Organometallic polyphosphorus and -arsenic ligands as linkers between pre-assembled linear CuI fragments

2015 ◽  
Vol 51 (14) ◽  
pp. 2893-2895 ◽  
Author(s):  
Martin Fleischmann ◽  
Luis Dütsch ◽  
Mehdi Elsayed Moussa ◽  
Andrea Schindler ◽  
Gábor Balázs ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Building Blocks ◽  
Polynuclear Complexes ◽  
Simple Route ◽  
One Dimensional

We present a simple route to multimetallic CuI building blocks and their interaction with organometallic polyphosphorus and -arsenic linkers affording in novel polynuclear complexes or one-dimensional coordination polymers.

Synthesis, crystal structures and magnetic characterisation of two 2p–3d metallic coordination polymers

2017 ◽  
Vol 41 (6) ◽  
pp. 365-369 ◽  
Author(s):  
Chongchong Xue ◽  
Jingwen Shi ◽  
Daopeng Zhang
Keyword(s):  
Magnetic Susceptibility ◽  
Coordination Polymers ◽  
Supramolecular Structure ◽  
Three Dimensional ◽  
Building Blocks ◽  
Chain Structure ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
Dimensional Network

The coordination polymers {Mg[Fe(L)(CN)5]}n·0.5nH2O and {MgCu2(CH3COO)6}n [L = bis( N-imidazolyl)methane] have been synthesised. X-ray diffraction revealed that {Mg[Fe(L)(CN)5]}n·0.5nH2O has a one-dimensional neutral chain structure consisting of alternating [Mg(L)2(H2O)2)]2+ species and [Fe(L)(CN)5]2– building blocks, which can be further linked into a three-dimensional supramolecular structure by inter-chain p–p interactions. {MgCu2(CH3COO)6}n has a three-dimensional network with the [MgCu2(CH3COO)6] unit as neutral core extended by Mg–O bonds. Magnetic susceptibility studies on {MgCu2(CH3COO)6}n revealed antiferromagnetic interactions between adjacent Cu(II) ions.

scholarly journals Rational Self-Assembly of Tricobalt Extended Metal Atom Chains and [MF6]2-Building Blocks into One-Dimensional Coordination Polymers

2017 ◽  
Vol 2018 (3-4) ◽  
pp. 320-325 ◽  
Author(s):  
Miguel Cortijo ◽  
Vladimir Bulicanu ◽  
Kasper S. Pedersen ◽  
Mathieu Rouzières ◽  
Jesper Bendix ◽  
...  
Keyword(s):  
Metal Atom ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Building Blocks ◽  
One Dimensional

Two cobalt(II) supramolecular isomers based onN,N′-bis(pyridin-3-yl)oxalamide induced by the molecular orientation of lattice DMF molecules

2016 ◽  
Vol 72 (2) ◽  
pp. 170-173 ◽  
Author(s):  
Di-Chang Zhong ◽  
Ya-Qiong Wen ◽  
Ji-Hua Deng ◽  
Tao-Hua Jian ◽  
Ke-Jun Wang
Keyword(s):  
Coordination Polymers ◽  
Building Block ◽  
Molecular Orientation ◽  
Solvothermal Method ◽  
Building Blocks ◽  
X Ray Diffraction ◽  
Coordination Networks ◽  
One Dimensional ◽  
X Ray ◽  
Supramolecular Isomerism

Supramolecular isomerism for coordination networks refers to the existence of different architectures having the same building blocks and identical stoichiometries. For a given building block, different arrangements can lead to the formation of a series of supramolecular isomers. Two one-dimensional CoIIcoordination polymers based onN,N′-bis(pyridin-3-yl)oxalamide (BPO), bothcatena-poly[[[dichloridocobalt(II)]-bis[μ-N,N′-bis(pyridin-3-yl)oxalamide-κ2N:N′]] dimethylformamide disolvate], {[CoCl2(C12H10N4O2)2]·2C3H7NO}n, have been assembled by the solvothermal method. Single-crystal X-ray diffraction analyses reveal that the two compounds are supramolecular isomers, the isomerism being induced by the orientation of the dimethylformamide (DMF) molecules in the crystal lattice.

