Self-assembly of extended structures through non-coordination intermolecular forces: Synthesis, crystal structures, and properties of metal complexes with 5-methyl-2-pyrazinecarboxylate

Polyhedron ◽  
2006 ◽  
Vol 25 (15) ◽  
pp. 2967-2975 ◽  
Author(s):  
Stefania Tanase ◽  
Martin van Son ◽  
Gerard A. van Albada ◽  
René de Gelder ◽  
Elisabeth Bouwman ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Crystal Structures ◽  
Self Assembly ◽  
Intermolecular Forces ◽  
Structures And Properties

Homochiral imidazole-based dicarboxylate metal complexes with SrSi2 topology: synthesis, crystal structures, and properties

2014 ◽  
Vol 67 (5) ◽  
pp. 822-836 ◽  
Author(s):  
Li Sun ◽  
Jiang-Feng Song ◽  
Rui-Sha Zhou ◽  
Jia Zhang ◽  
Lu Wang ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Crystal Structures ◽  
Structures And Properties

scholarly journals Crystal structures and Hirshfeld surface analysis of transition-metal complexes of 1,3-azolecarboxylic acids

2019 ◽  
Vol 75 (9) ◽  
pp. 1319-1326
Author(s):  
Natthaya Meundaeng ◽  
Timothy John Prior ◽  
Apinpus Rujiwatra
Keyword(s):  
Carboxylic Acid ◽  
Transition Metal ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Surface Analysis ◽  
Transition Metal Complexes ◽  
Self Assembly ◽  
Hirshfeld Surface ◽  
Hirshfeld Surface Analysis ◽  
Single Crystal Structures

The crystal structures of five new transition-metal complexes synthesized using thiazole-2-carboxylic acid (2-Htza), imidazole-2-carboxylic acid (2-H2ima) or 1,3-oxazole-4-carboxylic acid (4-Hoxa), namely diaquabis(thiazole-2-carboxylato-κ2 N,O)cobalt(II), [Co(C4H2NO2S)2(H2O)2], 1, diaquabis(thiazole-2-carboxylato-κ2 N,O)nickel(II), [Ni(C4H2NO2S)2(H2O)2], 2, diaquabis(thiazole-2-carboxylato-κ2 N,O)cadmium(II), [Cd(C4H2NO2S)2(H2O)2], 3, diaquabis(1H-imidazole-2-carboxylato-κ2 N 3,O)cobalt(II), [Co(C4H2N2O2)2(H2O)2], 4, and diaquabis(1,3-oxazole-4-carboxylato-κ2 N,O 4)cobalt(II), [Co(C4H2NO3)2(H2O)2], 5, are reported. The influence of the nature of the heteroatom and the position of the carboxyl group in relation to the heteroatom on the self-assembly process are discussed based upon Hirshfeld surface analysis and used to explain the observed differences in the single-crystal structures and the supramolecular frameworks and topologies of complexes 1–5.

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