Steric saturation of the ytterbium coordination environment: (TptBu,Me)Yb(OMes), a four coordinate, monomeric, base-free divalent lanthanide complex, its solvation with tetrahydrofuran, and comparison to the β-diketonate complex, (TptBu,Me)Yb(dpm)

Polyhedron ◽  
2004 ◽  
Vol 23 (2-3) ◽  
pp. 263-271 ◽  
Author(s):  
Martin Morissette ◽  
Stefan Haufe ◽  
Robert McDonald ◽  
Gregory M. Ferrence ◽  
Josef Takats
Keyword(s):  
Lanthanide Complex ◽  
Coordination Environment ◽  
Divalent Lanthanide

scholarly journals Redox activity of a dissymmetric ligand bridging divalent ytter-bium and reactive nickel fragments

2021 ◽  
Author(s):  
Ding Wang ◽  
Maxime Tricoire ◽  
Valeriu Cemortan ◽  
Jules Moutet ◽  
Grégory Nocton
Keyword(s):  
Nickel Complex ◽  
Bond Formation ◽  
Lanthanide Complex ◽  
Redox Activity ◽  
Trimeric Complex ◽  
Redox Active ◽  
Divalent Lanthanide

The reaction of a nickel complex bearing a redox-active dissymmetric ligand (Kbimpm) with a divalent lanthanide complex, Cp*2Yb(OEt2) affords an unprecedented, trimeric complex with C(sp3)–C(sp3) bond formation between two ligands in an exo position.

scholarly journals Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls

2019 ◽  
Vol 55 (41) ◽  
pp. 5765-5768 ◽  
Author(s):  
Ravi Yadav ◽  
Thomas Simler ◽  
Michael T. Gamer ◽  
Ralf Köppe ◽  
Peter W. Roesky
Keyword(s):  
Lanthanide Complex ◽  
Divalent Lanthanide

The reduction of M2(CO)10 (M = Mn, Re) with different divalent lanthanide (Ln = Sm, Yb) compounds was investigated.

Boosting electrochemical nitrogen reduction reaction performance of two-dimensional Mo porphyrin monolayers via turning the coordination environment

2021 ◽  
Vol 23 (7) ◽  
pp. 4178-4186
Author(s):  
Shiqiang Liu ◽  
Zhiwen Cheng ◽  
Yawei Liu ◽  
Xiaoping Gao ◽  
Yujia Tan ◽  
...  
Keyword(s):  
Energy Conversion ◽  
Reduction Reaction ◽  
Metal Catalysts ◽  
Two Dimensional ◽  
Coordination Environment ◽  
Nitrogen Reduction ◽  
Reaction Performance ◽  
Conversion Efficiencies

Designing atomically dispersed metal catalysts for the nitrogen reduction reaction (NRR) is an effective approach to achieve better energy conversion efficiencies.

Enhancing Electrocatalytic Production of H 2 O 2 by Modulating Coordination Environment of Cobalt Center

2021 ◽  
Author(s):  
Guoling Wu ◽  
Zhongjie Yang ◽  
Tianlin Zhang ◽  
Yali Sun ◽  
Chang Long ◽  
...  
Keyword(s):  
Coordination Environment ◽  
Cobalt Center

Controllable Coordination of Phosphotungstic Acid-Modified Carbon Matrix for Anchoring Different Sizes of Pt Species: From Single Atoms, Subnanoclusters to Nanoparticles

2021 ◽  
Author(s):  
Jiazhe Li ◽  
Zhiyuan Yan ◽  
Lingxiang Bao ◽  
Cheng-Hui Sun ◽  
Si-Ping Pang
Keyword(s):  
Phosphotungstic Acid ◽  
Carbon Matrix ◽  
High Density ◽  
Coordination Environment ◽  
Single Atoms

Pt species with different sizes uniformly dispersed on phosphotungstic (PTA) acid modified carbon matrix (PTA-C) were controllably synthesized by manipulating the coordination environment. The results indicate that high-density and well-defined...

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