Multiphased mixed crystals: Interconnection of the conductivity activation energy with bulk properties

2008 ◽  
Vol 403 (19-20) ◽  
pp. 3809-3811 ◽  
Author(s):  
Vassiliki Katsika-Tsigourakou ◽  
Aglaia Vassilikou-Dova
2021 ◽  
Vol 66 (2) ◽  
pp. 159
Author(s):  
A.I. Pogodin ◽  
M.M. Luchynets ◽  
M.Y. Filep ◽  
A.A. Kohutych ◽  
T.O. Malakhovska ◽  
...  

Cu7−xPS6−xIx mixed crystals were grown by the direct crystallization from a melt. The electrical conductivity is measured in the frequency range from 10 Hz to 300 kHz and in the temperature interval 293–383 K. The frequency, temperature, and compositional dependences of the electrical conductivity for Cu7−xPS6−xIx mixed crystals are studied. The measurements of thermoelectric parameters of Cu7−xPS6−xIx mixed crystals are carried out in the temperature interval 293–383 K. The compositional behaviors of the electrical conductivity, activation energy, Seebeck coefficient, and power factor are investigated. The interrelation between the structural, electrical, and thermoelectrical properties is analyzed.


1988 ◽  
Vol 66 (5) ◽  
pp. 373-375 ◽  
Author(s):  
C. J. Arsenault ◽  
D. E. Brodie

Zn-rich and P-rich amorphous Zn3P2 thin films were prepared by co-evaporation of the excess element during the normal Zn3P2 deposition. X-ray diffraction techniques were used to investigate the structural properties and the crystallization process. Agglomeration of the excess element within the as-made amorphous Zn3P2 thin film accounted for the structural properties observed after annealing the sample. Electrical measurements showed that excess Zn reduces the conductivity activation energy and increases the conductivity, while excess P up to 15 at.% does not alter the electrical properties significantly.


1986 ◽  
Vol 70 ◽  
Author(s):  
J. Kolodzey ◽  
S. Aljishi ◽  
Z E. Smith ◽  
V. Chu ◽  
R. Schwarz ◽  
...  

ABSTRACTThe effects of illumination on the optical and electronic properties of narrow gap hydrogenated and fluorinated amorphous Si-Ge (a-Si1-xGex:H, F) alloys have been evaluated. A series of alloys with optical gaps ranging from 1.30 eV to 1.64 eV has been light soaked at ∼1 sun intensity for 354 hours. Measurements of sub-gap absorption, photo- and dark conductivities and dark conductivity activation energy were made on alloys in the annealed and the light-soaked states. The results indicate that samples with optical gaps ≳ 1.4 eV degrade significantly. The 1.3 eV sample shows no degradation in its optical or electronic properties except for a factor of 5 increase in the dark conductivity.


1998 ◽  
Vol 36 (5-6) ◽  
pp. 290-293 ◽  
Author(s):  
Jean-Claude M'Peko ◽  
A.Rabdel Ruiz-Salvador ◽  
Gerardo Rodrı́guez-Fuentes

Author(s):  
Yuliya Verhozina ◽  
Yuriy Pozhidaev

The composition and structure of the membrane based on the acid-base method of elemental analysis, IR and NMR spectroscopy were studied. The ion-exchange capacity, proton conductivity, activation energy, and thermogravimetric analysis of the resulting membranes were studied.


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