Ultrasound assisted syntheses of a nano-structured two-dimensional mixed-ligand cadmium(II) coordination polymer and direct thermolyses for the preparation of cadmium(II) oxide nanoparticles

Polyhedron ◽  
2011 ◽  
Vol 30 (6) ◽  
pp. 929-934 ◽  
Author(s):  
Zohreh Rashidi Ranjbar ◽  
Ali Morsali
Keyword(s):  
Coordination Polymer ◽  
Mixed Ligand ◽  
Oxide Nanoparticles ◽  
Two Dimensional ◽  
Ultrasound Assisted

Exploration of semiconducting properties of Zn(II) and Cd(II) based coordination polymers with dicarboxylate of chair-type backbone

CrystEngComm ◽  
2021 ◽  
Author(s):  
Akhtaruz Zaman ◽  
Baishakhi Pal ◽  
Samim Khan ◽  
Basudeb Dutta ◽  
Sanobar Naaz ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Room Temperature ◽  
Mixed Ligand ◽  
Two Dimensional ◽  
Slow Diffusion ◽  
Ligand System ◽  
Diffusion Technique ◽  
Semiconducting Properties ◽  
Cyclohexanedicarboxylic Acid

A new Cd(II)-based two-dimensional coordination polymer (2D CP) [{Cd2(cis-1,4-chdc)2(1,10-phen)2}۰5H2O]n (1) has been synthesized at room temperature by slow diffusion technique using 1,4-cyclohexanedicarboxylic acid (1,4-H2chdc) and 1,10-phenanthroline (1,10-phen) mixed-ligand system. The...

A two-dimensional copper(II) coordination polymer based on 2,4′-oxybis(benzoate) and 4,4′-bipyridine

2017 ◽  
Vol 73 (7) ◽  
pp. 503-507 ◽  
Author(s):  
Long Tang ◽  
Juan Zhang ◽  
Xiao-Xia Liu ◽  
Ji-Jiang Wang ◽  
Feng Fu
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Three Dimensional ◽  
Crystal Structure Analysis ◽  
Mixed Ligand ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
X Ray ◽  
Dimensional Wave

The reaction of Cu(NO3)2·3H2O with 2,4′-oxybis(benzoic acid) and 4,4′-bipyridine under hydrothermal conditions produced a new mixed-ligand two-dimensional copper(II) coordination polymer, namely poly[[(μ-4,4′-bipyridine-κ2 N,N′)[μ-2,4′-oxybis(benzoato)-κ4 O 2,O 2′:O 4,O 4′]copper(II)] monohydrate], {[Cu(C14H8O5)(C10H8N2)]·H2O} n , which was characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction. The X-ray diffraction crystal structure analysis reveals that the CuII ions are connected to form a two-dimensional wave-like network through 4,4′-bipyridine and 2,4′-oxybis(benzoate) ligands. The two-dimensional layers are expanded into a three-dimensional supramolecular structure through intermolecular O—H...O and C—H...O hydrogen bonds. Furthermore, magnetic susceptibility measurements indicate that the complex shows weak antiferromagnetic interactions between adjacent CuII ions.

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