Mechanical spectrum study of glass transition by a composite method

2009 ◽  
Vol 404 (20) ◽  
pp. 3771-3774 ◽  
Author(s):  
Y.H. Yuan ◽  
L. Zhang ◽  
X.L. Wang ◽  
X.N. Ying ◽  
F. Yan ◽  
...  
1977 ◽  
Vol 47 (7) ◽  
pp. 451-456 ◽  
Author(s):  
J. P. Walters ◽  
D. R. Buchanan

Analysis of the detailed dynamic mechanical spectrum in the vicinity of the glass-transition temperature (Tg) of a series of polyamide textile fibers allows the prediction of their relative dyeabilities with a disperse dye, Celanthrene Fast Blue 2G, to an accuracy of about 1 K/S unit. The technique is sensitive enough to account for dyeing variations caused by annealing treatments or by drawing variations, as well as those caused by differences in molecular structure. From the position of the maximum in tan? as a function of temperature in a dynamic mechanical experiment, one definition of the Tg, it is possible to estimate semi-quantitatively whether or not a fiber will be dyeable at 100°C without carrier. In general, fibers whose Tg at 100% RH, as defined here, occurs at or below 100°C can be dyed to at least moderate shades without carrier.


2012 ◽  
Vol 184 ◽  
pp. 361-365
Author(s):  
Xue Jun Jin ◽  
M. J. Jin ◽  
J. Y. Liu ◽  
G. L. Fan

Strain glass is a new type of glass state discovered recently in Ni-rich Ti-Ni ferroelastic alloys. It is formed by doping sufficient point defects such as solute atoms or alloying elements into a martensitic alloy to destroy the long range strain order generated by the diffusionless martensitic phase transformation. The strain glass was observed in an off-stoichiometric Heusler Au7Cu5Al4 alloy by the mechanical spectrum analysis. The martensitic transformation was experimentally confirmed following the occurrence of strain glass transition during the cooling. It is different from the model developed mainly in Ni-Ti based alloys among which the martensitic transformation was totally suppressed once the strain glass transition takes place. We conclude that newly observed strain glass in an off-stoichiometric Au7Cu5Al4 alloy belongs to one type of precursor phenomena.


1998 ◽  
Vol 77 (2) ◽  
pp. 305-311 ◽  
Author(s):  
Thomas Scheidsteger, Rolf Schilling

1998 ◽  
Vol 08 (PR6) ◽  
pp. Pr6-109-Pr6-113
Author(s):  
P. Gallo ◽  
F. Sciortino ◽  
P. Tartaglia ◽  
S.-H. Chen

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