Syntheses and crystal structures of ferrocene-containing enaminones and their copper complexes

Polyhedron ◽  
2004 ◽  
Vol 23 (1) ◽  
pp. 15-21 ◽  
Author(s):  
Yao-Cheng Shi ◽  
Hua-Mei Yang ◽  
Wen-Bin Shen ◽  
Chao-Guo Yan ◽  
Xiao-Ya Hu
2021 ◽  
Author(s):  
Nazanin Kordestani ◽  
Hadi Amiri Rudbari ◽  
Alexandra R Fernandes ◽  
Luís R Raposo ◽  
André Luz ◽  
...  

To investigate the effect of different halogen substituents, leaving groups and the flexibility of ligand on the anticancer activity of copper complexes, sixteen copper(II) complexes with eight different tridentate Schiff-base...


Polyhedron ◽  
1999 ◽  
Vol 18 (24) ◽  
pp. 3173-3179 ◽  
Author(s):  
Paul F Kelly ◽  
Sit-Ming Man ◽  
Alexandra M.Z Slawin ◽  
Kevin W Waring

2006 ◽  
Vol 2006 ◽  
pp. 1-11 ◽  
Author(s):  
Michael Devereux ◽  
Malachy McCann ◽  
Denis O'Shea ◽  
Mark O'Connor ◽  
Eileen Kiely ◽  
...  

2,2-dimethylpentanedioic acid (2dmepdaH2) and 3,3-dimethylpentanedioic acid (3dmepdaH2) reacted with copper(II) acetate to give [Cu(2dmepda)(H2O)3]2(1) and [Cu(3dmepda)(H2O)3]2(2). Reaction of (1) and (2) with 1,10-phenanthroline and 2,2′-bipyridine yielded [Cu(2dmepda)(phen)(H2O)]20.5phen (3), [Cu(2dmepda)(bipy)(H2O)]2(4), [Cu(2dmepda)(bipy)(EtOH)]2⋅2EtOH(4A), [Cu(3dmepda)(phen)(H2O)]2(5), and [Cu(3dmepda)(bipy)(H2O)]2⋅(6). The structures of (4A) and (6) each consists of a [Cu(bipy)(dicarboxylate)(solvent)]2dimer. The superoxide dismutase (SOD) mimetic activity of the novel copper complexes and their manganese analogues was investigated. The dimethyl sulphoxide(DMSO) soluble complexes (1)–(4) and (6) were assessed for their cancer chemotherapeutic potential towards hepatocellular carcinoma and kidney adenocarcinoma cell lines. The 1,10-phenanthroline containing complex [Cu(2dmepda)(phen)(H2O)]20.5phen (3) was the most potent with activity that compares well to that ofcisplatin.


Nature ◽  
1962 ◽  
Vol 194 (4835) ◽  
pp. 1237-1239 ◽  
Author(s):  
T. COOPER ◽  
H. C. FREEMAN ◽  
G. ROBINSON ◽  
J. C. SCHOONE

2004 ◽  
pp. 862 ◽  
Author(s):  
Sneh L. Jain ◽  
Pravat Bhattacharyya ◽  
Heather L. Milton ◽  
Alexandra M. Z. Slawin ◽  
Joe A. Crayston ◽  
...  

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