksandrov ◽  
N.I. Makarova ◽  
S.I. Levchenkov ◽  
...  
Keyword(s):  
Schiff Base ◽  
Metal Complexes ◽  
Quantum Chemical Calculations ◽  
Quantum Chemical ◽  
Spectroscopic Studies ◽  
Mixed Ligand

scholarly journals Synthesis, Characterization and Antimicrobial Activities of Sulfadiazine Schiff Base and Phenyl Dithiocarbamate Mixed Ligand Metal Complexes

2018 ◽  
Vol 08 (08) ◽  
pp. 346-354
Author(s):  
Benjamin Chibuzo Ejelonu ◽  
Sulaiman Adeoye Olagboye ◽  
Oluwatoba Emmanuel Oyeneyin ◽  
Oladipo Adebayo Ebiesuwa ◽  
Oluwatomisin Emmanuel Bada
Keyword(s):  
Schiff Base ◽  
Metal Complexes ◽  
Antimicrobial Activities ◽  
Mixed Ligand

scholarly journals Troilite (FeS) Oxidation in the Presence of a Newly Synthesized TRIS-based Base

2019 ◽  
Vol 70 (7) ◽  
pp. 2639-2642
Author(s):  
Madalina Ionela Duinea ◽  
Geta Carac ◽  
Irina Daniela Dabuleanu ◽  
Mihaela Alexandra Petcu ◽  
Laura Gabriela Sarbu ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Schiff Base ◽  
Optical Microscopy ◽  
Quantum Chemical Calculations ◽  
Potentiodynamic Polarization ◽  
Quantum Chemical ◽  
Corrosion Current ◽  
Inhibitory Effect ◽  
Oxidative Dissolution ◽  
Current Densities

The effect of a newly synthesized TRIS-based Schiff base (XC) on the oxidative dissolution of FeS in air-equilibrated solutions with pH 2.26 and temperature of 27�C was investigated by Potentiodynamic polarization, Cyclic Voltammetry, Optical Microscopy and quantum chemical calculations. The XC concentration varied between 0 and 0.52 mM. It was observed that XC decreases the corrosion current densities of the oxidative dissolution of FeS. Our results indicate that the inhibitory effect of XC is due to its adsorption on the FeS surface.

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