Binucleating, macrocyclic [14]N4 ligands and their complexes. Synthesis of the free ligand 2,3-dioxo-5,6:13,14-dibenzo-9,10-(4',5'-dimethylbenzo)-1,4,8,11-tetraazacyclotetradeca-7,11-diene (L) and of the 7,12-Me2-L metal complexes and derivatives. Crystal structures and properties of the [M'][M(7,12-Me2-L)] complexes (M = Ni(II); M = Co(II); M' = ZnCl2, M = Ni(II); M' = [Na(5-crown-15)]+, M = Ni(II); M' = [(C2H5)4N]+, M = Ni(II))

1990 ◽  
Vol 29 (2) ◽  
pp. 191-201 ◽  
Author(s):  
D. Christodoulou ◽  
M. G. Kanatzidis ◽  
D. Coucouvanis
2014 ◽  
Vol 67 (5) ◽  
pp. 822-836 ◽  
Author(s):  
Li Sun ◽  
Jiang-Feng Song ◽  
Rui-Sha Zhou ◽  
Jia Zhang ◽  
Lu Wang ◽  
...  

2006 ◽  
Vol 59 (5) ◽  
pp. 307 ◽  
Author(s):  
Muna R. A. Al-Mandhary ◽  
Christopher M. Fitchett ◽  
Peter J. Steel

The syntheses and metal complexes of 1,2,4,5-tetrakis(8-quinolyloxymethyl)benzene 1 and hexakis(8-quinolyloxymethyl)benzene 2 are described. X-Ray crystal structures are reported of the free ligand 1, a binuclear silver(i) and a tetranuclear copper(i) complex of 1, as well as a binuclear cobalt(ii) and trinuclear palladium(ii) and silver(i) complexes of 2. Within these discrete metal complexes the ligands are found to adopt a range of coordination modes, with considerable variation in the relative orientations of the ligand arms as a result of the flexibility imparted by the CH2O linker units.


Polyhedron ◽  
2006 ◽  
Vol 25 (7) ◽  
pp. 1618-1624 ◽  
Author(s):  
Ya-Min Li ◽  
Jian-Jun Zhang ◽  
Rui-Biao Fu ◽  
Sheng-Chang Xiang ◽  
Tian-Lu Sheng ◽  
...  

Polyhedron ◽  
2013 ◽  
Vol 57 ◽  
pp. 24-29 ◽  
Author(s):  
Yu-Hui Tan ◽  
Ji-Si Wu ◽  
Chang-Shan Yang ◽  
Qiang-Ren Liu ◽  
Yun-Zhi Tang ◽  
...  

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