scholarly journals Linear One-Dimensional Coordination Polymers Constructed by Dirhodium Paddlewheel and Tetracyanido-Metallate Building Blocks

Crystals ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 614 ◽  
Author(s):  
David Prior ◽  
Miguel Cortijo ◽  
Rodrigo González-Prieto ◽  
Santiago Herrero ◽  
Reyes Jiménez-Aparicio ◽  
...  
Keyword(s):  
Single Crystal ◽  
Coordination Polymers ◽  
Chloroform Solution ◽  
Building Blocks ◽  
X Ray Diffraction ◽  
Dichloromethane Solution ◽  
Space Group ◽  
One Dimensional ◽  
X Ray ◽  
Group A

In this article, we describe the preparation of anionic heteronuclear one-dimensional coordination polymers made by dirhodium paddlewheels and tetracyanido-metallatate building blocks. A series of complexes of (PPh4)2n[{Rh2(µ-O2CCH3)4}{M(CN)4}]n (M = Ni (1), Pd (2), Pt (3)) formulae were obtained by reaction of [Rh2(μ-O2CCH3)4] with (PPh4)2[M(CN)4] in a 1:1 or 2:1 ratio. Crystals of 1−3 suitable for single crystal X-ray diffraction were grown by slow diffusion of a dichloromethane solution of the dirhodium complex into a chloroform solution of the corresponding tetracyanido–metallatate salt. Compounds 1 and 2 are isostructural and crystallize in the triclinic P-1 space group, while compound 3 crystallizes in the monoclinic P21/n space group. A detailed description of the structures is presented, including the analysis of the packing of anionic chains and PPh4+ cations.

scholarly journals One-dimensional coordination polymers of [Co3(dpa)4]2+ and [MF6]2− (M = ReIV, ZrIV and SnIV)

2015 ◽  
Vol 51 (100) ◽  
pp. 17748-17751 ◽  
Author(s):  
Vladimir Bulicanu ◽  
Kasper S. Pedersen ◽  
Mathieu Rouzières ◽  
Jesper Bendix ◽  
Pierre Dechambenoit ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Building Blocks ◽  
One Dimensional ◽  
Metal Metal

1-D coordination polymers of alternating metal–metal bonded trinuclear [Co3(dpa)4]2+ building blocks and [MF6]2− (M = Re, Zr, Sn) linkers have been structurally and magnetically characterized.

Anion and solvent controlled growth of crystalline and amorphous zinc(II) coordination polymers and a molecular complex

2021 ◽  
Author(s):  
Claire Deville ◽  
Henrik Særkjær Jeppesen ◽  
Vickie McKee ◽  
Nina Lock
Keyword(s):  
Coordination Polymers ◽  
Molecular Complex ◽  
Research Field ◽  
Metal Coordination ◽  
Controlled Growth ◽  
Bottom Up ◽  
One Dimensional

Controlled bottom-up synthesis of amorphous coordination polymers with tailored metal coordination is a research field in its infancy. In this study, synthesis control was achieved to selectively prepare one-dimensional (1D)...

On-Surface Synthesis of One-Dimensional Coordination Polymers with Tailored Magnetic Anisotropy

2021 ◽  
Author(s):  
Benjamin Mallada ◽  
Piotr Błoński ◽  
Rostislav Langer ◽  
Pavel Jelínek ◽  
Michal Otyepka ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Coordination Polymers ◽  
One Dimensional

Spin Crossover in a Series of Non-Hofmann-Type Fe(II) Coordination Polymers Based on [Hg(SeCN)3]− or [Hg(SeCN)4]2– Building Blocks

2021 ◽  
Author(s):  
Tong Cao ◽  
Francisco Javier Valverde-Muñoz ◽  
Xiaoyi Duan ◽  
Mingjian Zhang ◽  
Ping Wang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Spin Crossover ◽  
Building Blocks
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