Discrete systems and two-dimensional coordination polymers containing potentially multidentate and bridging inorganic anions: Observation of a new type of two-dimensional topology

Polyhedron ◽  
2014 ◽  
Vol 74 ◽  
pp. 57-66 ◽  
Author(s):  
Arpita Biswas ◽  
Arpita Jana ◽  
Sohini Sarkar ◽  
Hazel A. Sparkes ◽  
Judith A.K. Howard ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Discrete Systems ◽  
Inorganic Anions ◽  
Two Dimensional ◽  
New Type

scholarly journals Proton dynamics of two-dimensional oxalate-bridged coordination polymers

2014 ◽  
Vol 16 (32) ◽  
pp. 17295-17304 ◽  
Author(s):  
Satoshi Miyatsu ◽  
Maiko Kofu ◽  
Atsushi Nagoe ◽  
Takeshi Yamada ◽  
Masaaki Sadakiyo ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Coordination Polymers ◽  
Conduction Mechanism ◽  
Proton Conductor ◽  
Proton Conduction ◽  
Two Dimensional ◽  
Quasielastic Neutron ◽  
New Type ◽  
Proton Dynamics ◽  
Quasielastic Neutron Scattering

The dynamics of H2O molecules and NH4+ ions in a new type of crystalline proton conductor (NH4)2(adp)[Zn2(ox)3]·3H2O has been investigated by quasielastic neutron scattering techniques to elucidate the proton conduction mechanism.

scholarly journals From helices to superhelices: hierarchical assembly of homochiral van der Waals 1D coordination polymers

2021 ◽  
Vol 12 (38) ◽  
pp. 12619-12630
Author(s):  
Guo-Guo Weng ◽  
Ben-Kun Hong ◽  
Song-Song Bao ◽  
Yujie Wen ◽  
Lan-Qing Wu ◽  
...  
Keyword(s):  
Growth Mechanism ◽  
Coordination Polymers ◽  
Van Der Waals ◽  
Hierarchical Assembly ◽  
New Type

Superhelices of terbium phosphonates formed following a new type of “chain-twist-growth” mechanism involving flexible cyclohexyl groups.

Stability and Stabilization for Discrete System With Probabilistic Nonlinearities

2013 ◽  
Vol 135 (5) ◽  
Author(s):  
Xia Zhao ◽  
Engang Tian
Keyword(s):  
Sufficient Conditions ◽  
Discrete Systems ◽  
System Model ◽  
Linear Matrix ◽  
Time Varying Delay ◽  
Mean Square Stability ◽  
New Type ◽  
Stability And Stabilization ◽  
The Mean ◽  
Varying Delay

This paper investigates stability and stabilization of discrete systems with probabilistic nonlinearities and time-varying delay. New characters of the nonlinearities, the probability of the nonlinearities happening between different bounds, are used to build new type of system model, which can help us make a full use of the inner variation information of the nonlinearities. With the help of the new characters, new system model is proposed. Then, sufficient conditions for the mean square stability of the system can be obtained by using the Lyapunov functional approach and linear matrix inequalities technique. An example is proposed to illustrate the efficiency of the proposed method.

Two-dimensional lanthanide(III) coordination polymers: solvothermal synthesis, crystal structure, and stability

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Runmei Ding ◽  
Zixin He ◽  
Meilin Wang ◽  
Danian Tian ◽  
Peipei Cen
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Analysis Data ◽  
Water Stability ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
X Ray ◽  
Solvothermal Conditions

AbstractBased on 2-(4-pyridyl)-terephthalate (H2pta) and oxalate ligands, two new lanthanide-containing coordination polymers (CPs), [Tb(pta)(C2O4)0.5(H2O)2)]·2H2O (1) and [Sm(pta)(C2O4)0.5(H2O)2)]·2H2O (2), have been synthesized under solvothermal conditions. The structures of both 1 and 2 have been determined by single-crystal X-ray diffraction. Infrared, elemental analysis, powder X-ray diffraction and thermogravimetric analysis data are also presented. The crystals of 1 and 2 exhibit isostructural layer-like networks, crystallizing in the triclinic space group P$‾{1}$. The layers are further stabilized and associated into 3D architectures through hydrogen bonding. Remarkably, the CPs 1 and 2 exhibit excellent water stability and remarkable thermostability with thermal decomposition temperatures of more than 420 °C.

scholarly journals Crystal structures of {[Cu(Lpn)2][Fe(CN)5(NO)]·H2O}nand {[Cu(Lpn)2]3[Cr(CN)6]2·5H2O}n[where Lpn = (R)-propane-1,2-diamine]: two heterometallic chiral cyanide-bridged coordination polymers

2015 ◽  
Vol 71 (4) ◽  
pp. 392-397
Author(s):  
Olha Sereda ◽  
Helen Stoeckli-Evans
Keyword(s):  
Hydrogen Bonds ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Water Molecules ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Compound I ◽  
Distorted Octahedral ◽  
Coordination Spheres ◽  
Compound Ii

The title compounds,catena-poly[[[bis[(R)-propane-1,2-diamine-κ2N,N′]copper(II)]-μ-cyanido-κ2N:C-[tris(cyanido-κC)(nitroso-κN)iron(III)]-μ-cyanido-κ2C:N] monohydrate], {[Cu(Lpn)2][Fe(CN)5(NO)]·H2O}n, (I), and poly[[hexa-μ-cyanido-κ12C:N-hexacyanido-κ6C-hexakis[(R)-propane-1,2-diamine-κ2N,N′]dichromium(III)tricopper(II)] pentahydrate], {[Cu(Lpn)2]3[Cr(CN)6]2·5H2O}n, (II) [where Lpn = (R)-propane-1,2-diamine, C3H10N2], are new chiral cyanide-bridged bimetallic coordination polymers. The asymmetric unit of compound (I) is composed of two independent cation–anion units of {[Cu(Lpn)2][Fe(CN)5)(NO)]} and two water molecules. The FeIIIatoms have distorted octahedral geometries, while the CuIIatoms can be considered to be pentacoordinate. In the crystal, however, the units align to form zigzag cyanide-bridged chains propagating along [101]. Hence, the CuIIatoms have distorted octahedral coordination spheres with extremely long semicoordination Cu—N(cyanido) bridging bonds. The chains are linked by O—H...N and N—H...N hydrogen bonds, forming two-dimensional networks parallel to (010), and the networks are linkedviaN—H...O and N—H...N hydrogen bonds, forming a three-dimensional framework. Compound (II) is a two-dimensional cyanide-bridged coordination polymer. The asymmetric unit is composed of two chiral {[Cu(Lpn)2][Cr(CN)6]}−anions bridged by a chiral [Cu(Lpn)2]2+cation and five water molecules of crystallization. Both the CrIIIatoms and the central CuIIatom have distorted octahedral geometries. The coordination spheres of the outer CuIIatoms of the asymmetric unit can be considered to be pentacoordinate. In the crystal, these units are bridged by long semicoordination Cu—N(cyanide) bridging bonds forming a two-dimensional network, hence these CuIIatoms now have distorted octahedral geometries. The networks, which lie parallel to (10-1), are linkedviaO—H...O, O—H...N, N—H...O and N—H...N hydrogen bonds involving all five non-coordinating water molecules, the cyanide N atoms and the NH2groups of the Lpn ligands, forming a three-dimensional framework.

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