Binuclear coordination compounds as building-blocks in designing polynuclear complexes

Polyhedron ◽  
2004 ◽  
Vol 23 (4) ◽  
pp. 673-678 ◽  
Author(s):  
Mirela Pascu ◽  
Marius Andruh ◽  
Achim Müller ◽  
Marc Schmidtmann
Keyword(s):  
Coordination Compounds ◽  
Building Blocks ◽  
Polynuclear Complexes

Coordination Compounds as Synthetic Building Blocks

Synlett ◽  
2002 ◽  
Vol 2002 (07) ◽  
pp. 1043-1054 ◽  
Author(s):  
Yitzhak Tor
Keyword(s):  
Coordination Compounds ◽  
Building Blocks

Organometallic polyphosphorus and -arsenic ligands as linkers between pre-assembled linear CuI fragments

2015 ◽  
Vol 51 (14) ◽  
pp. 2893-2895 ◽  
Author(s):  
Martin Fleischmann ◽  
Luis Dütsch ◽  
Mehdi Elsayed Moussa ◽  
Andrea Schindler ◽  
Gábor Balázs ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Building Blocks ◽  
Polynuclear Complexes ◽  
Simple Route ◽  
One Dimensional

We present a simple route to multimetallic CuI building blocks and their interaction with organometallic polyphosphorus and -arsenic linkers affording in novel polynuclear complexes or one-dimensional coordination polymers.

Cu(N–N)2Cl2 and Cu(N–N–N)Cl2 and HgCl2 building blocks in the synthesis of coordination compounds—X-ray studies and magnetic properties

2010 ◽  
Vol 183 (9) ◽  
pp. 2012-2020 ◽  
Author(s):  
B. Machura ◽  
A. Świtlicka ◽  
I. Nawrot ◽  
J. Mroziński ◽  
R. Kruszynski ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Compounds ◽  
Building Blocks ◽  
X Ray

Polynuclear and Extended Coordination Compounds from Preorganized Bimetallic Components: Tuning the Magnetic Properties of Dinickel(II) Building Blocks

2004 ◽  
Vol 2004 (12) ◽  
pp. 2413-2420 ◽  
Author(s):  
Guido Leibeling ◽  
Serhiy Demeshko ◽  
Bernhard Bauer-Siebenlist ◽  
Franc Meyer ◽  
Hans Pritzkow
Keyword(s):  
Magnetic Properties ◽  
Coordination Compounds ◽  
Building Blocks

Cyano-bridged polynuclear coordination compounds derived from paramagnetic [Mn(H2daptsc)]2+ and photochromic [Fe(CN)5NO]2− building blocks

CrystEngComm ◽  
2021 ◽  
Vol 23 (14) ◽  
pp. 2733-2745
Author(s):  
Valentina D. Sasnovskaya ◽  
Leokadiya V. Zorina ◽  
Sergey V. Simonov ◽  
Artem D. Talantsev ◽  
Artem A. Mikhailov ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Coordination Compounds ◽  
Building Blocks ◽  
Multifunctional Materials ◽  
Polynuclear Coordination Compounds

Metal complexes with H2daptsc ligand were first used as building blocks to create polynuclear multifunctional materials.

Comparison of halogen bonding networks with Ru(ii) complexes and analysis of the influence of the XB interactions on their reactivity

2017 ◽  
Vol 203 ◽  
pp. 257-283 ◽  
Author(s):  
Marta E. G. Mosquera ◽  
Irene Egido ◽  
Carlos Hortelano ◽  
María López-López ◽  
Pilar Gómez-Sal
Keyword(s):  
Coordination Compounds ◽  
Analogous Result ◽  
Halogen Bonding ◽  
Building Blocks ◽  
Structural Features ◽  
Isocyanide Ligands ◽  
Unexpected Reaction ◽  
Chloride Ligand ◽  
Chloride Ligands ◽  
Supramolecular Networks

Coordination compounds of formula [Ru(Cl)2(CNR)4] are interesting building blocks for the preparation of halogen bonding supramolecular networks, since the chloride ligand is a good XB acceptor. When using I2 as the XB donor, an unexpected reaction on the ruthenium coordination sphere happens where the chloride ligands are substituted by iodides. The isolation of several intermediates with different substitution degrees and showing XB interactions in a solid state network evidenced the clear influence of the XB species in this unusual reaction process. The extension of the studies to bromine gave the analogous result, i.e. the substitution of the chloride ligands by bromides. Furthermore, changing the organic substituent in the isocyanide ligands from alkyl to aryl does not affect the outcome of the reaction; however the process is faster when the alkyl substituents are present. In the course of the study of these reactions we have isolated a whole range of XB-based networks were interactions such as Cl⋯I–I, Br⋯Br–Br, I⋯I–I and I⋯Br–Br are present, a systematic comparison of the XB structural features for the different networks isolated and the influence in their reactivity has been performed.

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