Zirconium(IV) and hafnium(IV) coordination polymers with a tetra-acetyl-ethane (Bisacac) ligand: Synthesis, structure elucidation and gas sorption behavior

Polyhedron ◽  
2015 ◽  
Vol 89 ◽  
pp. 297-303 ◽  
Author(s):  
Felix Hentschel ◽  
Vladimir V. Vinogradov ◽  
Alexandr V. Vinogradov ◽  
Alexander V. Agafonov ◽  
Vadim V. Guliants ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structure Elucidation ◽  
Sorption Behavior ◽  
Gas Sorption ◽  
Ligand Synthesis

Ionic π-Conjugated Polymer Networks by Catalyst-Free Polymerization, Photoluminescence and Gas Sorption Behavior

2016 ◽  
Vol 217 (17) ◽  
pp. 1886-1898 ◽  
Author(s):  
Tomáš Faukner ◽  
Arnošt Zukal ◽  
Jiří Brus ◽  
Jiří Zedník ◽  
Jan Sedláček
Keyword(s):  
Conjugated Polymer ◽  
Polymer Networks ◽  
Sorption Behavior ◽  
Gas Sorption ◽  
Catalyst Free

Syntheses, structures and gas sorption properties of two coordination polymers with a unique type of supramolecular isomerism

2015 ◽  
Vol 2 (2) ◽  
pp. 136-140 ◽  
Author(s):  
Xiao-Lin Qi ◽  
Jia-Wen Ye ◽  
Rui-Biao Lin ◽  
Pei-Qin Liao ◽  
Si-Yang Liu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Difference ◽  
Sorption Properties ◽  
Gas Sorption ◽  
Unique Type ◽  
Supramolecular Isomerism ◽  
Porous Properties

Two genuine supramolecular isomers with a unique type of structural difference and completely different porous properties have been synthesized and characterized.

Halogen···Halogen Interactions in the Supramolecular Assembly of 2D Coordination Polymers and the CO2 Sorption Behavior

2016 ◽  
Vol 16 (9) ◽  
pp. 5514-5519 ◽  
Author(s):  
Faruk Ahmed ◽  
Syamantak Roy ◽  
Kaushik Naskar ◽  
Chittaranjan Sinha ◽  
Seikh Mafiz Alam ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Supramolecular Assembly ◽  
Sorption Behavior ◽  
Co2 Sorption

Two Coordination Polymers Created via In Situ Ligand Synthesis Involving C−N and C−C Bond Formation

2007 ◽  
Vol 46 (21) ◽  
pp. 8717-8721 ◽  
Author(s):  
Russell K. Feller ◽  
Paul M. Forster ◽  
Fred Wudl ◽  
Anthony K. Cheetham
Keyword(s):  
Coordination Polymers ◽  
Bond Formation ◽  
Ligand Synthesis

Anion-controlled Zn(II) Coordination Polymers with 1-(tetrazo-5-yl)-3-(triazo-1-yl) benzene as an Assembling Ligand: Synthesis, Characterization, and Efficient Detection of Tryptophan in Water

2021 ◽  
Author(s):  
Hanxu Sun ◽  
Jie Zhou ◽  
Zhen Zhang ◽  
Mei He ◽  
Liancheng He ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Human Body ◽  
Efficient Detection ◽  
Excessive Intake ◽  
Ligand Synthesis ◽  
Harmful Effects ◽  
Physiological Systems

Tryptophan regulates and participates in various physiological systems in the human body, and its excessive intake has harmful effects. Therefore, detecting and monitor tryptophan in water and distinguish it from...

scholarly journals Different Benzendicarboxylate-Directed Structural Variations and Properties of Four New Porous Cd(II)-Pyridyl-Triazole Coordination Polymers

2020 ◽  
Vol 8 ◽  
Author(s):  
Ying Zhao ◽  
Jin Jing ◽  
Ning Yan ◽  
Min-Le Han ◽  
Guo-Ping Yang ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Gas Sorption ◽  
Structural Variations ◽  
Benzenedicarboxylic Acid ◽  
Topological Framework ◽  
The Stability

Four new different porous crystalline Cd(II)-based coordination polymers (CPs), i. e., [Cd(mdpt)2]·2H2O (1), [Cd2(mdpt)2(m-bdc)(H2O)2] (2), [Cd(Hmdpt)(p-bdc)]·2H2O (3), and [Cd3(mdpt)2(bpdc)2]·2.5NMP (4), were obtained successfully by the assembly of Cd(II) ions and bitopic 3-(3-methyl-2-pyridyl)-5-(4-pyridyl)-1,2,4-triazole (Hmdpt) in the presence of various benzendicarboxylate ligands, i.e., 1,3/1,4-benzenedicarboxylic acid (m-H2bdc, p-H2bdc) and biphenyl-4,4′-bicarboxylate (H2bpdc). Herein, complex 1 is a porous 2-fold interpenetrated four-connected 3D NbO topological framework based on the mdpt− ligand; 2 reveals a two-dimensional (2D) hcb network. Interestingly, 3 presents a three-dimensional (3D) rare interpenetrated double-insertion supramolecular net via 2D ···ABAB··· layers and can be viewed as an fsh topological net, while complex 4 displays a 3D sqc117 framework. Then, the different gas sorption performances were carried out carefully for complexes 1 and 4, the results of which showed 4 has preferable sorption than that of 1 and can be the potential CO2 storage and separation material. Furthermore, the stability and luminescence of four complexes were performed carefully in the solid state.

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